Studies of mass and energy correlations in thermal neutron fission of U-235 accompanied by long range alpha particles

Several characteristics of fission accompanied by long range alpha particles (LRA) have been studied in the thermal neutron induced fission of²³⁵U. The kinetic energies of fission fragments and the LRA were measured with a back-to-back ionization chamber and semiconductor detectors respectively. The kinetic energies of the two fragments and the LRA in LRA fission, along with the energies of pair fragments in the normal binary fissions, were recorded event by event on a magnetic tape by means of a four-parameter data acquisition system. The data were analysed to study the dependence of different quantities in LRA fission on the fragment mass ratio, LRA energy and the total kinetic energy of the fission fragments. It is seen that the most probable energy of LRA increases significantly for near symmetric mass divisions. The total kinetic energy for all mass ratios in LRA fission is found to be (2.6±0.7) MeV larger than that in binary fission. The difference in the total kinetic energies in LRA and binary fissions is seen to be dependent on mass ratio. This result may suggest that the scission configuration in LRA fission is different for different mass ratios. Correlations between the fission fragment and LRA energies have been studied for several mass ratios. It is seen that the most probable fragment kinetic energyĒ _k varies nearly linearly with the LRA energyE _a for various mass divisions but the variation of the most probable LRA energyĒ _a with fragment kinetic energyE _k is found to deviate from linearity for several mass ratios. From a least square fit to the variation ofĒ _k withE _a it is found that the slope (dĒ _k/dE_a) increases with the increase in mass ratio. The present results are discussed to arrive at a better understanding of the scission configuration in the fission accompanied by LRA emission.     

S42+ and S42− : an ab initio study

The structures of S₄²⁺ and S₄^2? have been investigated by ab initio calculations using the GAUSSIAN 70 system of programs and the 44-31G basis set. Electronic singlet states of the square form and three possible conformations of the chain structure were examined for both ions, and the singlet rectangle form of S₄^2? was also investigated. The anti chain form of S₄²⁺ was found to be 78.3 kJ mol^? more stable than the square form, in contrast to previous experimental data. S₄^2?is predicted to adopt the chain structure with the anti conformation.     

The quantum Sturm-Liouville equation,quantum resolvent,quantum integrals,and quantum KdV: The fast decrease case

We construct quantum operators solving the quantum versions of the Sturm-Liouville equation and the resolvent equation, and show the existence of conserved currents. The construction depends on the following input data: the basic quantum field O(k) and the regularization.     

2＋1维U（1）格点规范理论的相图

应用单元格试探作用量变分法研究2 1维U(1)格点规范场的相图。解析地计算出序参量——平均元格能量,与MC方法所得结果符合很好。证实2 1维U(1)格点规范理论是禁闭的。消除了以往文献中用单链试探作用量变分法出现的不正确的一级相变点,还可以很方便地计算到比MC方法的β更大的深度弱耦合区。     

与岩浆有关热液矿床的矿体赋存部位

结合实际工作中的体会，探讨了与岩浆有关的热液矿床矿体赋存部位与岩浆岩类型、矿种类型及构造开放条件的关系，并运用连通器原理，解释了一些矿田中常见的矿体等高性的成因。     

Particulates formed by a stabilized high voltage spark discharge

Light scattering was used to demonstrate the presence of small (?1 μm) particles in the immediate surroundings of a stable spark discharge. Several parameters, including electrode composition and surface condition, which are of importance in emission spectrochemical analysis, were found to be of importance in affecting the scattering signal. Electron micrographs of the heaviest particles revealed two distinct types of particles. Analytical implications are discussed.     

An unusual reaction of terramycin with methyl iodide

An unusual fragmentation reaction was observed when terramycin is treated with MeI in acetone at room temp. The reaction proceeds with quaternization, loss of trimethylamine, fission of bonds 4a,5 and 12,12a with formation of an aldehydo-lactone derived from rings B, C and D. Additionally some transformations of this lactone are described.     

Integrated microfluidic devices with enhanced separation performance: application to phosphoproteome analyses of differentiated cell model systems

This work reports on the application of a microfluidic device integrating nanoscale LC to nanoelectrospray MS (nano-LC-chip-MS) for the analysis of complex protein digests. Peak profile analyses of more than 700 peptide ions, reproducibly detected across replicate nano-LC-chip-MS runs (n = 5), indicated that the system provided RSD values of 0.24% on retention time, +/- 30 ppm on m/z measurement and +/- 30% variation on intensity over three orders of magnitude. RP adsorbant media with different alkyl chains and particle size packed in both trapping and separation channels were investigated to improve the chromatographic performance of this system. A two-fold improvement in chromatographic peak capacity was achieved using microfluidic devices comprising a 5 mircrom C3 trap with 2.5 microm C18 trap separation channel compared to the traditional 5 microm C18 stationary phase. Enhanced sample selectivity for the identification of phosphopeptides was obtained by combining immobilized metal affinity media prior to peptide separation on the RP microfluidic device. This system was evaluated in the context of differential phosphoproteome analyses to identify changes in signaling events and protein expression of human monocytes following the administration of phorbol ester.     

基于虚拟磁盘的保密U盘

目前主流品牌的保密U盘均采用硬件加密的方式,安全级别较高,数据加密速度快,应用也比较简单。但由于硬件加密的实现需要用到价位较高的专用芯片,使得这种类型的产品价格也比较昂贵。本文提出一种基于虚拟磁盘的保密U盘实现方案,该方案具有成本低、高效、实用等特点。