PHASE INVERSION AND ITS MECHANICAL MODEL STUDIES FOR THE TWO-PHASE POLYMER BLEND SYSTEMS (Ⅱ)——DYNAMIC VISCOELASTIC RESPONSE

The dynamic viscoelastic response of the two-phase polymer blend systems shows the characteristics of the thermorheologically complex materials. In this paper theoretical equations for describing the dynamic viscoelastic response of such polymer blend systems have been established by means of the mechanical modeling technique. The dynamic viscoelastic response of the blend systems at any blend composition can be predicted theoretically by using the equations established, provided that the dynamic viscoelastic response of the two pure components and the mechanical model parameters are known in advance. Thus, we provide an effective method for studying the dynamic mechanical properties and the molecular relaxation characteristics of the two-phase polymer blend systems.     

Reliable evaluation of temperature-independent parameters in correlation of vapour–liquid equilibrium data

A new algorithm/program has been elaborated for simultaneous processing of different sets of vapour–liquid equilibrium data. The program was tested with six binary hexane + isomeric pentanol systems, each of them measured at three different isobaric conditions and one isothermal system of tert-butyl-methyl-ether + 2-methyl-2-propanol measured at three different temperatures. The correlation uses the maximum likelihood method, taking into account real behaviour of vapour phase. The parameters obtained are valid within the whole temperature range of the data, and are consistent in comparison with those obtained from individual correlations of isobars or isotherms. Results are presented for the Wilson and NRTL equations.     

低电流密度下恒电流法制备的聚苯胺修饰电极

研究了低电流密度下恒电流法制备的聚苯（ＰＡ）修饰电极的性质及其影响因素，探讨了低电流密度聚合的ＰＡ膜的优点。发现此种条件下聚合的ＰＡ膜具有较好的电荷传输能力，它不仅对Ｂｒ＾－，Ｔｌ＾＋／Ｔｌ等电对的氧化还原反应有更好的电催化活性，而且对Ｈ＾＋的Ｎｅｒｎａｓｔ响应也更接近理论值。     

担载型铂催化剂上甲烷活化的TPSR研究

用程序升温表面反应手段，系统地考察了甲烷在Ｐｔ催化剂上的吸附活化特征及甲烷分解后产生的表面碳物种。结果表明，ＣＨ４确能在ＳｉＯ２担载型Ｐｔ催化剂表面发生解离吸附，生成复杂的碳物种。这些碳物种间可发生相互转化。     

高分子基PTC复合材料的研究及其应用

本文概述了高分子基PTC复合材料最近的研究动态，阐述了其作为热敏材料在自控温加热系统和过流保护元件方面的广泛应用。     

钢坯磨削温度的若干试验研究

通过使用“可磨式”人工热电偶进行的不同条件下的磨削温度测量试验研究了钢坯磨削工件表层温度,结果表明钢坯被磨削表层温度分布与热强呈三角形分布时的理论分析结果相同,表层峰值温度随磨削压力及磨削功率增大而提高,且随工件进给速度提高而略有降低,峰值温度还随磨削角度减小而提高,90°磨削的峰值温度比0°磨削要低250℃左右,砂轮种类也对峰值温度有重要影响,使用锆刚玉砂轮时磨削温度低于棕刚玉砂轮,试验结果表明高效钢坯磨削的磨削区温度远比普通磨削为高,可达1200℃左右,还从不同方面探讨了磨削高温对钢坯磨削的影响,认为尽管磨削高温有若干不利影响,但对高效钢坯磨削却是重要条件,上述讨论,从一个方面揭示了钢坯磨削机理,并验证了关于钢坯磨削温度的理论分析结果。     

Three-way-output response system by electric potential: UV-vis, CD, and fluorescence spectral changes upon electrolysis of the chiral ester of tetracyanoanthraquinodimethane

The newly prepared tetracyanoanthraquinodimethane (TCNAQ) derivatives 1a,b with a chiral auxiliary are good electron acceptors and exhibit weak circular dichroism (CD) based on the absorption of TCNAQ. The twin-type electron acceptor 1c with two TCNAQ units shows larger ellipticity by exciton coupling. UV-vis, CD, and fluorescence spectra were changed drastically upon electrochemical reduction of 1c, which demonstrates the unprecedented three-way-output response system.