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41.
A convenient route to new 3-quinolinonyl-pyrazoles and isoxazoles is described through cyclization of 3-[(E)-3-(dimethylamino)-2-propenoyl]-4-hydroxy-1-methyl-2(1H)-quinolinone. The phototoxicity as well as the cytotoxic activities of the title compounds are evaluated against leukemia- and adenocarcinoma-derived cell lines in comparison to the normal human keratinocytes. 相似文献
42.
43.
本文通过对比实验,指出新型减噪阻尼环的减噪性能大大优于钢阻尼环,尤其在抗冲击方面。并引入“松动“的概念对新型阻尼环的减噪机理进行了探讨. 相似文献
44.
We consider the decay rate of energy of the 1D damped original nonlinear wave equation. We first construct a new energy function. Then, employing the perturbed energy method and the generalized Young’s inequality, we prove that, with a general growth assumption on the nonlinear damping force near the origin, the decay rate of energy is governed by a dissipative ordinary differential equation. This allows us to recover the classical exponential, polynomial, or logarithmic decay rate for the linear, polynomial or exponentially degenerating damping force near the origin, respectively. Unlike the linear wave equation, the exponential decay rate constant depends on the initial data, due to the nonlinearity. 相似文献
45.
A mathematical method to solve structural problems, using parameter-transfer finite elements (P-TFE) was recently proposed by the authors [1] [2] [3]. The proposed transfer finite element approach is able to create a mathematical model of a structure, taking into account directly the whole behaviour of the structure under dynamic, aerodynamic, and thermal actions, and not by assembling, in a separate fashion, the stiffness and the mass matrix on one side and the external load vector as performed by the classical finite element procedure.The purpose of this paper is to apply the above methodology to optimization problems, in particular to obtain the minimum structural weight for a beam, under primary constraints on buckling load or natural frequencies.The use of P-TFE in the field of structural optimization overcomes most difficulties of the usual techniques of solution and the element is particularly useful in the evaluation of the sensitivity matrix.The formulation of the optimization problem based on P-TFE is presented and some applications are studied. The numerical results obtained are compared with other existing methodologies and briefly discussed.
List of Symbols {B} m vector of the generalized state variables - {C} m vector of integration constants - [I] unit matrix - EI bending stiffness - A cross-sectional area - u adimensional thickness - l beam length - M,M bending moment - [N] m shape function ofm-th order - [N*] shape function atx 0 - P axial load - [R] i transfer matrix of thei-th element - T,T shear force - w transverse displacement - x adimensional independent variable - x 0 value ofx at the left of the element - {Y} vector of state variables - {Y*} imposed condition atx 0 - 0m Kronecker delta with the first pedix always set equal to zero - normalized eigenfrequency - normalized buckling load - mass density 相似文献
Sommario Gli autori hanno già proposto un metodo per studiare problemi strutturali [1] [2] [3], introducendo una nuova metodologia di discretizzazione, basata sull'impiego di elementi finiti di trasferimento, funzioni esplicite di un parametro, indicati come P-TFE. Tali elementi sono in grado di rappresentare, in similitudine alla funzione di trasferimento, il comportamento completo dell'elemento strutturale in esame, soggetto ad azioni dinamiche, aerodinamiche e termiche; sono parimenti in grado di produrre, in similitudine al metodo degli elementi finiti, un modello matematico discreto di un continuo.Scopo del presente lavoro è di applicare detta metodologia a problemi di ottimizzazione, in particolare alla ricerca del minimo peso per una trave che mantenga inalterate le sue caratteristiche di carico critico o le frequenze naturali di vibrazione.Vengono quindi presentati alcuni risultati numerici dei casi esaminati e confrontati con quelli ottenuti da altri autori con l'impiego di altre metodologie.
List of Symbols {B} m vector of the generalized state variables - {C} m vector of integration constants - [I] unit matrix - EI bending stiffness - A cross-sectional area - u adimensional thickness - l beam length - M,M bending moment - [N] m shape function ofm-th order - [N*] shape function atx 0 - P axial load - [R] i transfer matrix of thei-th element - T,T shear force - w transverse displacement - x adimensional independent variable - x 0 value ofx at the left of the element - {Y} vector of state variables - {Y*} imposed condition atx 0 - 0m Kronecker delta with the first pedix always set equal to zero - normalized eigenfrequency - normalized buckling load - mass density 相似文献
46.
L. Hatvani 《Proceedings of the American Mathematical Society》1996,124(2):415-422
The equation is considered under the assumption . It is proved that is sufficient for the asymptotic stability of , and is best possible here. This will be a consequence of a general result on the intermittent damping, which means that is controlled only on a sequence of non-overlapping intervals.
47.
Min Hsien Liu 《中国化学会会志》2007,54(1):141-148
Density functional theory (DFT) calculations are made and least squares calibration performed for various halohydrocabons, which were 27 straight‐chain alkyl halides, 20 branch‐chain alkyl halides and 19 aromatic halides, to determine their enthalpies of formation (ΔHf). The mean absolute error (M. |A.E.|) in ΔHf across 66 molecular computations was only 7.8 kJ/mol (1.9 kcal/mol). Grouping the molecules by their structural characteristics improved M. |A.E.| of ΔHf by 0.2–2.2 kJ/mol over that obtained using corresponding modified data for the same 66 unclassified molecules. 相似文献
48.
The structure and the relative stability of isomers of molecules X2H2F2 (X=Si, Ge, Sn) have been studied using the density functional theory (DFT). We have determined the optimised structures of the substituted isomers. The XX bond have been studied and compared to that of the parent molecules: X2H4. It appears that, for the planar and trans ethylenic systems, the double bond character of the XX decreases when the hydrogen atoms are substituted by fluorine atoms. The most stable structure is shown to be the one where the two fluorine atoms are fixed on the same atom. The bridged structures are also studied. 相似文献
49.
利用EHMO方法,对n=5~12的完整多面体硼烷骨架、缺一个和两个顶点以及戴一个和两个帽原子的各种异构体进行了量子化学计算。直接对硼烷的价成键轨道数公式BMO=4n-[f+3(s+1)]进行了验证。在对计算结果讨论的基础上,进一步探讨了骨架几何结构与成键轨道数之间的关系。 相似文献
50.
利用溶胶-凝胶分配理论对氢键溶液的模型体系进行研究, 给出了体系的凝胶化条件以及凝胶点后氢键网络中各类结构参数的计算方案, 并进行了相应的数值计算. 结果表明, 当两类质子受体基团的活性不同时, 质子受体基团的竞争作用对网络结构有一定影响. 这为控制氢键网络结构特征提供了可能的理论线索. 相似文献