使用控件在PowerPoint课件制作中实现交互功能

在教学领域中,PowerPoint作为课件制作工具被广泛地采用,深受广大教师和开发人员欢迎,但其提供的现有交互功能十分有限。文章以“黑板”功能和“阅读计时器”为例,介绍了利用该软件提供的ActiveX控件,并结合基础的VBA知识,可为课件设计出符合教学实情的交互式功能。     

ASP.NET中记录定位的实现

由于ASP.NET中缺少记录移动命令,给MIS的开发带来不便.在分析了datagrid控件的特点的基础上,结合数据库关键字,实现了ASP.NET中进行记录定位.     

基于VB的网络应用程序设计

长期以来，网络编程一直是个神秘的领域，涉及到众多的专业术语，需要较深厚的网络专业基础才能涉足。而利用VB提供的网络编程控件来进行网络编程，不需要掌握网络深层知识，可迅速地开发出各种各样的网络应用程序。文章较系统地介绍了基于VB的网络应用程序设计的方法，介绍了Winsock、WebBrowser控件的常用事件、属性和方法。     

基于酸促进的单原子活性位点Ir-La-S/AC催化剂在甲醇羰基化中的应用

甲醇羰基化是世界上重要的均相催化反应之一. 无论是Rh或者Ir体系, 虽然碘甲烷的引入会带来腐蚀问题, 但是绝大多数的甲醇羰基化反应过程都需要碘甲烷作为助催化剂才能有较好的活性. 多年来人们在不断研究非均相羰基化过程(即均相多相化), 以避免均相中间歇生产和产物分离的缺点. 其中Ir体系的非均相羰基化报道很少, 值得关注的是Eastman公司将Ir-La/AC体系成功地应用于非均相的甲醇羰基化过程. 基于此, 本文试图引入硫元素以提高Ir-La/AC催化剂的羰基化活性, 即将含有La和Ir前驱体的硫酸溶液通过共浸渍法制备了高活性的Ir-La-S/AC催化剂, 评价了该系列催化剂的性能, 并进行了深入的表征. Ir-La-S/AC催化剂的TOF最高可达2760 h-1, 远远高于Ir-La/AC催化剂1000 h-1. HAADF-STEM的结果表明,Ir-La-S/AC催化剂中Ir物种绝大多数处于单分散状态, 而Ir-La/AC催化剂中的Ir物种为平均粒径为1.5 nm的纳米颗粒状态, 说明Ir-La-S/AC催化剂中Ir的使用效率要远远高于Ir-La/AC. 其次, NH3-TPD的结果显示在制备过程中硫酸的加入使催化剂的酸性位点大幅度增多, 而酸性位可以加速Ir体系机理中CO插入这一决速步骤. 目前普遍认为, Ir+物种为甲醇羰基化的活性中心, 故通过TPR和原位XPS测试证实了Ir-La-S/AC催化剂比Ir-La/AC中的Ir物种在通过CO/H2= 10:1混合气活化后更容易还原到Ir+, 而且这又说明在Ir-La-S/AC催化剂中更易发生Ir3+物种还原消除为Ir+物种且同时产生酰基碘(AcI)这一重要循环步骤. 所以Ir-La-S/AC催化剂具有更多的酸促进位点, 更高的Ir分散度和更多的Ir+活性物种. 此外, Ir-La-S/AC催化剂的羰基化活性在66 h之后才趋于稳定(1660 h-1), 通过XRF测试发现该过程中有少量的硫流失, 而大部分剩余的硫比较稳定的存在于催化剂表面, 且通过ICP-MS结果显示Ir和La没有明显的流失, 因此66 h之前活性下降主要是由于部分S的流失, 而不是金属物种Ir和La流失造成的. 总之, 我们成功地制备了一种硫促进的双功能Ir-La-S/AC催化剂, 这种方法不仅减轻了由液体酸带来的环境污染和设备腐蚀, 同时避免了液相铱体系催化剂的循环使用问题.     

多相催化体系的反应机理和失活模式(英文)

Solving the problem of catalyst deactivation is essential in process design. To do this, various aspects of the kinetics of processes with catalyst deactivation, and their different mechanisms, are discussed. Catalyst deactivation often cannot be avoided, but more knowledge on its mechanism can help to find kinetic means to reduce its harmful consequences. When deactivation is caused by coke, the generation of coke precursors is the determining step in the deactivation kinetics. Different types of deactivation were distinguished that lead to different evolution of the process. The phenomenon of non-uniform coking can be linked to catalyst surface non-uniformity. For the class of catalysts with more than one type of active sites, an explanation was suggested for the observed trends in the deactivation modes. For catalytic proc-esses using catalyst particles of industrial size, the influence of intraparticle diffusion resistance is important. The analysis showed that for a number of processes, the decrease of the reaction rate due to deactivation is less under diffusion control. For certain reaction mechanisms, there exist operation conditions where the rate of the process under diffusion control exceeds the rate in the kinetic control regime. A signifi-cant problem is the change of selectivity in the course of catalyst deactivation. The selectivity may either decrease or increase, and depends on the reaction mechanism during deactivation. The changes are larger when there is no diffusion resistance. The intentional poisoning of catalysts and its influence on catalyst activity and selectivity for the process of ethylene oxide production was discussed.     

New cohort of optically active nanostructure poly(amideimide)s: Production and properties

Novel aromatic-aliphatic poly(amide-imide)s containing chiral units in the main chain and hydroxyl benzamide units in the side chain have been obtained from the step-growth polymerization of 3,5-diamino-N-(4-hydroxyphenyl) benzamide(2) with different chiral diacid chlorides(1a-1e).Theoretical calculations were done by means of computational chemistry methods to narrate the stable conformation and orientation of each diacid chloride monomers under reaction conditions.These polymers were characterized by conventional techniques.The resulting polymers show good thermal stability.Other physical properties of polymers including crystallinity,inherent viscosity and morphological characteristics were also studied.     

HL-2A 装置 LHCD 系统灯丝电源远程控制的 一种新方法

为解决 HL-2A 装置低杂波电流驱动(LHCD)系统灯丝电源无法远程控制的问题,介绍了基于西门子 WinCC 监测系统的 HL-2A 装置 LHCD 系统灯丝电源 MSComm 串行通信系统的设计与实现。在 WinCC 图形编辑 器中直接调用 MSComm 控件,编写 VBS 全局脚本实现对串口的访问,解决了硬件组态过程中串行通讯操作被 WinCC 所限制的问题。采用了虚拟串口技术、工业以太网通讯技术、光纤隔离技术等,提高了 WinCC 组态串口 设备的灵活性。HL-2A 装置 LHCD 实验证明,在 HL-2A 装置放电的复杂电磁环境下,LHCD 灯丝电源 MSComm 串行通信系统运行稳定、功能完善。     

Enhanced hydrogen evolution from the face-sharing [RuO6] octahedral motif

Hampered by the ambiguous mechanism of hydrogen evolution reaction(HER)in basic media,the exploration of highly efficient catalytically active sites for alkaline HER is of significance.Herein,a metal oxide Sr₄Ru₂O₉engineering a face-sharing[RuO₆]octahedra motif was synthesized through the solid-state method,and served as HER electrocatalyst.Benefited from the Ru-Ru metallic bonding crossing the common plane,the H*adsorption and reaction energy barriers were optimized.Sr₄Ru₂O₉only required an ultra-small overpotential(η10)of 28 m V at a current density of 10 mA cm^-2 for HER in 1.0 M KOH with an exceptional stability(180 hours),outperforming the commercial Pt/C(η10=38 mV).These findings suggest a fresh insight in designing novel active sites for electrocatalysis.     

用VB实现有线电视网络监测系统的数据通信及存储

本文介绍了在VB6.0中,根据RS232通信协议,利用ActiveX控件MSComm通信控件,实现PC机与单片机的串行通信,同时利用ADO技术,达到有线电视网络监测系统中数据采集和存储的功能.     

用VB设计多媒体应用程序

探讨了用Visual Basic开发32位Windows多媒体应用程序的3种方法.一是利用API函数进行编程,实现多媒体应用;二是利用系统提供的控件(或组件)进行属性设置加代码编程调用;三是利用MCI接口,提供MCI驱动进行编程.并分别给出了一些应用实例.