(Al)GaAs/AlGaAs周期光波导中的等幅基模

本文应用周期介质光波导的模场分布函数和特征方程分析了(Al)GaAs/AlGaAs周期光波导中结构参量及介质折射率对模场分布形状的影响,研究了波导中形成等幅基模的条件,讨论了相应参量的优化选择。     

Higher order estimation at Lebesgue points

The symmetric derivative of a probability measure at a Lebesgue point can often be specified by an exact relation involving a regularity index. Knowledge of this index is of practical interest, for example to specify the local behavior of the measure under study and to evaluate bandwidths or number of neighbors to take into account in smoothing techniques. This index also determines local rates of convergence of estimators of particular points of curves and surfaces, like minima and maxima. In this paper, we consider the estimation of the d-dimensional regularity index. We introduce an estimator and derive the basic asymptotic results. Our estimator is inspired by an estimator proposed in Drees and Kaufmann (1998, Stochastic Processes and their Applications, 75, 149–172) in the context of extreme value statistics. Then, we show how (estimates of) the regularity index can be used to solve practical problems in nearest neighbor density estimation, such as removing bias or selecting the number of neighbors. Results of simulations are presented.     

不同偏置电流下半导体激光器的输出模式数目

本文通过求解半导体激光器的多模速率方程组,得到了不同偏置电流下半导体激光器的输出模式数目(定义为输出谱线半宽度内的模式数目)的表达式,首次从理论上预计了在阈值电流附近半导体激光器的输出模式数目.实验结果表明,理论和实验吻合得很好.     

Penny-shaped crack in a piezoelectric cylinder under electro-mechanical loads

Summary The fracture behavior of a penny-shaped crack in a axisymmetrical piezoelectric ceramic cylinder of finite radius under mechanical and electrical loads is analyzed under electric continuous boundary conditions on the crack surface. The potential theory and Hankel transform are used to obtain a system of dual integral equations, which is then expressed as a Fredholm integral equation. Singular mechanical and electrical fields and field intensity factors of mode I are obtained. The numerical values of various field intensity factors for PZT-6B piezoelectric ceramics are graphically shown for a uniform load and a ring-shaped load, respectively. The effects of the radius of the cylinder on the field intensity factors are investigated. This work was supported by the Korea Research Foundation Grant (KRF-2001-041-E00057).     

乙炔和甲基二氯硅烷的硅氢加成反应研究 Ⅱ.反应物料进样方式及催化剂保护剂的影响

考察了３种不同特点的物料进样方式对乙炔和甲基二氯硅烷的硅氢加成反应的影响；研究了温度、溶剂及乙炔流量等反应条件，对不同进样方式的硅氢加成反应的作用规律．结果表明，物料进样方式不同，反应体系中物料配比及物料混合程度也不同，导致了这一串联硅氢加成反应的硅烷转化率及一次加成选择性极大的差异；在不同进样方式的反应中，反应温度、溶剂等反应条件，表现出极为不同的影响规律；确定了具有高硅烷转化率和一次加成选择性的进样方式以及合适的反应条件．用直接水解的方法制备了聚甲基乙烯基硅氧烷，以此为保护剂，热分解氯铂酸，得到了有高反应活性和稳定性的金属铂胶体．     

Mode of coordination and stability of Cu(II) and Zn(II) complexes with adenosine,deoxyadenosine, cytidine and deoxycytidine

Summary Stability constants of Cu(II) and Zn(II) complexes with nucleosides have been determined from a computer analysis of potentiometric titration results. Spectral investigations prove that in acidic solution adenosine coordinates to Cu(II)via its N1 or N7 atoms, while atpH>7 only N7 is involved. Similar interactions are observed for dAdo complexes. Spectral and potentiometric studies suggest that Zn does not form stable complexes with dAdo. In the case of cytidine and deoxycytidine, the preferred site of coordination is the N3 atom of the nucleoside. Oxygen atoms from the carbonyl groups are not involved in Cu(II) or Zn(II) coordination. The results of the spectral investigation have excluded the ribose and deoxyribose moieties of all studied ligands from participation in the interactions. In general, the mode of coordination of nucleosides and deoxynucleosides with Cu(II) and Zn(II) has been found analogous.

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Art der Koordination und Stabilität von Cu(II)- und Zn(II)-Komplexen mit Adenosin, Deoxyadenosin, Cytidin und Deoxycytidin

Zusammenfassung Mittels einer Computeranalyse von Ergebnissen aus potentiometrischen Titrationen wurden Stabilitätskonstanten für Komplexe aus Cu(II) bzw. Zn(II) und Nucleosiden bestimmt. Spektroskopische Untersuchungen zeigen, daß Adenosin in saurer Lösung über N1 oder N7 an Cu(II) koordinieren kann, während beipH>7 nur N7 reagiert. Analoges wird für die Komplexe mit dAdo beobachtet. Aus spektroskopischen und potentiometrischen Untersuchungen geht hervor, daß Zn mit dAdo keine stabilen Komplexe bildet. Im Fall von Cytidin und Deoxycytidin ist N3 die bevorzugte Koordinationsstelle des Nucleosids. Die Sauerstoffatome der Carbonylgruppen sind an der Bindung an Cu(II) und Zn(II) nicht beteiligt. Die spektroskopischen Ergebnisse schließen eine Beteiligung der Ribose- und Deoxyriboseeinheiten an den Wechselwirkungen aus. Allgemein wurde für Nucleoside und Deoxynucleoside ein analoger Koordinationsmodus gefunden.

     

Satellite Hole Investigation of the Vibrational Modes of 9-Aminoacridine upon Binding to DNA

The spectral features of satellite holes are used to investigate 9-aminoacridine-DNA interactions. The hole depths of the outer ring vibronic modes are reduced more than that of the inner ring vibronic modes, implying that inner ring motion is less perturbed than outer ring motion. As a result, the mode coupling between the inner ring and outer ring is reduced upon binding to DNA. However, similar hole frequency and width of the satellite hole corresponding to the NH₂ mode upon binding to DNA imply that the amino group of 9-aminoacridine sits outside the DNA.     

高校主体性德育模式的建构依据

为提高高校德育的实效性,构建以学生为中心的主体性德育模式。其目标建构既有哲学、心理学的理论基础,也有道德教育的方法论基础。