Polydiacetylene‐Tb3+ Nanosheets of Which Both the Color and the Fluorescence Can Be Reversibly Switched between Two Colors

Polydiacetylenes (PDAs), an organic layered compound, show a series of intriguing properties, such as thermochromism and fluorescence emission in the red‐phase. However, their irreversible color change, and weak and single‐color fluorescence emitted only from the red‐phase PDAs, have limited their applications. Herein, we report double‐reversible PDA‐Tb³⁺ nanosheets of which both the color and the fluorescence can be reversibly switched between two colors. PDA‐Tb³⁺ nanosheets have the nearly defect‐free intercalated structure in which a layer of Tb³⁺ ions was intercalated in between each two PDA bilayers to tether almost all of the carboxyl groups at the end of the side chains of the PDA. When the PDA is in the blue phase, the PDA‐Tb³⁺ nanosheets emit the green fluorescence of Tb³⁺ ions. When the PDA is in the red phase, the Tb³⁺ fluorescence disappears while the intrinsic red fluorescence of PDA is effectively enhanced through the fluorescence resonance energy transfer (FRET) process; the PDA‐Tb³⁺ nanosheets emit stronger red fluorescence compared with the PDA in red phase. Moreover, the tethering of almost all of the carboxyl groups at the end of the side chains of the PDA endows the nanosheets with the double reversibility in both the color and fluorescence transitions.     

构建以职业生涯需求为主导的就业指导体系

大学生处于职业生涯发展的探索期,其职业发展既有理想的成分,又不得不考虑现实条件的限制.因此,大学生的职业生涯发展有其特殊的需求.针对大学生职业生涯发展的特殊需求,开展全程化就业指导,是构建当前高校就业指导体系的有效策略.     

New possibilities for testing local realism in high energy physics

The three photons from the dominant ortho-positronium decay and two vector mesons from the η_c exclusive decays are found to be in tripartite and high-dimensional entangled states, respectively. These two classes of entangled states possess the Hardy type nonlocality and allow a priori for quantum mechanics vs local realism test via Bell inequalities. The experimental realizations are shown to be feasible, and a concrete scheme to fulfill the test in experiment via two-vector-meson entangled state is proposed.     

High-quality oriented ZnO films grown by sol-gel process assisted with ZnO seed layer

High-quality oriented ZnO films were prepared on silicon and quartz glass by sol-gel, assisted with a ZnO seed layer. The effects of the seed layer on the orientation, morphology and optical properties of ZnO films were investigated. Results show that the seed layer can effectively induce the growth of high-quality oriented ZnO films on two substrates, and the effectiveness of the seed layer strongly depends on preparation conditions, i.e., the spin-coating layer number and the preheating temperature. ZnO films with five layers on the seed layer preheated at 500 °C exhibit the single (0 0 2) orientation, which is much stronger than that on the flat substrate. Additionally, ZnO films on the seed layer show a denser internal structure and higher optical quality than that on the flat substrate. At ten layers, however, ZnO films on the seed layer show the multiple-orientation, which is similar to that on the flat substrate. Finally, the physical mechanism underlying the growth behavior of ZnO films assisted with the seed layer was discussed.     

EVA塑料发泡倍率的影响规律实验

采用田口实验设计方法,选取模具温度、模压时间、注射压力和模压压力进行正交实验,分析工艺参数对EVA(乙烯-醋酸乙烯酯共聚物)发泡倍率的影响.结果表明,模具温度对发泡倍率的影响较为显著,模压时间次之,注射压力与模压压力的影响较小.随着模具温度的升高,发泡倍率逐渐增大,最终趋于稳定值,随着模压时间的增加,发泡倍率也逐渐最大...     

MARKOV SKELETON PROCESS IN PERT NETWORKS

In this article, we investigate Programming Evaluation and Review Technique networks with independently and generally distributed activity durations. For any path in this network, we select all the activities related to this path such that the completion time of the sub-network （only consisting of all the related activities） is equal to the completion time of this path. We use the elapsed time as the supplementary variables and model this sub-network as a Markov skeleton process, the state space is related to the subnetwork structure. Then use the backward equation to compute the distribution of the sub-network＇s completion time, which is an important rule in project management and scheduling.     

云南壮剧民间土戏形成与发展过程的二次文献分析——国家级非物质文化遗产·云南壮剧保护研究（之二）

以《云南壮剧史》为据,运用二次文献分析的方法对云南壮剧民间土戏形成与发展的历史过程进行专业分析,发现民间土戏从清朝中晚期形成至今,其发展轨迹呈现＂山＂字形状,具有曲折波动的特点,尤其是历史上的两次重创为云南壮剧民间土戏的后续发展埋下了诸多隐患,出现了目前发展缓慢、传承困境等问题。如何应对云南壮剧民间土戏传承与可持续发展的困境问题,笔者认为应同时兼顾其自身的专业建设和文化空间的保护,二者缺一不可。     

Nonlinear branching processes with immigration

The nonlinear branching process with immigration is constructed as the pathwise unique solution of a stochastic integral equation driven by Poisson random measures. Some criteria for the regularity, recurrence, ergodicity and strong ergodicity of the process are then established.     

可溶PVA伴纺高支纯棉色织面料的生产工艺路线

对用可溶性维纶(PVA)伴纺生产高支高密纯棉色织面料的两种工艺路线("纱线染色、织造、退维"和"纱线退维、染色、织造")进行分析和试验研究.研究结果表明:采用"先退维、后染织"的工艺路线,退维股线的强力较低,可织性差,进行产业化生产的难度较大;采用"先染织、后退维"的工艺路线,织造效率和布面质量能得到保证,可应用于产业化生产;色织布退维后,织物的白度降低,颜色变浅,但无明显沾色现象.     

随机利率下跳-扩散过程的产量保险定价模型

本文研究了农产品价格为一般的跳-扩散模型,随机跳部分为复合Poisson过程,并假设远期利率服从HJM模型,利用测度变换技巧,给出了合同的在此模型下的解析解.