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61.
《Electroanalysis》2004,16(17):1401-1405
The immobilization of tris(2,2′‐bipyridyl)ruthenium(II), Ru(bpy)32+, at a glassy carbon electrode was achieved by entrapping the Ru(bpy)32+ in a vapor deposited titania sol‐gel membrane. The electrogenerated chemiluminescence (ECL) of the immobilized Ru(bpy)32+ was studied. The Ru(bpy)32+ modified electrode showed a fast ECL response to both oxalate and proline. The ECL intensity was linearly related to concentrations of oxalate and proline over the ranges from 20 to 700 μmol L?1 and 20 to 600 μmol L?1, respectively. The detection limits for oxalate and proline at 3σ were 5.0 μmol L?1 and 4.0 μmol L?1, respectively. This electrode possessed good precision and stability for oxalate and proline determinations. The electrogenerated chemiluminescence mechanism of proline system was discussed. This work provided a new way for the immobilization of Ru(bpy)32+ and the application of titania sol‐gel membrane in electrogenerated chemiluminescence. 相似文献
62.
Extraction-spectrophotometric determination of iron with 2-(2′-benzothiazolylazo)-4,6-dimethylphenol
Pérez Pont M. L. Sánchez M. J. Francisco A. García Montelongo F. 《Mikrochimica acta》1986,88(3-4):183-190
An extraction-spectrophotometric method for the determination of trace amounts of iron based on its extraction into chloroform with 2-(2-benzothiazolylazo)-4,6-dimethylphenol (BTADMP) from a pH 6.5 medium has been developed. The extracted 12 FeBTADMP complex species allow the determination of 4–30gmg of iron (=3.92×1041·mol–1·cm–1 at 790 nm). The method is highly selective and has been applied to the determination of iron in polymineral-polyvitamin pharmaceutical products. 相似文献
63.
The structures of B32 and B32H2–32 with Ih symmetry have been investigated by means of ab initio calculations at STO-3G level. The relationship between molecular orbitals of them has been analyzed and their bonding properties have been discussed. Then the possibility of their existence, as well as the similarity and difference between B32 (B32H2–32) and C60 (C60H60) have been inferred. 相似文献
64.
Electrochemistry and in situ electrochemical scanning tunneling microscopy (STM) were used to study the blocking and structural properties of Shiff base V-ape-V self-assembled monolayers (SAMs) on the surface of Au(111) in perchloric acid solution. The complex-plane impedance plots for the SAM covered Au(111) electrodes, with the redox couple of Fe(CN)64–/3– present in solution, exhibit arc shapes, revealing that the electrochemical kinetics were controlled by the electron-transfer step. For bare Au(111), the electrode process was mass transport limited. The molecules adsorb on Au(111) with a flat-lying orientation and form a long-range well-defined adlayer. A new structure of
was observed in the double-layer potential region. A structural model is proposed to interpret the molecular registry with Au(111) substrate. 相似文献
65.
In this paper we investigate a class of Lie group actions on
, the so-calledpolar actions, that naturally generalize the standard
actions. For a domain invariant under such an action (i.e., a generalized Reinhardt domain) we characterize the invariant
plurisubharmonic functions and determine the envelope of holomorphy in geometric terms. For a generalized Reinhardt domain
containing the origin of
we also compute its automorphism group.
Supported in part by NSF Grant 8602020 相似文献
66.
It has been conjectured that a lattice in a noncompact group of real rank one, other than SU(1,n), cannot be isomorphic to the fundamental group of a compact Kähler manifold; moreover, it is known to be true for SO(1,n). In this note it is shown that this conjecture also holds for the case of uniform lattices in F4(?20), the group of isometries of the Cayley hyperbolic plane. The result is a consequence of a classification theorem for harmonic maps between Kähler and Cayley hyperbolic manifolds. 相似文献
67.
We study topological conditions that must be satisfied by a compactC ∞ Levi-flat hypersurface in a two-dimensional complex manifold, as well as related questions about the holonomy of Levi-flat hypersurfaces. As a consequence of our work, we show that no two-dimensional complex manifold admits a subdomain Ω with compact nonemptyC ∞ boundary such that Ω ? ?2. 相似文献
68.
Chi-Keung Cheung 《Journal of Geometric Analysis》1992,2(2):105-119
In this paper we considered curvature conditions on a Kähler-Einstein surface of general type. In particular we showed that it has negative holomorphic sectional curvature if theL 2-norm of (3C 2 ?C 1 2 )/C 1 2 is sufficiently small, whereC 1 andC 2 are the first and second Chern classes of the surfaces. This generalizes a result of Yau on the uniformization of Kähler-Einstein surfaces of general type and with 3C 2 ?C 1 2 = 0. Also in the process, we obtain a necessary condition in terms of an inequality between Chern numbers for a Kähler-Einstein metric to have negative holomorphic sectional curvature. 相似文献
69.
We add to the known examples of complete Kähler manifolds with negative sectional curvature by showing that the following three classes of domains in euclidean spaces also belong: perturbations of ellipsoidal domains in ?n, intersections of complex-ellipsoidal domains in ?2, and intersections of fractional linear transforms of the unit ball in ?2. In the process, we prove the following theorem in differential geometry: in the intersection of two complex-ellipsoidal domains in ?2, the sum of the Bergman metrics is a Kähler metric with negative curvature operator. 相似文献
70.
It is an open question whether there is a strange attractor for the Henon mapping. We show that for certain maps close to
the Henon map there are strange attractors. 相似文献