首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   93787篇
  免费   4192篇
  国内免费   4659篇
化学   19818篇
晶体学   391篇
力学   3759篇
综合类   501篇
数学   10475篇
物理学   19363篇
综合类   48331篇
  2024年   193篇
  2023年   716篇
  2022年   1412篇
  2021年   1551篇
  2020年   1574篇
  2019年   1554篇
  2018年   1395篇
  2017年   1627篇
  2016年   1847篇
  2015年   2101篇
  2014年   4048篇
  2013年   4777篇
  2012年   4740篇
  2011年   5189篇
  2010年   4137篇
  2009年   5427篇
  2008年   5712篇
  2007年   6784篇
  2006年   6002篇
  2005年   4993篇
  2004年   4330篇
  2003年   4394篇
  2002年   4562篇
  2001年   3562篇
  2000年   3102篇
  1999年   2544篇
  1998年   2194篇
  1997年   1527篇
  1996年   1421篇
  1995年   1254篇
  1994年   1206篇
  1993年   925篇
  1992年   975篇
  1991年   737篇
  1990年   651篇
  1989年   560篇
  1988年   462篇
  1987年   389篇
  1986年   298篇
  1985年   242篇
  1984年   233篇
  1983年   139篇
  1982年   190篇
  1981年   183篇
  1980年   122篇
  1979年   150篇
  1978年   127篇
  1977年   118篇
  1976年   74篇
  1973年   58篇
排序方式: 共有10000条查询结果,搜索用时 156 毫秒
991.
We study notions of nondegeneracy and several levels of increasing degeneracy from the perspective of the local behavior of a local solution of a nonlinear program when problem parameters are slightly perturbed. Ideal nondegeneracy at a local minimizer is taken to mean satisfaction of second order sufficient conditions, linear independence and strict complimentary slackness. Following a brief exploration of the relationship of these conditions with the classical definition of nondegeneracy in linear programming, we recall a number of optimality and regularity conditions used to attempt to resolve degeneracy and survey results of Fiacco, McCormick, Robinson, Kojima, Gauvin and Janin, Shapiro, Kyparisis and Liu. This overview may be viewed as a structured survey of sensitivity and stability results: the focus is on progressive levels of degeneracy. We note connections of nondegeneracy with the convergence of algorithms and observe the striking parallel between the effects of nondegeneracy and degeneracy on optimality conditions, stability analysis and algorithmic convergence behavior. Although our orientation here is primarily interpretive and noncritical, we conclude that more effort is needed to unify optimality, stability and convergence theory and more results are needed in all three areas for radically degenerate problems.Research supported by National Science Foundation Grant ECS 90-00560 and Grant N00014-89-J-1537 Office of Naval Research  相似文献   
992.
对龙虾叶状幼体弧菌病采用多项措施,多种药物防治对比试验研究,总结出用沙-活性炭过滤海水,减少水体病原菌量,用漂白粉消毒水池和用具,杜绝污染源,用土毒素药浴亲虾,避免病原菌由卵带入,选用体格健壮的中年亲虾,保证孵化出的叶状幼体有旺盛的生命力,投放光合细菌、金藻、扁藻、丰年虫幼体、文蛤肉喂叶状幼体,改善叶状幼体营养,增强叶状幼体抗病力,利用光合细菌加速培育水体中有机物分解,净化水质,恶化病原菌生存环境  相似文献   
993.
Summary Complete Active-Space Self-Consistent-Field (CAS-SCF) calculations for cubic N8 are presented. We studied the N8↔4N2 reaction inD 4h symmetry and found its energy release and activation barrier with three different atomic basis sets. The energy release for this reaction is predicted to be around 526 kcal/mol, while the energy barrier to dissociation is estimated about 159 kcal/mol. These results are in substantial agreement with previousab initio estimates. The authors of this paper have agreed to not receive the proofs for correction.  相似文献   
994.
饱和水蒸汽与水的焓与熵参数的新关联式李斯特,马润梅,吴冷(北京化工大学机械工程系北京100029)关键词统计力学,剩余函数,焓与熵1引言本文根据统计力学与热力学剩余函数原理,结合本课题组曾已建立的饱和水蒸汽与水的新简明状态方程模型,经推导出一则适合于...  相似文献   
995.
Aqueous micellar solutions of ionic/neutral block copolymers have been studied by light scattering, small angle neutron scattering and small angle X-ray scattering. We made use of a polymer comprised of a short hydrophobic block (polyethylene-propylene) PEP and of a long polyelectrolytic block (polystyrene-sulfonate) PSSNa which has been shown previously to micellize in water. The apparent polydispersity of these micelles is studied in detail, showing the existence of a few large aggregates coexisting with the population of micelles. Solutions of micelles are found to order above some threshold in polymer concentration. The order is liquid-like, as demonstrated by the evolution with concentration of the peak observed in the structure factor (), and the degree of order is found to be identical over a large range of concentrations (up to 20 wt%). Consistent values of the aggregation number of the micelles are found by independent methods. The effect of salt addition on the order is found to be weak. Received: 19 June 1997 / Received in final form: 4 September 1997 / Accepted: 9 October 1997  相似文献   
996.
The reactions of phosphine derivatives of diallyl isocyanurates with palladium(ii) dichloride lead to the formation of complexes, whose structure, composition, and stability depend on the length of the methylene chain between the isocyanurate and diphenylphosphine fragments in the ligand. 1,3-Diallyl-5-[5′-(diphenylphosphino)pentyl and 10′-(diphenyl-phosphino)decyl] isocyanurates with PdCl2 form monomeric L2PdCl2 trans-complexes in which P atoms of the ligands participate in coordination with the metal. 1,3-Diallyl-5-[2′-(diphenylphosphino)ethyl] isocyanurate with PdCl2 forms a dimeric (LPdCl2)2 complex, which decomposes in a solution to the monomer including solvent molecule into the coordination sphere of the metal. The reactions of 1,3-diallyl-5-[4′-(diphenylphosphino)butyl] isocyanurate and 1,3-diallyl-5-[6′-(diphenylphosphino)hexyl] isocyanurate with PdCl2 give monomeric chelate LPdCl2 complexes in which one of the allyl groups of the isocyanurate cycle participates in coordination with the central ion along with the phosphorus atom. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1859–1865, September, 1998.  相似文献   
997.
油田产出污水是在油气钻井、开采、处理过程中必然的伴生物,也是石油工业中对环境造成危害的一大污染源。本文从综合治理、合理利用油田污水的角度出发,探讨了对油田污水应用环境控制技术,以治标和治本相结合,从石油工程的工艺本身和改进工艺过程减少油田污水的产出量和提高油田污水的回注利用率,从而显著改进环境质量,充分利用水资源的可能性,也讨论了当前在油田污水治理和回注利用方面应加强研究的几个问题。  相似文献   
998.
本文就科技英语和科技俄语的虚拟语气进行了简要对比。  相似文献   
999.
 利用高温高压方法合成了有稀土元素La掺杂的钙钛矿氧化物Sr1-xLaxTiO3。XRD测试表明,在x≤0.5时,样品基本为单相,呈立方相;晶胞体积随x的增加而增加,在x=0.4时开始减小。XPS测量发现,样品中存在Ti离子的变价。讨论了Ti离子价态的变化对晶格参数的影响。  相似文献   
1000.
We introduce a new class of experiments which provide graphic insights into the propagation of acoustic waves in anisotropic media. Simply stated, we have devised a means of observing the expanding acoustic wavefront from a point disturbance in a solid. The data may be viewed as a movie or a series of snapshots. The observed wavefronts represent the group-velocity surfaces of acoustic waves, which reflect the basic elastic anisotropy of the solid. The technique has been applied to coherent acoustic waves with frequencies in the megahertz range (at ambient temperatures) and to incoherent heat pulses in the hundred-gigahertz range (at liquid-helium temperatures). In this article, we first provide a pedagogical introduction to wave propagation in elastically anisotropic media, reviewing some early methods for visualizing acoustic waves. Next, we describe the “acoustic wavefront imaging” method and give representative results in crystals and composite materials. Finally, we show how this method relates to recent advances in phonon imaging and internal diffraction of ultrasound.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号