影响高性能混凝土工作性和强度的主要因素的正交试验研究

研究结果表明：水胶比、减水剂掺量及胶凝材料总量对砼坍落度影响显著,碎石粗骨料种类对砼强度有显著影响．结果选择出一个具有良好坍落度（２００ｍｍ）和较高强度（８０．５ＭＰａ）的砼配合比,而其水泥用量只有４５０ｋｇ／ｍ３．图１,表３,参４．     

大体积现浇混凝土的裂缝控制技术

在大体积混凝土的施工中,通过合理选用原材料,用UEA外加剂代替相应水泥用量并调整配合比,并分层设置通冷水管降低水化热,实现了温度控制的目标,解决了高标号大体积混凝土使用普通硅酸盐水泥的裂缝控制技术问题．     

喷射混凝土新型增稠速凝剂研究

不同水泥的增稠对比试验表明：喷射混凝土新型增调速凝剂（IVA）具有良好的增稠效果经扫描电镜的观察分析,其增稠原理是IVA分子的吸附“架桥”和液相膜空间网络综合作用;不同水泥、不同水灰比时凝结时间测定表明IVA具有良好的速凝适应性;强度试验证实IVA对水泥各龄期强度发展有利;在矿山巷道的应用表明IVA能明显减少喷射混凝土回弹．图3,表4,参4     

Reparameterization of hybrid functionals based on energy differences of states of different multiplicity

 Low-spin/high-spin energy splittings for Fe(II) transition-metal complexes – particularly in weak ligand fields – cannot be well described by density functional methods. Different density functionals yield results which differ by up to 1 eV in transition-metal complexes with sulfur-rich first coordination spheres. We attribute this failure to the fact that the high-spin state is systematically favoured in Hartree–Fock-type theories, because Fermi correlation is included in the exact exchange, while Coulomb correlation is not. We thus expect that the admixture of exact exchange to a given density functional will heavily influence the energy splitting between states of different multiplicity. We demonstrate that the energy splitting depends linearly on the coefficient of exact exchange admixture. This remarkable result is found for all the Fe(II)–S complexes studied. From this observation we conclude in connection with experimental results that Becke's 20% admixture should be reduced to about 15% if meaningful energetics are sought for transition-metal compounds. We rationalize that this reduction by 5% will not affect the quality of the hybrid functional since we arrive at a slightly modified functional, which lies between the pure density functional and the hybrid density functional, which both give good results for “standard” systems. Received: 13 July 2001 / Accepted: 31 August 2001 /  Published online: 16 November 2001     

Determination of pozzolanic activity of materials by thermal analysis

The results of pozzolanic activity determination using DTA-TG method are presented. This feature was characterised by Ca(OH)₂ residue determination in cement pastes admixtured with siliceous earth, consuming the calcium ions from hydrolysis of cement clinker minerals. The rate of pozzolanic reaction was thus estimated. Some results for fly ash containing pastes were also given. This revised version was published online in August 2006 with corrections to the Cover Date.     

正交法在冻结井壁砼复合外加剂试验中的应用

为了使冻结施工井壁混凝土能够在负温条件下凝结与硬化,并满足其各项性能要求,采用引气剂＋防冻剂＋早强减水剂复合的技术路线,通过正交试验设计复配了适应冻结施工早强流态井壁混凝土的复合外加剂。通过试验分析最终确定各组分掺量之间的最佳配比。复合外加剂的掺量为2.1%,可起到流态、早强、防冻及抗冻的作用。     

不同矿物掺合料对轻骨料混凝土抗碳化性能的影响

利用Ⅱ级粉煤灰、超细粉煤灰、磨细矿粉以及钢渣粉等量取代水泥,制备了轻骨料混凝土．并采用加速碳化试验和混凝土孔溶液pH值测试技术,研究了其碳化特性,分析了不同矿物掺合料对轻骨料混凝土抗碳化性能的影响机制．研究结果表明,掺II级粉煤灰和钢渣粉的试样各龄期碳化深度均高于基准样,且不同深度处的混凝土孔溶液pH值也低于基准样;而...     

减水剂对混凝土的影响及其施工应用

本文从混凝土减水剂的减水机理出发,探讨了各种减水剂的不同减水作用,并通过试验提出了不同类型减水剂在施工中的适宜掺量。     

含不同结构单元共聚羧酸高效减水剂的应用研究

介绍了多种共聚羧酸系列混凝土高效减水剂在混凝土中的应用特性，对混凝土的坍落度保持性、减水率、抗压强度等进行了研究。在混凝土中掺加0．6％－0．75％的共聚羧酸系列产品，最高减水率可达30％，混凝土的28d强度可提高30％－50％。     

Effect of Some Aromatic Admixtures on the Raman Line Intensity of Solid Cyclohexane at 77 K

The dependence of the intensity of Raman line components of E_g symmetry of cyclohexane, frozen rapidly down to 77 K, on the concentration of admixtures of benzene or naphtalene was studied quantitatively. The admixture of benzene was found to facilitate to a larger extent the overcooling of phase I of solid cyclohexane than admixture of naphtalene.