Sulfonated poly(aryl ether ether ketone ketone)s containing fluorinated moieties as proton exchange membrane materials

A series of sulfonated poly(aryl ether ether ketone ketone)s statistical copolymers with high molecular weights were synthesized via an aromatic nucleophilic substitution polymerization. The sulfonation content (SC), defined as the number of sulfonic acid groups contained in an average repeat unit, could be controlled by the feed ratios of monomers. Flexible and strong membranes in sodium sulfonate form could be prepared by the solution casting method, and readily transformed to their proton forms by treating them in 2 N sulfuric acid. The polymers showed high T_gs, which increased with an increase in SC. Membranes prepared from the present sulfonated poly(ether ether ketone ketone) copolymers containing the hexafluoroisopropylidene moiety (SPEEKK‐6F) and copolymers containing the pendant 3,5‐ditrifluoromethylphenyl moiety (SPEEKK‐6FP) had lower water uptakes and lower swelling ratios in comparison with previously prepared copolymers containing 6F units. All of the polymers possessed proton conductivities higher than 1 × 10^?2 S/cm at room temperature, and proton conductivity values of several polymers were comparable to that of Nafion at high relative humidity. Their thermal stability, oxidative stability, and mechanical properties were also evaluated. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2299–2310, 2006     

仿射Weyl群(E～)6的a值5的左胞腔

Coxeter群的胞腔是1979年Kazhdan和Lusztig中定义的，这些胞腔理论在代数群的表示理论中发挥了重要的作用。对一些特殊的情况，胞腔的分类已经明确地给出了，例如，对于秩为2的群参见，对于An^-参见，对于a值4的典范型和或参见.本文利用时俭益的运算算法给出了仿射Weyl群E6^-的a值等于5的所有左胞腔。     

冠状动脉粥样硬化病变中微量元素的X射线显微分析

本文应用EDAX-9100能谱仪,对家兔冠状动脉粥样硬化病变部位的微量元素进行显微分析,发现Zn/Cu比值大于1,提供了冠心病病因中“Zn/Cu假说”的实验论证。     

产物分离固相化细胞反应器的设计和数学模型

设计了一种以挥发性产物和非挥发性底物为特征的四相反应器——分离器。在此反应器中,生物催化剂被固定在固体柱填充物上并与含有底物的液相接触,汽相流过柱子而将挥发性产物蒸发迸入汽相。反应器由同方向流的浓缩器和反方向流的分离器两个基本汽——液流部分组成。并建立了吸附的单层细胞稳态群体数学模型和反应器平衡状态模型。     

建立人输卵管上皮细胞无血清培养

人输卵管上皮细胞（HOEC）可以体外较长时间无血清培养,DMEM／F12培养液的培养效果优于Ham’sF10,在加有多种因子和胎球蛋白的培养液中,HOEC可贴壁生长,生长能力达到合质量分数15％FCS的对照组的30％～40％,一般可传代2次,最长培养可维持38d,细胞形态与有血清培养差别不大,虽然无血清培养HOEC的生长速度、密度、传代成功率远不及有血清培养,但能抑制成纤维细胞生长,维持较纯的上皮细胞。     

Marked electrical synapses on AP neuron of the leech (Whitmania pigra)

An initial attempt reveals parameters of marked electric synapse on AP perceptive neuron of leech. The width of gap between marked AP and either neuro-or glio-process is 2–3 nm, the diameter of the hexagonal array of connexion is 8–9 nm with a central pole of 2–2.5 nm, the same as the structure of annular lamellar bodies internalized by AP-glia processes in the AP.     

Endothelial Cell Culture on Different Phospholipid Surfaces *

ＩｎｔｒｏｄｕｃｔｉｏｎＢｉｏｍａｔｅｒｉａｌｓａｒｅａｌｗａｙｓｕｓｅｄｉｎａｎｅｎｖｉｒｏｎｍｅｎｔａｄｊａｃｅｎｔｔｏｌｉｖｉｎｇｔｉｓｓｕｅｓａｎｄｂｌｏｏｄ．Ｃｅｌｕｌａｒｉｎｔｅｒａｃｔｉｏｎｓｗｉｔｈｉｍｐｌａｎｔｓａｒｅｏｆｐｒｉｍａ...     

Construction of High Level Expression Cell Lines of Erythropoietin *

Ｅｒｙｔｈｒｏｐｏｉｅｔｉｎ（ＥＰＯ）ｉｓｏｎｅｏｆｔｈｅｍｏｓｔｉｍｐｏｒｔａｎｔｒｅｇｕｌａｔｏｒｙｆａｃｔｏｒｓｄｕｒｉｎｇｔｈｅｄｅｖｅｌｏｐｍｅｎｔｏｆｍａｍｍａｌｉａｎｅｒｙｔｈｒｏｃｙｔｅ,ａｃｔｉｎｇｍａｉｎｌｙｏｎｔｈｅｅｒｙｔｈｒ...     

老年牙周炎患者外周血NK细胞活性的研究

测定老年牙周炎患者外周血ＮＫ细胞活性。采用ＭＴＴ法测定,并与成年和青少年牙周炎患者进行比较。发现老年牙周炎患者外周血ＮＫ细胞活性低于成年牙周炎患者（Ｐ＜０．０１）,也低于青少年牙周炎患者（Ｐ＜０．０５）。老年牙周炎患者ＮＫ细胞活性低下可能是老年人牙周病发病率高,组织破坏重的原因之一。