搜寻平面机构中虚约束的拆杆组法

本文根据机构的组成原理,提出一种搜寻机构中虚约束的新方法一拆杆组法,用该方法能方便地判断出机构中所含的虚约束,同时能迅速排除含有特定几何条件而实际上并不存在虚约束的机构.     

Comparative studies on the mechanism of uridine phosphorolysis

We have used quantum mechanical method to study the transition states(TSs) of uridine phosphorolysis reaction. Comparing the four different reaction pathways and the five transition states obtained, we conclude that enzymatic uridine phosphorolysis takes place mainly according to acid-catalyzed SN2 mechanism. The proposed reaction pathway is consistent with many experimental results.     

曲柄滑块刚体导引机构的尺度综合与运动仿真

根据曲柄滑块机构的型式 ,建立了一个含有对心和偏置两种情况在内的 2 0 30 0组的基本尺寸型连杆转角函数的谐波成分数据库。通过模糊识别方法 ,在已建立的数据库中 ,寻找出能够近似实现给定刚体导引的多个曲柄滑块机构基本尺寸型 ;然后计算机构的实际尺寸及安装尺寸参数。文中还给出了综合算例和运动仿真。     

吸附法治理汞废气的机理研究

该文对载银活性炭吸附汞蒸气的机理进行了探讨 ,通过电子探针和扫描电镜对载银活性炭及被汞“饱和”的载银活性炭进行微观结构分析 ,结果显示 ,银在活性炭中主要分布于活性炭的凸面处 ,汞只在有银存在的地方出现 ,表明普通活性炭不具备吸附汞的能力 ,载银活性炭吸附汞属于以银为核心的多分子物理吸附 ,工业上的“饱和”载银活性炭仍具有一定的吸附汞蒸气的能力 ,为交替式吸附床的结构设计提供了技术依据 .     

Adsorption effects and NMR properties: Continuous chain approach

The NMR properties of nuclei linked to long linear polymer molecules are sensitive to the influence of hard walls. In this context, the residual energy of tensorial spin-spin interactions is calculated using a path integral approach. Several thermodynamic quantities of the polymer system (free energy, equation of state,...) are also expressed, taking chain stiffness effects and the presence of two repulsive walls into consideration.     

An Integrated Two Phases Approach to Zn2+ Ions Electroreduction on Hg

The following two numerical models have been applied to zinc cations electroreduction in 1 M NaClO₄ water solution: a classical EE model describing the concentration of involved species in solution (semi infinitive diffusion region), an extended EE model describing both: the concentration of involved species in solution and the concentration of metallic zinc inside mercury drop (in limited area of diffusion). In the latter model the inner part of mercury drop and surrounding solution were treated as dynamic interrelated system. Both models were applied to experimental cyclic voltammetric CV data in 1 M NaClO₄, the results compared and discussed. The concentration profiles of all species including metallic zinc inside mercury drop were performed. The presented integrated model is essential for theoretical and analytical aspects of the electrochemistry of mercury soluble metal cations and amalgams.     

含氟废水处理研究与应用

本文就近年来国内对含氟废水处理研究及应用概况作了简要综述，可看出含氟废水处理的研究有了较大进展。     

A Novel Biomass Supported Na2CO3 System for Flue Gas Desulfurization

The breakthrough and stoichiometric SO2 adsorption efficiencies of a biomass supported Na2CO3 system (80 wt %Na2CO3/straw) have reached 48.9% and 80.6% respectively at a desulfurization temperature of 80℃.     

Proton conductivity of phosphoric acid derivative of fullerene

The proton conductive property of methano [60] fullerene diphosphoric acid has been investigated under various humidity conditions at the temperature range between 15 and 45 °C. It shows proton conductivity as high as 10⁻² S cm⁻¹ at 25 °C under relative humidity of 95%. Thermal analyses including TG–DTA and thermal desorption mass spectroscopy (TDS) confirm that the compound is thermally stable up to 200 °C. Proton conduction of the compound depends very much on humidity or water content. The logarithmic conductivity at 25 °C is increased linearly with increasing relative humidity. The activation energy (E_a) estimated from the slope of log(σT) vs. 1/T is decreased from 1.08 to 0.52 eV, as the relative humidity is increased from 40% to 75%. The humidity dependence of conductivity is discussed in the light of the observed hydration isotherm.     

我国信贷资本市场运作分析

资本市场是市场经济的产物。我国的信贷资本市场是整个资本市场的重要组成部分，它运作的好坏，机制是否健全、灵活、高效，不仅决定着信贷资本的供求双方资本的质量和数量，而又在某种意义上也对国家的金融风险和经济安全产生巨大影响。