HAsO_2在金电极上的阴极还原行为

采用环盘电极实验和交流阻抗技术等研究了ＨＡｓＱ_２在硫酸钠溶液（ｐＨ＝４．０）中在金电极上的阴极还原行为．结果表明,ＨＡｓＯ_２可以最终还原为 ＡｓＨ_３．整个还原过程可以分为两步：ＨＡｓＱ_２还原为金属Ａｓ和金属Ａｓ进一步还原成ＡｓＨ_３,还原产物ＡｓＨ_３在电极上的吸附较强,溶出性能较差．这两步还原过程在阻抗的复数平面图上呈现二个明显的电容弧,利用 ＥＱＵＩＶＣＲＴ软件对其进行计算机拟合,得到了对应的等效电路以及其中的反应电阻元件的数值．     

Identification of Transverse Crack Position and Depth in Rotor Systems

This paper introduces a method for the identification of the position and the depth of a transverse crack in a rotor system, by using vibration measurements. As it is reported in literature and from field experience, a transverse crack modifies the dynamic behaviour of the rotor, generating in a horizontal axis shaft periodical vibrations with 1x, 2x and 3x rev. components. A model-based diagnostic approach and a least-squares identification method in the frequency domain are used for the crack localisation along the rotor. The crack depth is calculated by comparing the static bending moment, due to the rotor weight and to the bearing alignment conditions, to the identified 'equivalent' periodical bending moment, which simulates the crack. Finally, the validation of the proposed method is carried out statically and dynamically by means of experimental results obtained on a test-rig.     

Effects of air-flow and evaporation on the development of thin liquid film over a rotating annular disk

Axisymmetric flow of thin pure liquid film on a spinning horizontal annular disk is studied under the action of air shear at the liquid–air interface and evaporation. The non-linear evolution equation that is obtained by singular perturbation method is solved analytically, for small Reynolds number, by using the method of characteristic and numerically by the use of Newton–Kantorovich method for any Reynolds number. Font breakdown time and its location from the center of the disk is predicted both by analytically and numerically. The result shows that the thinning of the initial film increases as air stress increase, same result is also escalated in presence of evaporation.     

Foucault Pendulum-like problems: A tensorial approach

The paper offers a comprehensive study of the motion in a central force field with respect to a rotating non-inertial reference frame. It is called Foucault Pendulum-like motion and it is a generalization of a classic Theoretical Mechanics problem. A closed form vectorial solution to this famous problem is presented. The vectorial time-explicit solution for the classic Foucault Pendulum problem is obtained as a particular case of the considerations made in the present approach. New interesting conservation laws for the Foucault Pendulum-like motion are deduced by using simple differential and vectorial computations. They help to visualize the shape of the trajectories. Exact vectorial expressions for the law of motion and the velocity are also offered. The case of the driven Foucault Pendulum is also analyzed, and a closed form solution is deduced based on the general considerations. In the end, an new tensorial prime integral for the Foucault Pendulum problem is offered. It helps to reveal in a concise form, within a single entity, all the scalar and vectorial conservation laws for the Foucault Pendulum motion.Two important engineering applications to this approach are presented: the motion of a satellite with respect to a rotating reference frame and the Keplerian relative orbital motion. The latter has a great importance in modeling the problems concerning satellite formation flying, satellite constellations and space terminal rendezvous. The classic problem of the harmonic oscillator in an electromagnetic field is also solved by using the instruments presented in this paper.     

硬质粒子扰动下铜电沉积研究

使用常规旋转电极电沉积技术,引入陶瓷球等一类硬质粒子,在旋转电极的带动下,使陶瓷球不断磨擦和撞击阴极表面而实现电铸铜.对比酸性溶液电铸铜和碱性溶液电铸铜,发现硬质粒子在电沉积过程中能扰动离子的放电过程,并影响电铸层的组织结构.但由于二者放电机理不同,前者形成的电铸层表面布满尖状毛刺,而后者则表面尖刺消失,但脆性大.SEM和XRD测试表明,由碱性电铸液沉积的电铸铜层,表面光亮平整,晶粒致密,大小约为100~300 nm,其结晶形态接近无序取向.     

Influence of Mg^2＋ on Initial Stages of CaCO3 Scale Formed on Metal Surface

Magnesium ions, which exist in formation water and injection water under downhole conditions in the oil and gas production industry, are a key determinant in the CaCO3 scale formation. Many studies have focused their attention on the effect of magnesium on the kinetics, the morphology and the content of Mg in the Ca-CO3 scale. Little attention has been paid to the effect of Mg^2 on the initial stages of CaCO3 formation on a metal surface. In this study, an electrochemical technique was used to study the influence of Mg^2 on the ini-tial stages of CaCO3 scale formed on a metal surface. With this electrochemical technique, the reduction of the dissolved oxygen in an analysis solution is considered on the surface of a rotating disk electrode (RDE) un-der potentiostatic control. The rate of oxygen reduction on the surface of the RDE enables the extent of sur-face coverage of scale to be assessed. With this electrochemical technique, a new insight into the effect of Mg^2 on CaCO3 scale formed on a metal surface is given.     

Fluid flow in a rotating curved rectangular duct

The fluid flowing in a rotating curved duct is subjected to both the Coriolis force due to a rotation and the centrifugal force due to a curvature. In this paper, the combined effects of the two forces on the flows in rotating curved rectangular ducts are examined numerically. According to the aspect ratio of the cross-section, the rectangular ducts are divided into three types: η>1, η=1, η<1, where η is the aspect ratio. The variations of the flow structures with the force ratio F (the ratio of the Corislis force to the centrifugal force) are studied in detail and many hitherto unknown flow patterns are found. The effects of the force ratio and the aspect ratio of the cross-section on the friction factor are also examined. Present results show both the characteristics of the secondary flow, axial flow and the natures of the friction factor.     

Spectroscopy of rotating linear dilaton black holes from boxed quasinormal modes

Numerical studies of the coupled Einstein‐Klein‐Gordon system have recently revealed that confined scalar fields generically collapse to form caged black holes. In the light of this finding, we analytically study the characteristic resonance spectra of the confined scalar fields in rotating linear dilaton black hole geometry. Confining mirrors (cage) are assumed to be placed in the near‐horizon region of a caged rotating linear dilaton black hole ( is the radius of the cage and r₂ represents the event horizon). The radial part of the Klein‐Gordon equation is written as a Schrödinger‐like wave equation, which reduces to a Bessel differential equation around the event horizon. Using analytical tools and proper boundary conditions, we obtain the boxed‐quasinormal mode frequencies of the caged rotating linear dilaton black hole. Finally, we employ Maggiore's method, which evaluates the transition frequency in the adiabatic invariant quantity from the highly damped quasinormal modes, in order to investigate the entropy/area spectra of the rotating linear dilaton black hole.     

The ideal relativistic rotating gas as a perfect fluid with spin

We show that the ideal relativistic spinning gas at complete thermodynamical equilibrium is a fluid with a non-vanishing spin density tensor σ_μν. After having obtained the expression of the local spin-dependent phase-space density f(x, p)_στ in the Boltzmann approximation, we derive the spin density tensor and show that it is proportional to the acceleration tensor Ω_μν constructed with the Frenet-Serret tetrad. We recover the proper generalization of the fundamental thermodynamical relation, involving an additional term −(1/2)Ω_μνσ^μν. We also show that the spin density tensor has a non-vanishing projection onto the four-velocity field, i.e. t^μ = σ_μνu^ν ≠ 0, in contrast to the common assumption t^μ = 0, known as Frenkel condition, in the thus-far proposed theories of relativistic fluids with spin. We briefly address the viewpoint of the accelerated observer and inertial spin effects.     

旋转热管生物反应器的流场模拟研究

采用热管技术对传统生物反应器进行革新,自主开发出一种适用于多种生物反应的新型生物反应器,提出了将热管本身作为搅拌轴的设计思想,同时以计算流体力学(CFD)为基础建立旋转热管生物反应器的数学模型,计算了不同雷诺数下此类搅拌轴的功率准数,并得到了功率曲线。采用标准k-ε湍流模型成功模拟了反应器内的速度分布,为反应器的优化设计提供了基础。