Vinyl‐type polymerization of norbornene by nickel(II) bisbenzimidazole catalysts

Novel nickel(II) bisbenzimidazole complexes were prepared via a three‐step synthetic procedure consisting of aniline/diacid condensation, ligand N‐alkylation, and metal complexation. The complexes were characterized by X‐ray crystallography and found to possess a pseudotetrahedral geometry. Upon activation with methylaluminoxane, these nickel bisbenzimidazoles did not polymerize simple olefins (e.g., ethylene, propylene, and 1‐butene) but were found to carry out the rapid and efficient polymerization of norbornene. The polynorbornene products were characterized by gel permeation chromatography/light scattering, ¹³C NMR, and IR, and their Mark–Houwink and dn/dc parameters were determined. The molecular weights of the polynorbornenes were very high (weight‐average molecular weight = 587,000–797,000 g/mol). ¹³C NMR suggested that the polymerization occurred via vinyl addition (i.e., a 2,3‐linked polymer); no ring‐opened product was observed. Thermogravimetric analysis indicated that the polynorbornenes were stable up to 400 °C under nitrogen. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2095–2106, 2003     

Accelerated glycosylation under frozen conditions

O-Glycosylations using thiomethyl glycosides as donors were compared under both frozen and unfrozen conditions. In the presence of MeOTf as a promoter, enormous rate acceleration was observed when the glycosylation was conducted in p-xylene below its freezing point.     

Banach空间中拟-似变分包含解的存在与逼近问题

研究了Banach空间中拟-似变分包含解的存在与逼近问题.给出了一种寻求解的新的迭代算法,建立了具混合误差的Ishikawa型迭代序列强收敛到解的充要条件.所得结果推广了一些相关的结果.     

大中直径螺旋焊管切管机的试验研究

介绍一种采用机械式铣削方法(旋风铣)来切断螺旋焊管的移动式切管机,并在实验的基础上与其它方式的切管方法进行了分析对比,从而肯定了这种切管方式的较大的优越性.     

水稻新品种海科115的选育

本文介绍水稻新品种海科115的选育。要选育高产、优质、高抗的新品种应该注重:根据海南气候的特点和生产实际需要;选择主要性状互补性强、优点多缺点少的品种作亲本;选育过程、重视库源比,通过长粒化来达大粒化和提高结实率;注重抗源的利用和抗病性状的选择。     

ON THE COHOMOLOGY OF GENERALIZED RESTRICTED LIE ALGEBRAS

0.IntroductionThispaperisaimedatdevelopingthecohomologytheoryofmodularLiealgebrasandthendeterminingthefirstcohomologygroupsofCartantypeLiealgebras.AsgeneralizationoftheconceptofrestrictedLiealgebras,ageneralizedrestrictedLiealgebra(GRLiealgebra)wasintroducedin[21],whichisassociatedwithabasisandamappingofthebasisintotheLiealgebrasatisfyingthegeneralized-restrictednessconditions.Generalizedrestrictedrepresentations(GRrepresentations)werethenintroduced,whichcanbereducedtotherepresentationsofa…     

Precise Asymptotics for Lévy Processes

Let {X（t）, t ≥ 0} be a Lévy process with EX（1） = 0 and EX^2（1） 〈 ∞. In this paper, we shall give two precise asymptotic theorems for {X（t）, t 〉 0}. By the way, we prove the corresponding conclusions for strictly stable processes and a general precise asymptotic proposition for sums of i.i.d. random variables.     

双曲函数型辅助方程构造具5次强非线性项的波方程的新精确孤波解

在辅助方程法的基础上利用两种函数变换和一种双曲函数型辅助方程，通过符号计算系统Mathematica构造了在力学当中一个重要的模型，有5次强非线性项的波方程的新三角函数型和双曲函数型精确孤波解.这种方法寻找其他具5次强非线性项的非线性发展方程的新精确解方面具有普遍意义. 关键词： 双曲函数型辅助方程 函数变换 具5次强非线性项的波方程 精确孤波解     

L1-optimal estimates for a regression type function in R

Let X₁, X₂, …, X_n be random vectors that take values in a compact set in R^d, d ≥ 1. Let Y₁, Y₂, …, Y_n be random variables (“the responses”) which conditionally on X₁ = x₁, …, X_n = x_n are independent with densities f(y | x_i, θ(x_i)), i = 1, …, n. Assuming that θ lives in a sup-norm compact space Θ_q,d of real valued functions, an optimal L₁-consistent estimator of θ is constructed via empirical measures. The rate of convergence of the estimator to the true parameter θ depends on Kolmogorov's entropy of Θ_q,d.     

m阶多时滞中立型微分方程的2T周期解

研究m阶常系数线性多时滞中立型方程的周期解，讨论了2T周期解的存在性和唯一性，得到了2T周期解存在唯一若干新的充分必要条件。所得主要结果适用性更广。它包括了许多相关献的结果为其特例，推广、改进了这些献的主要结果。可对所研究的中立型方程周期解存在的大量情形作出判断，而这些情形用其他献的结果是无法判断的。换言之，对方程（1），主要结果是最一般化的，用同样的方法已不可能得到更好的结果。