High sensitivity CW-cavity ring down spectroscopy of water in the region of the 1.5 μm atmospheric window

The absorption spectrum of natural water vapour around 1.5 μm has been recorded with a typical sensitivity of 5 × 10⁻¹⁰ cm⁻¹ by using a CW-cavity ring down spectroscopy set up based on fibred DFB lasers. A series of 31 DFB lasers has allowed a full coverage of the 6130.8-6748.5 cm⁻¹ (1.63-1.48 μm) region corresponding to the H transparency band of the atmosphere. The line parameters (wavenumber and intensity) of a total of 5190 lines, including 4247 lines of water vapor, were derived by a one by one fit of the lines to a Voigt profile. Different isotopologues of water (H₂¹⁶O, H₂¹⁸O, H₂¹⁷O, and HD¹⁶O) present in natural abundance in the sample contribute to the spectrum. For the main isotopologue, H₂¹⁶O, 2130 lines were measured with line intensities as weak as 10⁻²⁹ cm/molecule while only 926 lines (including a proportion of 30% inaccurate calculated lines) with a minimum intensity of 3 × 10⁻²⁷ cm/molecule are provided by the HITRAN and GEISA databases. Our comparison in the whole 5750-7965 cm⁻¹ region, has also evidenced that an error in the process of conversion of the intensity units from cm⁻²/atm to cm⁻¹/(molecule × cm⁻²) at 296 K, has led to H₂¹⁶O line intensities values listed in the HITRAN-2000 database, systematically 8 % below the original FTS values. The rovibrational assignment was performed on the basis of the ab initio calculations by Schwenke and Partridge with a subsequent refinement and validation using the Ritz combination principle together with all previously measured water transitions relevant to this study. This procedure allowed determining 172, 139, 71, and 115 new energy levels for the H₂¹⁶O, H₂¹⁸O, H₂¹⁷O, and HD¹⁶O isotopologues, respectively. The results are compared with the available databases and discussed in regard of previous investigations by Fourier transform spectroscopy. The spectrum analysis has showed that most of the transitions which cannot be assigned to water are very weak and are due to impurities such as carbon dioxide and ammonia, leaving only about 3% of the observed transitions unassigned. The interest of a detailed knowledge of water absorption for trace detectors developed in the 1.5 μm range is underlined: for instance HDO contributes significantly to the considered spectrum while no HDO line parameters are provided by the HITRAN database.     

用人本思想管理高校图书馆的人力资源

引入了管理学中的人本管理原则，阐述了人本思想和人本管理的内涵，并论述了运用人本管理思想管理图书馆人力资源的现实意义及其具体的实施办法。     

提高电脑建筑效果图制作效率的措施

对提高电脑效果图制作效率的重要性及常用方法进行了探讨，分析了制图效率低的原因，对合理配置计算机系统、优化计算机系统资源、熟练掌握软件使用技巧等进行了具体论述。     

需求特征对供应链中企业资源再利用的影响分析

为了了解需求因素对供应链中企业资源再利用的影响,选取工业园上下游企业的相互联系为分析背景,建立企业间的供应链模型,研究了需求不确定性σ和需求弹性k对供应链中企业资源再利用的影响.模型仿真结果表明:对存在物料供需关系的2个企业来说,随着主产品需求不确定性σ的不断增大,2个企业的总利润π呈不断下降的趋势,销售损失和库存成本增加,企业资源再利用受到阻碍;随着弹性因子k的不断增大,需求批量与供给批量差距呈现出一种先减小后增大的趋势,总利润π减小,对企业资源再利用起到了负面的影响,阻碍其发展.     

网络图书馆研究

介绍了网络图书馆的概念及其特征,阐述了网络图书馆的服务内容,分析了网络图书馆的运行模式和管理体制。     

论西藏传统艺术资源与其价值开发

文章从西藏艺术资源的界定、种类与分布、优势条件与独有地位、面临的问题与发展前景以及西藏传统艺术的精神资源与经济资源的开发几个方面客观地分析了艺术资源所具有的历史意义和现实意义,提出了我们如何认识本民族特有的传统艺术资源的价值和它在当前和今后本地区的两个文明建设方面应发挥的具体作用问题。     

从新视角透视企业竞争力的来源

在综述与评价国内外学者有关竞争力研究观点的基础上,分析了企业竞争力的来源,介绍了企业竞争力来源模型。     

Water wave radiation by a sphere submerged in water with an ice-cover

Using the multipoles method, we formulate the problems of radiation (both heave and sway) of water waves by a submerged sphere in deep as well as in uniform finite depth water with an ice-cover, with the ice-cover being modelled as an elastic plate of very small thickness. In each case this leads to an infinite system of linear equations which are solved numerically by standard techniques. The added-mass and damping coefficients for a heaving and swaying sphere are obtained and depicted graphically against the wave number for various values of the radius of the submerged sphere and flexural rigidity of the ice-cover to show the effect of the presence of ice-cover on these quantities. When the flexural rigidity is taken to be zero, the numerical results for the added-mass and damping coefficient for water with a free surface are recovered.     

An enantioselective Michael addition of malonate to nitroalkenes catalyzed by low loading demethylquinine salts in water

An enantioselective Michael addition of malonate to nitroalkenes is efficiently catalyzed by low loading demethylquinine salts in water; the yield range from 49% to 93% and the ee up to 90%.     

PARTIAL VERSUS GENERAL STORAGE POLICY: COMMODITIES AND RESOURCES

This paper examines joint storage considerations when both commodities and resources can be stored, e.g., grain and water for irrigation. Results suggest that when separate agencies control public resource and commodity storage, suboptimal storage rules occur unless (i) each agency is sensitive to the policies of the other, (ii) commodity inventories are adjusted in response to prices, and (iii) resource inventories are adjusted in response to both commodity demand and resource supply conditions. For example, the common case where water storage depends on weather and reservoir conditions alone is not sufficiently general. The results imply that water management agencies that tend to be dominated by engineers and hydrological considerations need to incorporate economic considerations into decision processes.