ChemInform Abstract: An ab initio Theoretical Study of the Electronic Structure of UO2+ and [UO2(CO3)3]5‐.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.     

Nilpotency of group ring units symmetric with respect to an involution

Let F be an infinite field of characteristic different from 2. Let G be a torsion group having an involution ∗, and consider the units of the group ring FG that are symmetric with respect to the induced involution. We classify the groups G such that these symmetric units satisfy a nilpotency identity (x₁,…,x_n)=1.     

Strong commutativity preserving maps in prime rings with involution

Let A be a prime ring of characteristic not 2, with center Z(A) and with involution *. Let S be the set of symmetric elements of A. Suppose that f:S→A is an additive map such that [f(x),f(y)]=[x,y] for all x,y∈S. Then unless A is an order in a 4-dimensional central simple algebra, there exists an additive map μ:S→Z(A) such that f(x)=x+μ(x) for all x∈S or f(x)=-x+μ(x) for all x∈S.     

Aus der Praxis Erste Ergebnisse zur On-line-Schnellextraktion mit Kronenethern bei kernchemischen Experimenten

Im Zusammenhang mit on-line-Bestrahlungsexperimenten har sich vor allem die He-Jet-Technik einen festen Platz erobert [1- 5], der nicht in Frage gestellt werden soll. Unge- uchtet dessen erseheint es zweekmäßig, ergänzend Techniken zu entwickeln, die ausschließlich auf Verwendung von flüsigen Phasen basieren. Das erlaubt es, die vielfältigen Möglichkeiten zu nutzen, welehe die Chemie in Lösungen für Trenn- und Anreicherungsaufgaben bietet. Dabei wird von der Grundannahme ausgegangen, daß bezüglich der Transportgeschwindigkeit die entsprechenden Parameter der Gas-Jet-Technik durch rein flüssige Varianten bestenfalls erreicht jedoch kaum übertroffen werden können. In der zur Verfügung stehenden Literatur wurde lediglich von Aronsson u. a. 1973 ein System beschrieben, wo in einer n, γ-Reaktion eine Lösung direkt bestrahlt wird [6], dieses findet sich jedoch in der späteren Literatur nicht wieder.

Die hier darzulegenden Ergebnisse stellen erste Experimente zur direkten Bestrablung einer Lösung mit beschleunigten Ionen dar. Sie sollen in letzter Konsequenz der Erarbeitung einer Experimentiervariante     

ChemInform Abstract: Density Functional Theory Calculations of UO2 Oxidation: Evolution of UO2‐x,U4O9‐y,U3O7, and U3O8.

DFT calculations of UO₂ oxidation indicate stable compounds U₄O_8.889, U₃O₇, and U₃O_7.333, which are based on ordering of split quad‐interstitial clusters.     

QCD as a topologically ordered system

We argue that QCD belongs to a topologically ordered phase similar to many well-known condensed matter systems with a gap such as topological insulators or superconductors. Our arguments are based on an analysis of the so-called “deformed QCD” which is a weakly coupled gauge theory, but nevertheless preserves all the crucial elements of strongly interacting QCD, including confinement, nontrivial θ$\theta$ dependence, degeneracy of the topological sectors, etc. Specifically, we construct the so-called topological “BF” action which reproduces the well known infrared features of the theory such as non-dispersive contribution to the topological susceptibility which cannot be associated with any propagating degrees of freedom. Furthermore, we interpret the well known resolution of the celebrated U(1)_A$\mathrm{<font\; color="red">U</font>}{\left(1\right)}_A$ problem where the would be η^′${\eta }^{\prime }$ Goldstone boson generates its mass as a result of mixing of the Goldstone field with a topological auxiliary field characterizing the system. We then identify the non-propagating auxiliary topological field of the BF formulation in deformed QCD with the Veneziano ghost (which plays the crucial role in resolution of the U(1)_A$\mathrm{<font\; color="red">U</font>}{\left(1\right)}_A$ problem). Finally, we elaborate on relation between “string-net” condensation in topologically ordered condensed matter systems and long range coherent configurations, the “skeletons”, studied in QCD lattice simulations.     

Range and energy-loss of 16.34 Mev/u 238U in kapton polyamide

Abstract

The range and energy-loss of 16.34 MeV/u ²³⁸U in Kapton-polyamide plastic have been measured by the nuclear track technique. The experimental ranges are compared with two sets of theoretical values. It has been observed that ranges obtained from the computer code ‘DEDXT’ are found to be 5–8% lower as compared to measured ones whereas those from Northcliffe and Schilling are about 10–15% overestimated above 8 MeV/u.     

ON PSEUDO-COMMUTATMTY AND COMMUTATIVITY IN RINGS

Abstract

A ring R is called pseudo-commutative if for each x,y ε R there exists an integer n = n(x, y) for which xy = nyx. We first show that a generalization of a commutativity condition of Chacron and Thierrin implies pseudo-commutativity in rings; we then study pseudo-commutativity and commutativity in rings with constraints of the form xy = σk_iyⁱxⁱ, where the k_i are integers.