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11.
本文对丁基罗丹明B、罗丹明6G和四溴荧光素在萃取光度法和浮选光度法中的应用做了综述。参考文献44篇。 相似文献
12.
A new solid substrate-room temperature phosphorimetry method for the determination of trace mercury has been established. It bases on the fact that in acetic acid medium, Hg2+ ion can catalyze the substitute reaction of CN− ligand in [Fe(CN)6]4− by 2,2′-bipyridyl (bipy), and the resultant [Fe(bipy)3]2+ cation can react with FinBr4− anion of tetrabromofluorescein (HFinBr4) to form ion association complex [Fe(bipy)3]2+[(FinBr4)2]2− which can emit phosphorescent signal on filter paper substrate. Under the optimum condition, the linear dynamic range of this method is 1.6-16 fg per spot with a detection limit (LD) of 0.18 fg per spot (0.4 μl sample solution per spot), and the regression equation of working curve is ΔIp=1.058+7.671 CHg2+ (fg per spot ), n=7, correlation coefficient is 0.9990. This method has been applied to the determination of trace mercury in hair and cigarette samples with satisfactory result. The reaction mechanism for formation of the ion association complex is also discussed. 相似文献
13.
本对四溴荧光素、丁基罗丹明B各自的吸光性质以及它们的形成的离子缔合物的吸光性质进行了研究。测得四溴荧光素与丁基罗丹明B在pH7时的缔合比为1:2。其Ksp=2.16×10^-18。缔合物的萃取率为83.2%。为进一步研究四溴荧光素、丁基罗丹明B的萃取光度分析奠定了理论基础。 相似文献
14.
罗丹明6G·四溴荧光素等色染料离子对浮选光度法测定金 总被引:3,自引:0,他引:3
提出了等色染料离子对浮选光度法。向罗丹明6G(R6G)和AuBr-4的甲苯萃取物R6GAuBr4中,加入pH=55的(NH4Ac-HAc)缓冲溶液,使R6G离子进入水相,并向其中加入与R6G颜色相同的四溴荧光素(TBF),形成等色染料离子对R6G+·TBF-被甲苯浮选。将浮选物溶于丙酮,于530nm处光度测定。由于2个染料分子(Au∶R6G∶TBF=1∶1∶1)同时吸光,方法具有很高的灵敏度,ε=20×105L·mol-1·cm-1;金含量在0~036mg/L服从比耳定律,相对标准偏差为29%,方法应用于粗铜中金的测定,结果满意。 相似文献