高中化学学业水平考试与课程标准的一致性分析

基于SEC一致性分析模式,对某省2010、2011、2012年的高中化学学业水平考试试题中必修部分与课程标准的一致性进行研究,得出2者之间不存在统计学意义上显著的一致性。通过柱形图,从认知水平和内容主题2个维度分析影响试题与课程标准一致性的因素。最后对一致性研究方法和分析结果进行了简单的讨论和反思。     

同位素示踪SEC-ICP-MS研究大鼠体内镉的形态

通过建立凝胶排阻色谱分离紫外与电感耦合等离子体质谱在线检测的联用技术,研究了灌喂低浓度镉富集同位素后大鼠各器官中镉与蛋白结合的形态.结果发现,镉主要在肝、肾、睾丸中与硫蛋白结合形成金属硫蛋白.与传统方法相比.该法危害性小、具有更接近慢性中毒、能将重金属来源分为天然来源和人为引入等特点.     

Thermal degradation of poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT) and their blends upon melt processing

Poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT) are biodegradable aliphatic polyesters, which being semicrystalline and thermoplastic can be processed by conventional methods. Their blends give interesting materials for industrial packaging applications, due to their increased ductility as PBAT content increases. However, like many aliphatic polyesters, the PLA matrix degrades upon melt processing thus affecting the thermo-mechanical features of the blended material. In this work, we studied the effect of processing at high temperature on the molecular weight distribution, morphology, and thermo-mechanical properties of both homopolymers, as well as the PLA/PBAT 75/25 blend. Notably, different processing conditions were adopted in terms of temperature (range 150-200 °C) and other relevant processing parameters (moisture removal and nitrogen atmosphere). Analysis of PLA/PBAT blends indicated that intermolecular chain reactions took place under strong degradative conditions of PLA, yielding PLA/PBAT mixed chains (copolymers). Increasing amounts of copolymers resulted in improved phase dispersion and increased ductility, as SEM and mechanical tests indicated. Conversely, reduced PLA degradation with less copolymer formation, afforded higher modulus materials, owing to poorer dispersion of the soft phase (PBAT) into the PLA matrix.     

基于SEC准则的油田开发规划不确定优化模型及算法

在油价低迷的国际背景下,上市石油公司进行油田开发规划时越来越重视经营效益。美国证券交易委员会(SEC)要求上市石油公司采用产量法计提折耗,极大地影响了石油公司开发规划方案的制定。油田开发受到自然、技术等多种不确定因素的影响,在制定开发规划时需充分考虑这些不确定性。本文基于不确定理论,考虑措施增油效果和新增投资两类不确定参数,以经营效益最大化和新增投资最小化为目标,构建了基于SEC准则的油田开发规划不确定优化模型,并利用差分进化算法求解,给出措施工作量的帕累托解集。本文以D油田年度规划为例,通过构建模型并求解,给出开发规划方案集,并进一步分析SEC储量的下降对上市石油公司经营效益、新增投资回报率、油气总产量、油气完全成本和措施工作量的影响,为企业制定开发规划方案提供参考。     

Catalytic Chain Transfer Copolymerization of Propylene Oxide and CO2 using Zinc Glutarate Catalyst

Oligo and poly(propylene ether carbonate)-polyols with molecular weights from 0.8 to over 50 kg/mol and with 60–92 mol % carbonate linkages were synthesized by chain transfer copolymerization of carbon dioxide (CO₂) and propylene oxide (PO) mediated by zinc glutarate. Online-monitoring of the polymerization revealed that the CTA controlled copolymerization has an induction time which is resulting from reversible catalyst deactivation by the CTA. Latter is neutralized after the first monomer additions. The outcome of the chain transfer reaction is a function of the carbonate content, i. e. CO₂ pressure, most likely on account of differences in mobility (diffusion) of the various polymers. Melt viscosities of poly(ether carbonate)diols with a carbonate content between 60 and 92 mol % are reported as function of the molecular weight, showing that the mobility is higher when the ether content is higher. The procedure of PO/CO₂ catalytic chain copolymerization allows tailoring the glass temperature and viscosity.     

Continuous Size Classification of Nanoparticles Utilizing Brownian Motion in Microchannel Size Exclusion Chromatography

This study presents a new method for classifying the sizes of colloidal nanoparticles of below 100 nm in diameter in liquid dispersion using a microchannel size exclusion chromatography (SEC) chip. This chip can classify polydisperse colloidal nanoparticles containing a mix of two monodisperse nanoparticles into several monodisperse particle populations. The particles classified by the SEC chip are then sequentially analyzed by a photon correlation spectroscopy (PCS) method in combination with a flow cell. Two different pillar patterns of such SEC chips were used in experiments to investigate the effects of these patterns on the nanoparticle classification performance. The results obtained were compared with those from a numerical simulation. Standard polystyrene latex particles with diameters of 20 nm and 100 nm were used in this study. The usefulness of this methodology was verified since the simulation and measurement results were in good agreement with each other.     

Separation and analysis of the soluble trimer of Aβ1-40 and its effects on the rise in intracellular calcium

Alzheimer’s disease (AD) is one of the progressive neurodegenerative diseases associated with protein conformational transition, generally known as protein conformational disorders[1]. The general characteriza- tions of AD are the intracellular fibrillar…     

Review of validation and reporting of non-targeted fingerprinting approaches for food authentication

Food fingerprinting approaches are expected to become a very potent tool in authentication processes aiming at a comprehensive characterization of complex food matrices. By non-targeted spectrometric or spectroscopic chemical analysis with a subsequent (multivariate) statistical evaluation of acquired data, food matrices can be investigated in terms of their geographical origin, species variety or possible adulterations. Although many successful research projects have already demonstrated the feasibility of non-targeted fingerprinting approaches, their uptake and implementation into routine analysis and food surveillance is still limited. In many proof-of-principle studies, the prediction ability of only one data set was explored, measured within a limited period of time using one instrument within one laboratory. Thorough validation strategies that guarantee reliability of the respective data basis and that allow conclusion on the applicability of the respective approaches for its fit-for-purpose have not yet been proposed. Within this review, critical steps of the fingerprinting workflow were explored to develop a generic scheme for multivariate model validation. As a result, a proposed scheme for “good practice” shall guide users through validation and reporting of non-targeted fingerprinting results. Furthermore, food fingerprinting studies were selected by a systematic search approach and reviewed with regard to (a) transparency of data processing and (b) validity of study results. Subsequently, the studies were inspected for measures of statistical model validation, analytical method validation and quality assurance measures. In this context, issues and recommendations were found that might be considered as an actual starting point for developing validation standards of non-targeted metabolomics approaches for food authentication in the future. Hence, this review intends to contribute to the harmonization and standardization of food fingerprinting, both required as a prior condition for the authentication of food in routine analysis and official control.     

Characterization of carbon nanotubes and analytical methods for their determination in environmental and biological samples: A review

In the present paper, a critical overview of the most commonly used techniques for the characterization and the determination of carbon nanotubes (CNTs) is given on the basis of 170 references (2000–2014). The analytical techniques used for CNT characterization (including microscopic and diffraction, spectroscopic, thermal and separation techniques) are classified, described, and illustrated with applied examples. Furthermore, the performance of sampling procedures as well as the available methods for the determination of CNTs in real biological and environmental samples are reviewed and discussed according to their analytical characteristics. In addition, future trends and perspectives in this field of work are critically presented.     

Determining Free‐Radical Propagation Rate Coefficients with High‐Frequency Lasers: Current Status and Future Perspectives

Detailed knowledge of the polymerization mechanisms and kinetics of academically and industrially relevant monomers is mandatory for the precision synthesis of tailor‐made polymers. The IUPAC‐recommended pulsed‐laser polymerization–size exclusion chromatography (PLP–SEC) approach is the method of choice for the determination of propagation rate coefficients and the associated Arrhenius parameters for free radical polymerization processes. With regard to specific monomer classes—such as acrylate‐type monomers, which are very important from a materials point of view—high laser frequencies of up to 500 Hz are mandatory to prevent the formation of mid‐chain radicals and the occurrence of chain‐breaking events by chain transfer, if industrially relevant temperatures are to be reached and wide temperature ranges are to be explored (up to 70 °C). Herein the progress and state‐of‐the‐art of high‐frequency PLP–SEC with pulse repetition rates of 500 Hz is reported, with a critical collection of to‐date investigated 500 Hz data as well as future perspectives for the field.