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41.
Ding Yuan Ting Wu Rong-yuan Chen Gui-zhen Zhang 《Journal of Macromolecular Science: Physics》2018,57(5):348-363
The properties of polymer matrix composites are related not only to the chemical composition of the materials but also to the processing equipment used for their preparation which has a direct influence on the microstructure of the composites. In this paper polypropylene (PP)/multi-walled carbon nanotubes (MWCNTs) nanocomposites were prepared by melt blending through a self-developed, eccentric rotor extruder (ERE). The structure and elongational deformation mechanism of an ERE were described in detail. The morphological, rheological, thermal and mechanical properties of the resulting PP/MWCNTs nanocomposites were investigated. Scanning electron microscopy (SEM) and rheological analysis showed that the MWCNTs were well dispersed in the PP matrix. The thermal stability was investigated by thermogravimetric analysis (TGA) and indicated that the addition of MWCNTs could effectively improve the thermal stability of pure PP. The percentage of crystallinity and tensile strength of the composites were improved as a result of the heterogeneous nucleation effect of the MWCNTs in the PP matrix. The research results revealed that the enhancement of the properties of PP/MWCNTs composites could be attributed to a better dispersion of the MWCNTs in the matrix as compared to samples prepared by conventional extrusion. 相似文献
42.
金属氢的高压合成机理 总被引:3,自引:1,他引:3
从氢原子间及氢分子间的相互作用入手,提出了固体氢中氢分子在高压作用下解离为氢原子,并以氢原子相互结合成金属氢的微观转化过程的机理。用这样的转化机理,可以解释毛河光等关于固体氢的拉曼光谱频率随高压变化规律的实验结果。 相似文献
43.
Summary Polyamines and polyamine conjugates display a diverse range of important biological functions, ranging from antibiotics to immunosuppressants and glutamate receptor antagonists. For these reasons, polyamines provide an excellent template/scaffold for combinatorial chemistry. In this paper we present methods for the solid-phase immobilisation of polyamines for use in synthetic and combinatorial chemistry and describe how they have been employed in the preparation of a number of important polyamine conjugates and polyamine libraries. Thus, we have designed, synthesised and utilised a number of polyamine linkers for both solution and resin screening combinatorial application. 相似文献
44.
Tiziana Boffa Ballaran 《Phase Transitions》2013,86(1-2):137-154
Following recent developments in the application of autocorrelation analysis of line broadening in powder absorption IR spectra, the possibility that elastic strain heterogeneities are responsible both for such broadening and for enthalpy variations in solid solutions has been explored systematically. Recent data for five silicate solid solutions, augite-jadeite, almandine-grossular, albite-anorthite, anthophyllite-grunerite and clinoenstatite-clinoferrosilite, are reviewed. Variations in the autocorrelation parameter for line broadening, j corr, scale linearly with calorimetric data for enthalpy variations, j H , associated with cation substitutions and ordering in these systems. It is proposed that, while there may not be a universal calibration of j H in terms of j corr for all structures, it should be possible to produce empirical calibrations for groups of solid solutions with the same basic structure. Variations in j corr at different phonon frequency ranges provide additional insights into the structural mechanisms by which ordering, mixing, displacive and reconstructive processes occur in silicate solid solutions. 相似文献
45.
Araujo RG Oleszczuk N Rampazzo RT Costa PA Silva MM Vale MG Welz B Ferreira SL 《Talanta》2008,77(1):400-406
Two analytical methods for the determination of cadmium in wheat flour by electrothermal atomic absorption spectrometry without prior sample digestion have been compared: direct solid sampling analysis (SS) and slurry sampling (SlS). Besides the conventional modifier mixture of palladium and magnesium nitrates (10 μg Pd + 3 μg Mg), 0.05% (v/v) Triton X-100 has been added to improve the penetration of the modifier solution into the solid sample, and 0.1% H2O2 in order to promote an in situ digestion for SS. For SlS, 30 μg Pd, 12 μg Mg and 0.05% (v/v) Triton X-100 have been used as the modifier mixture. Under these conditions, and using a pyrolysis temperature of 800 °C, essentially no background absorption was observed with an atomization temperature of 1600 °C. About 2 mg of sample have been typically used for SS, although as much as 3-5 mg could have been introduced. In the case of SlS multiple injections had to be used to achieve the sensitivity required for this determination. Calibration against aqueous standards was feasible for both methods. The characteristic mass obtained with SS was 0.6 pg, and that with SlS was 1.0 pg. The limits of detection were 0.4 and 0.7 ng g−1, the limits of quantification were 1.3 and 2.3 ng g−1 and the relative standard deviation (n = 5) was 6-16% and 9-23% for SS and SlS, respectively. The accuracy was confirmed by the analysis of certified reference materials. The two methods were applied for the determination of cadmium in six wheat flour samples acquired in supermarkets of different Brazilian cities. The cadmium content varied between 8.9 ± 0.5 and 13 ± 2 ng g−1 (n = 5). Direct SS gave results similar to those obtained with SlS using multi-injections; the values of both techniques showed no statistically significant difference at the 95% confidence level. Direct SS was finally adopted as the method of choice, due to its greater simplicity, the faster speed of analysis and the better figures of merit. 相似文献
46.
Prof. Xiaona Li Yang Xu Prof. Changtai Zhao Duojie Wu Dr. Limin Wang Matthew Zheng Xu Han Dr. Simeng Zhang Junyi Yue Prof. Biwei Xiao Dr. Wei Xiao Dr. Ligen Wang Prof. Tao Mei Prof. Meng Gu Prof. Jianwen Liang Prof. Xueliang Sun 《Angewandte Chemie (International ed. in English)》2023,62(48):e202306433
As exciting candidates for next-generation energy storage, all-solid-state lithium batteries (ASSLBs) are highly dependent on advanced solid-state electrolytes (SSEs). Here, using cost-effective LaCl3 and CeCl3 lattice (UCl3-type structure) as the host and further combined with a multiple-cation mixed strategy, we report a series of UCl3-type SSEs with high room-temperature ionic conductivities over 10−3 S cm−1 and good compatibility with high-voltage oxide cathodes. The intrinsic large-size hexagonal one-dimensional channels and highly disordered amorphous phase induced by multi-metal cation species are believed to trigger fast multiple ionic conductions of Li+, Na+, K+, Cu+, and Ag+. The UCl3-type SSEs enable a stable prototype ASSLB capable of over 3000 cycles and high reversibility at −30 °C. Further exploration of the brand-new multiple-cation mixed chlorides is likely to lead to the development of advanced halide SSEs suitable for ASSLBs with high energy density. 相似文献
47.
Macchione MM Merheb CW Gomes E da Silva R 《Applied biochemistry and biotechnology》2008,146(1-3):223-230
A comparative study was carried out to evaluate protease production in solid-state fermentation (SSF) and submerged fermentation
(SmF) by nine different thermophilic fungi – Thermoascus aurantiacus Miehe, Thermomyces lanuginosus, T. lanuginosus TO.03, Aspergillus flavus 1.2, Aspergillus sp. 13.33, Aspergillus sp. 13.34, Aspergillus sp. 13.35, Rhizomucor pusillus 13.36 and Rhizomucor sp. 13.37 – using substrates containing proteins to induce enzyme secretion. Soybean extract (soybean milk), soybean flour,
milk powder, rice, and wheat bran were tested. The most satisfactory results were obtained when using wheat bran in SSF. The
fungi that stood out in SSF were T. lanuginosus, T. lanuginosus TO.03, Aspergillus sp. 13.34, Aspergillus sp. 13.35, and Rhizomucor sp. 13.37, and those in SmF were T. aurantiacus, T. lanuginosus TO.03, and 13.37. In both fermentation systems, A. flavus 1.2 and R. pusillus 13.36 presented the lowest levels of proteolytic activity. 相似文献
48.
瞬态提纯轴心轨迹在回转机械诊断中的应用研究 总被引:3,自引:0,他引:3
史东锋 《西安交通大学学报》1999,33(3):104-107
针对回转机械常用信号处理方法的4个缺陷,提出了基于改进傅里叶变换的瞬态提纯轴心轨迹方法,淫来分析瞬变信号,该方法集成了短时傅里叶变换和全息谱的优点,通过一系列工频椭圆的变化规律来直观地反映转子的振动特性。经启车实例分析,证明该方法将成为诊断和分析转子振动特性的强有力工具。 相似文献
49.
刘伟佳 《吉林师范大学学报(自然科学版)》2012,33(3):47-49
在实际转子中"陀螺效应"在一定程度上会影响临界转速.本文采用ANSYS模拟的方法计算转子的临界转速并研究其"陀螺效应".通过计算几个长度相同半径不同的简单梁的临界转速,确定梁跨比不同时"陀螺效应"对临界转速影响. 相似文献
50.
段正忠 《渝西学院学报(自然科学版)》2005,4(2):32-35
大中型鼠笼型异步电动机目前广泛采用间接起动方法,而传统的起动方法存在着许多缺点.采用电子式软起动器能解决传统方法中的不足,在计算机技术广泛应用的今天,电子式软起动器的性价比已达到一个合理的水平,值得大力推广和应用. 相似文献