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101.
Jean-Pierre Bouanich Ghislain Blanquet Muriel Lepère 《Journal of Molecular Spectroscopy》2004,227(2):172-179
H2-broadening coefficients have been measured for 35 lines of C2H4 at 173.2 K in the P, Q, and R branches of the ν7 fundamental band near 10 μm, using a tunable diode-laser spectrometer. These lines were individually fitted with a Voigt and a Rautian profile to determine their collisional widths. The resulting broadening coefficients, as well as those previously measured at room temperature are compared with values calculated on the basis of a semiclassical model of interacting linear molecules, using an atom-atom Lennard-Jones potential in addition to the weak electrostatic contributions. A satisfactory agreement is obtained for the results at room temperature, but the theoretical results at low temperature are generally smaller than the experimental data. Finally, the temperature dependence of the broadening coefficients has been determined both experimentally and theoretically. 相似文献
102.
Félicité Misago Jacques Walrand Ghislain Blanquet 《Journal of Molecular Spectroscopy》2006,237(1):46-52
Using a tunable diode-laser spectrometer, N2-broadening coefficients have been measured for 15 lines in the ν3 band of C32S2 at room and low temperatures (298, 273.2, 248.2, 223.2, and 198.2 K). These lines with J values ranging from 2 to 62 are located in the spectral range 1519-1545 cm−1. The collisional widths are obtained by fitting each measured spectral line with a Voigt and a Rautian lineshape model and for a few lines we also used a Galatry model. From these results, we have determined the n parameter of the temperature dependence of each broadening coefficient. A semiclassical calculation of these broadenings has been performed by considering in addition to the main electrostatic quadrupole-quadrupole interaction an anisotropic dispersion contribution leading to satisfactory results at all temperatures and providing the n temperature dependence parameter in good agreement with the experimental determination. 相似文献
103.
Luca Spani Molella Rolf-Hermann Rinkleff Karsten Danzmann 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,63(5):987
The optical properties of a caesium atomic beam driven on a resonant hyperfine transition in the D2 line were studied as a function of the probe laser frequency. Using a third off-resonant laser system, a heterodyne interferometer allowed simultaneous absorption and phase shift measurements of either the probe or the coupling laser. The signal features of the probe and coupling laser transmitted intensities showed strong differences in the vicinity of the hyperfine transitions excited by the probe laser. Regular absorption signals and electromagnetically induced transparency were found in either transmitted intensities. Furthermore, light induced birefringence of the probe laser was measured. 相似文献
104.
Design and analysis of thermally tunable liquid crystal filled hybrid photonic crystal fiber coupler
We propose a novel tunable photonic crystal fiber (PCF) coupler scheme, that the light is coupled between a total internal reflection (TIR) guiding core and a photonic bandgap (PBG) guiding core. By introducing the thermo-optic responsive nematic liquid crystals (NLC) into the air holes around the PBG core, the hybrid PCF based coupler exhibits enhanced thermal tunability. The thermo-optical characteristics of the proposed coupler are numerically studied using finite element method (FEM) and beam propagation method (BPM). The proposed design can find promising applications in filtering and sensing devices. 相似文献
105.
This paper demontrates a novel configuration of a linear cavity erbium-doped fiber laser using fiber loop mirrors to effectively suppress the noise generated by the amplified spontaneous emission (ASE). A tunable filter is deployed in each fiber loop mirror to create a narrow passband for the selected mode. The fiber laser produces high background suppression ratio (BSR) of more than 75 dB from 1525 to 1565 nm at the output coupling of 95%. There is no residual ASE detected at the output to verify the effectiveness of the noise filtering in the proposed fiber laser. Low threshold powers are obtained in the range of 2.5–3 mW and the peak power variation is smaller than 1.6 dB. 相似文献
106.
107.
1 Introduction Allopticalwavelengthconverters,thattransforminformationononewavelengthtoanother,willbeimportantinfutureopticalswitchesandwavelengthmultiplexednetworks.Therearethreekindsofwavelengthconverters:wave mixing ,opticalgatingandlaserconverter[1~ 3… 相似文献
108.
《应用光谱学评论》2013,48(4):395-432
Abstract The need for higher sensitive detection technology for trace gas samples, either in the laboratory setup or in the atmospheric remote sensing has been a goal for several decades. The development of the tunable diode laser has propelled the progress of trace detection technology, and modulation technology enables the improvement of the detection sensitivity. As a result, the detection of 10?7 or 10?8 absorbance is possible for some applications, and modulation technology has been applied to the ultraviolet as well as mid-infra red wavelength range. In this review, recent progress of tunable diode lasers and diode laser-based modulation technologies are presented. Wavelength modulation, frequency modulation, and two-tone frequency modulation techniques are mainly described along with the actual application of the techniques. In addition, the state-of-the-art of diode laser development which can be adopted for the trace detection is presented. 相似文献
109.
基于HITRAN光谱数据库的TDLAS直接吸收信号仿真研究 总被引:1,自引:0,他引:1
对TDLAS直接吸收信号进行仿真研究, 能够充分了解TDLAS直接吸收的过程以及各个物理参量的变化对吸收信号的影响。首先全面研究分析了TDLAS直接吸收方法的理论基础及算法, 给出了基于朗伯-比尔定率的气体吸收线强、吸收截面、浓度、线型函数以及气体总体配分函数等参量的表达式及计算步骤。基于HITRAN光谱数据库, 利用MATLAB程序对TDLAS直接吸收过程进行了仿真, 计算得到了一定温度、压力、浓度等条件下的吸收谱数据。以H2O为研究对象, 仿真了其在各个线型下的吸收谱, 并与商用软件Hitran-PC的结果进行比较, 结果显示两者在Lorentz线型下的最大误差小于0.5%, 在Gauss线型下的最大误差小于2.5%, 在Voigt线型下的最大误差小于1%, 因此验证了仿真算法及结果的正确性。还对不同压力和温度下ν2+ν3谱带H2O的吸收谱进行了仿真, 研究了吸收谱随压力和温度变化规律。在低压范围, 多普勒展宽占主导, 线宽随压力变化很小, 而幅度随压力增大而增大, 在高压范围, 碰撞展宽占主导, 线宽随压力增大而增大, 而幅度则随压力增大而趋于定值。最后还给出了大气环境温度范围内的温度修正曲线。该研究可以为TDLAS直接吸收方法的实际应用提供理论参考和指导。 相似文献
110.
A. Lucchesini S. Gozzini 《Journal of Quantitative Spectroscopy & Radiative Transfer》2011,112(9):1438-1442
A tunable diode laser spectrometer has been employed to examine the 3rd overtone absorption lines of C2H4 at around 12 000 cm−1 (830 nm). The spectrometer sources are heterostructure AlGaAs tunable diode lasers operating “free-running”. By the aid of the wavelength modulation spectroscopy with the second harmonic detection technique and a Herriott type multipass cell 63 very weak absorption lines have been observed for the first time, with cross sections as low as 2 × 10−26 cm2/mol, equivalent to . The self-broadening coefficient has been measured for one of the most intense lines. 相似文献