Helix parameters in bi- and multicomponent mixtures composed of orthoconic antiferroelectric liquid crystals with three ring molecular core

Eight types of bicomponent systems composed of antiferroelectric compounds with different polarity of achiral chain and different temperature dependence of helical pitch as well as three multicomponent mixtures composed of antiferroelectric compounds with opposite helical twist sense were studied. The phase miscibility was tested by polarising optical microscopy. The results of the helical pitch and helical twist sense measurements obtained by a spectrophotometric method of selectively reflected light and by polarimetric method, respectively, are presented. It was found that it is possible to control helical pitch length and temperature of helix twist inversion in antiferroelectric mixtures by controlling the ratio of compounds with left- and right-handed helix in such mixtures, although all of them have the same chiral terminal chain.     

The temperature and concentration dependence of helical pitch in the mixtures of antiferroelectric compounds with the opposite helical twist sense

The temperature dependence of helical pitch for members of an homologous series of orthoconic antiferroelectric compounds (3FmHPhF) and their bicomponent mixtures (m = 3 and 5 as well as m = 3 and 7) has been measured by the method of selective light reflection. The compounds have the same chiral centre but they have different temperature dependence of the helical pitch as well as the helical twisting sense in SmC*_A phase: right for member m = 3, left for m = 7, and both right and left for m = 5. For this last homologue, the change of twisting sense is connected with the appearance of the unwound structure. Concentration dependence on helical pitch was investigated in the mixtures. It was demonstrated that it is possible to obtain mixtures with desirable high pitch and also with totally unwound structure.     

软件补偿方法在测温智能仪表中的应用

软件补偿方法具有效果好、精确度高、成本低的优点。介绍了在研制多点巡回检测仪中采用的几种软件补偿方法：前向通道特性补偿使放大器等元件不因外界条件的变化而受到任何影响；引线电阻的补偿可实现引线电阻对系统无任何影响；热电阻、热电偶的非线性度补偿效果明显，节省开销。     

迈克尔逊干涉仪中补偿板与干涉条纹

通过分析缺失补偿板的迈克尔逊干涉仪中的附加光程差,推出干涉条纹满足的方程式,并用计算机模拟了动镜移动过程中变化的干涉条纹,与实验结果相一致.     

PVC基活性炭的制备及其吸附性能的研究Ⅰ——PVC沥青的制备及其预氧化

以PVC树脂为原料,采用两个恒温段的程序升温方法加热脱氯制备PVC沥青,并通过空气预氧化法,对所制备的PVC沥青进行了预氧化处理.实验结果表明,PVC树脂在流速为100 mL/min氮气气氛中,以10℃/min速率程序升温至270℃,恒温脱氯150 min后再程序升温至410℃并恒温芳化120 min,可以制备出脱氯率和得率均较高的PVC沥青.该PVC沥青在300℃温度下,采用空气预氧化法预氧化120min,可获得增重率约为11%,氧化交联度较高、耐热性能较好的预氧化PVC沥青.FT-IR光谱分析结果表明,PVC沥青在预氧化的过程中,主要发生了氧化脱氢、脱水、CO2缩聚交联反应,使沥青形成耐热型的氧桥结构,从而达到预氧化目的.     

煤沥青的电化学加氢：Ⅱ.精制沥青的电化学加氢

在隔离式是电解中，用泡沫铅作用阴极，铂作阳极，饱和甘汞电极做参考电极，对太原钢铁公司焦化厂煤沥青经溶剂萃取后所得的精制沥青进行了电化学加氢的研究，考察了电解体系工艺条件对加氢效果的影响。     

浙江新高考化学加试题难度研究*

在对已有试题难度量化工具进行改进的基础上,建构了化学加试题难度评估工具。对2015年至2019年国家新高考实验区浙江省的8次化学选考加试题的难度进行了量化评价。结果表明,8次化学加试题整卷难度变化较大,但同一学年、有相同学生可能参与的2次化学选考的整体难度相近;加试题能力特征和难度差异明显,“有机化学基础”加试题(第32题)难度相对稳定,而第30题(化学反应原理)与第31题(实验化学)加试题难度却表现出一定的波动性。在对8次化学加试题的难度及相关因素进行分析的基础之上,也对如何提高加试题的编制质量,提出了可行性建议。     

螺旋桨运输机进气道阻力特性分析

以某型螺旋桨运输机带动力装置飞行试验台为研究对象，建立了三维流场模型，采用CFD进行了网格划分及数值计算。以前期飞行试验数据和发动机热力循环模型计算结果为边界条件，开展了不同飞行马赫数、高度及桨叶角的数值计算。选用桨叶角表征发动机状态，分析了不同飞行高度、马赫数、螺旋滑流对进气道前罩作用力和附加前体力影响的变化规律。计算结果表明：不同高度、桨叶角及马赫数均会改变进气道阻力，在马赫数0.5，高度4 km状态下，桨叶角由40°增大至50°，前罩作用力减小1 700 N，附加前体力减小3 600 N,而附加前体力系数及前罩作用力系数随飞行高度基本不变。进气道阻力特性研究为后续试飞中确定涡桨发动机外部阻力特性分析提供了数据支持。     

双附加气室空气弹簧动力学模型及其特性研究

设计了一款串联双附加气室约束膜式空气弹簧作为机载计算设备的隔振元件.利用气体的连续方程、状态方程、能量方程及弹簧的受力状态等建立弹簧的动力学模型,分析了空气弹簧的非线性特性、两节流孔半径变化及两附加气室体积变化对阻尼比的影响和空气弹簧的隔振效果.结果表明:空气弹簧具有周期非线性的特点;在各气室初始体积不变的情况下阻尼比的极大值首先与节流孔Ⅰ有关,在节流孔Ⅰ的半径足够大时,才与节流孔Ⅱ有关;在保持附加气室总体积不变的条件下,随着附加气室A与附加气室B体积比的增加,阻尼比减小;无论附加气室容积比如何变化,产生最大阻尼的节流孔Ⅱ的半径不变.