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211.
几种LED衬底材料的特征对比与研究现状 总被引:5,自引:0,他引:5
概述了LED川衬底的三种物质氧化铝、炭化硅、氧化锌各自的特性.衬底选取的原则.得出它们作讨底的优缺点及其研究现状. 相似文献
212.
基于化学气相反应法,以高纯Si和SiO2为反应源材料,在碳纤维表面原位生长β-SiC纳米纤维。采用XRD、SEM和TEM 等分析测试手段对SiC纳米纤维进行了表征分析,研究了不同反应温度和时间对生成β-SiC纳米纤维微观形貌和结构的影响,并探讨了β-SiC纳米纤维的生长机制。研究结果表明:采取化学气相反应法能够制备高质量、高纯度的β-SiC纳米纤维,纳米纤维的直径约为100~300 nm。随着反应温度的提高和时间的延长,纳米纤维的产额增加,且微观组织形貌发生了变化。结合制备过程和纳米纤维微观结构的观察分析,表明气-固(VS)机制是SiC纳米纤维生长的主要机理。 相似文献
213.
以聚铝碳硅烷(PACS)为先驱体, 采用先驱体转化技术制备出耐超高温的连续SiC纤维. 研究了制备过程中纤维结构和取向的演变及其对纤维性能的影响. 研究结果表明, 耐超高温连续SiC纤维制备过程中纤维结构的演变随温度变化分为分子间交联(≤600 ℃)、基本无机化(600—800 ℃)、完全无机化(800—1300 ℃)和结晶重排(1300—1800 ℃) 四个阶段; 纤维的取向随着结构的演变而改变, 连续PACS纤维沿轴向具有的微弱取向, 经热分解后演变到1300 ℃的产物中, 1300 ℃后随着结晶重排的发生, 纤维由各向异性转变为各向同性; 结构和取向的转变对于纤维性能具有很大的影响. 相似文献
214.
三维网络SiC增强铜基复合材料的干摩擦磨损性能 总被引:14,自引:0,他引:14
用销—盘式高温摩擦磨损试验机研究了85Cu—6Sn—6Zn—3Pb合金及三维网络SiC增强铜基复合材料的干摩擦磨损性能,测量了铜合金及不同体积分数的复合材料在不同温度及载荷下的摩擦系数和磨损率;用扫描电子显微镜观察磨损表面形貌,并分析了三维网络SiC对铜合金磨损机制的影响.结果表明:复合材料的耐磨性远优于铜合金,而且随着三维网络SiC体积分数、温度及载荷的增加,复合材料的抗磨损性能明显提高;这种新型复合材料的摩擦系数随载荷变化保持稳定,在很宽的温度范围内,摩擦系数的稳定性均优于铜合金.这是由于三维网络SiC在磨损表面形成硬的微突体并起承载作用,同时其独特的结构制约了基体合金的塑性变形和高温软化,有利于磨损表面氧化膜的留存.这种复合材料作为传动及制动用摩擦材料具有明显的优越性. 相似文献
215.
1Introduction
Polysilanes are novel polymers with Si-Si catenation chain. They can be used as precursors for SiC ceramic, have important applications in anti-oxidation of C/C composites[1]. Poly(methylsilane)(PMS), which is anideal precursor to stoichiometric SiC, is synthesized by the sodium polycondensation reaction of monomer CH3SiHCl2. During the reaction, there is an initiation period. In this period there is no obvious exothermic reaction after dropping of monomer, then suddenly eruptive reaction arise and temperature goes up quickly. After the eruption, the polymerization can proceed smoothly. This phenomenon is harmful to scale-up. To solve this problem, we did relevant research, but the additive, crown ether, is expensive[2]. This paper describes the influence of naphthalene(NAPH) and p-dibromobenzene(DBB) on the reaction. Good effect is attained for these additives. 相似文献
216.
Tianle Zhou Mingyuan Gu Yanping Jin Junxiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):371-379
The curing kinetics of the diglycidyl ether of bisphenol‐A (DGEBA)/2‐ethyl‐4‐methylimidazole (EMI‐2,4)/nano‐sized carborundum (nano‐SiC) system was studied by means of nonisothermal differential scanning calorimetry (DSC). An isoconversional method of kinetic analysis yields a dependence of the effective activation energy E on the extent of conversion that decreases initially, and then increases as the cure reaction proceeds. The variations of E were used to study the cure reaction mechanisms, and the Shrinking Core Model was used to study the resin–particle reaction. The results show that the presence of nano‐SiC particles prevents the occurrence of vitrification, as well as inhibits the cure reaction. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 371–379, 2006 相似文献
217.
218.
将具有三维网状结构和连通孔道的高弹性聚氨酯海绵作为先驱体,选用一级品α-SiC为骨料,配以各种添加剂,分水基和非水基2种配方调制浆料,浸渍先驱体成型。采用常规烧结法和反应烧结法烧结制品,并利用XRD和SEM等测试手段对制品的结构与性能进行了分析研究。结果表明:经过反复实验研究制备的2组样品中的A-2,B-5具有代表性,通过对比A-2,B-5 2样品的性能、显微结构、晶相,确定了碳化硅泡沫瓷制备的最佳工艺方法,提出了反应烧结碳化硅泡沫瓷的烧结机理。 相似文献
219.
Erwin Schmitt Thomas Straubinger Michael Rasp Arnd-Dietrich Weber 《Superlattices and Microstructures》2006,40(4-6):320
For several years the major focus of material issues in SiC substrates was laid on the reduction of macroscopic defects like polytype inclusions, low angle grain boundaries and micropipes. Although significant improvements have been achieved, there are still shortcomings in material quality that have to be overcome. Since it is clear that dislocations are the main reason for degradation in power devices the prevailing attention has shifted to that field of material research. The aim of our work was to investigate the mechanisms that affect the generation of macroscopic and microscopic defects during sublimation growth. Intense studies were utilized on dislocation and stacking fault formation. For this reason we systematically varied parameters of the growth process and applied several methods for the characterization to evaluate material properties most precisely, e.g. KOH-defect-etching, X-ray-diffraction, electron microscopy and optical microscopy. The investigations were accompanied by failure analysis of devices of the Schottky type. We found out that for the improvement of substrate quality emphasis has to be laid on the reduction of thermoelastic stress in the growing crystal. From results of numerical calculations we were able to derive moderate growth conditions with reduced temperature gradients prevailing during the growth process. As a consequence we succeeded in decreasing the defect concentration. The best value so far achieved for the sum of both BPD and TED was 7×103 cm−2. 相似文献
220.
G. Brauer W. Anwand W. Skorupa C. Teichert J. Cizek P.G. Coleman A. Kohyama 《Applied Surface Science》2006,252(9):3342-3351
A SiC/SiC composite is characterized by X-ray diffraction, atomic force microscopy and various positron spectroscopies (slow positron implantation, positron lifetime and re-emission). It is found that besides its main constituent 3C-SiC the composite still must contain some graphite. In order to better interpret the experimental findings of the composite, a pyrolytic graphite sample was also investigated by slow positron implantation and positron lifetime spectroscopies. In addition, theoretical calculations of positron properties of graphite are presented. 相似文献