Synthesis and characterisation of bis(pentafluorophenyl)antimony(V) cations, [(C6F5)2SbL3]

Pentacoordinate complex cations of the general formula [(C₆F₅)₂SbL₃]³⁺ stabilized as solid salts in combination with tetraphenylborate (BPh₄), tetrafluorobroate (BF₄) anions, where L=DMSO, Ph₃AsO, PyO, DMF, α-, β- and γ-picoline have been isolated. The newly formed complexes were characterized by elemental analysis, molar conductance measurements, solid-state IR and and NMR. From these results, a five-fold coordination around antimony was required.     

全球信息网WWW上的化学资源

文献查阅是化学工作者必须掌握的基本技能之一.随着计算机网络技术的迅速发展,利用全球信息网WWW浏览和获取化学信息已成为查阅化学文献最重要的方法之一.在化学工作者中普及万维网WWW查阅各类化学信息和获取化学资源的方法是非常重要的.作者简要叙述WWW的基本原理和通过WWW获取化学信息和化学资源的方法,并给出部分Internet化学资源.     

The regioselectivity of the formation of 2-pyrazolylthiazoles and their precursors from the reaction of 2-hydrazinothiazoles with 4,4,4-trifluoro-1-hetaryl-1,3-butanediones

Reaction of 2-hydrazinothiazoles 1 with 1-thienyl- and 1-furyl-1,3-butanediones 2a,b in methanol in the presence of hydrochloric acid mainly leads to a mixture of pyrazoles 3 and pyrazolines 4 or pyrazoles 3 and 5 in strong acidic conditions. Isomeric hydrazones 6 and pyrazolines 4 were formed and isolated in these reactions in the absence of hydrochloric acid. It has been shown that the regioselectivity in the reaction of diketones 2 with hydrazine 1 is governed by both the concentration of acid and the nature of substituents in the 1,3-diketones 2. Cyclization of hydrazones 6 is shown to occur under milder conditions than dehydration for pyrazolines 4. The new heterocyclic compounds were prepared and fully characterized by NMR spectra and by X-ray analysis for 3c.     

Molecular structure and spectral properties of thionaphthalimides

The molecular structure and absorption spectra of monothio- and dithio-naphthalimides were compared to their naphthalimide analogues using AM1, PM3 and ZINDO/S semiempirical quantum chemical methods. The substitution of the 4R-naphthalimide oxygen atoms by sulphur atoms resulted in a red-shift of the absorption spectra by Δλ_max60-65 and 100-140 nm, respectively. The thionated naphthalimide derivatives do not show observable fluorescence due to intersystem crossing to the triplet -states localised at the CS groups. The -absorption bands of monothioimides are located at 525-580 nm (ε=60-80) and those for dithioimides at 535-560 nm (ε=140-390) and 628-686 nm (ε=34-68). None of these transitions are solvent sensitive. The -transitions of N-phenylthioimides have also a small contribution from -states due to a partial conjugation between CS group and π-electronic system of the N-phenyl ring. As a result, the bands of aromatic substituted N-phenylthioimides are red-shifted as compared to those of the aliphatic N-methyl-thioimides.     

基于W eb和开源技术的“生产管理系统”的开发与应用

主要介绍了当今流行的W eb技术、面向对象的Java编程语言及一系列的开放源代码技术,并就美国一家公司的“生产管理系统”从原有的C/S结构移植到基于W eb的B/S结构的改造工程,论述了整个系统的移植过程,及其成功经验,最后总结了我们在进行企业信息化建设过程中可借鉴之处.     

基于B/S结构和ASP.NET技术的Web应用研究及实现

首先对ASP．NET技术的特点进行分析，然后对基于B／S结构和ASP．net技术的Web应用程序开发过程进行了探讨，最后给出了一个网络考试系统应用实例。     

基于Web的科研项目管理系统的设计与开发

研制了基于互联网的科研项目申报评审系统，采用C／S与B／S相结合的模式设计网上申报系统，Web方案设计专家评审系统实现了科研项目的网上申报、评审及管理等功能，较好地解决了Word文本和数据库的衔接问题，系统经有关管理部门和单位试用，效果良好，提高了科研管理水平和效率．     

基于Web的形成性考核智能管理系统研究

以远程开放教育中形成性考核工作的需要为中心，充分利用现代计算机技术、多媒体技术、通信技术、数据挖掘和人工智能等技术，充分利用现有管理系统中的数据，建立了基于WEB的形成性考核智能管理系统，实现了考核课程学生自主学习的智能引导、全过程监控、科学合理评价到形成性考核成绩的自动化。最大可能的发挥形成性考核对学生学习的促进作用。     

WEB数据挖掘研究与探讨

随着WWW迅猛发展,WWW上的信息量不断增加,如何在这些信息中找到用户真正需要的内容,成了数据组织和web相关领域的专家学者关注的焦点.为了解决这个问题,把数据挖掘的理论和技术应用于WWW,出现了一个新的研究领域-Web数据挖掘.主要介绍了Web数据挖掘的原理、应用、实现以及它的最近发展情况.