全文获取类型
收费全文 | 119850篇 |
免费 | 6277篇 |
国内免费 | 13788篇 |
专业分类
化学 | 69696篇 |
晶体学 | 1111篇 |
力学 | 2374篇 |
综合类 | 824篇 |
数学 | 12028篇 |
物理学 | 19170篇 |
综合类 | 34712篇 |
出版年
2024年 | 182篇 |
2023年 | 877篇 |
2022年 | 2253篇 |
2021年 | 2301篇 |
2020年 | 2646篇 |
2019年 | 2598篇 |
2018年 | 2298篇 |
2017年 | 3279篇 |
2016年 | 3516篇 |
2015年 | 3428篇 |
2014年 | 4294篇 |
2013年 | 7349篇 |
2012年 | 7835篇 |
2011年 | 6693篇 |
2010年 | 5467篇 |
2009年 | 6960篇 |
2008年 | 7397篇 |
2007年 | 8604篇 |
2006年 | 7973篇 |
2005年 | 6866篇 |
2004年 | 6353篇 |
2003年 | 5221篇 |
2002年 | 6128篇 |
2001年 | 3840篇 |
2000年 | 3541篇 |
1999年 | 3275篇 |
1998年 | 2674篇 |
1997年 | 2209篇 |
1996年 | 1892篇 |
1995年 | 1738篇 |
1994年 | 1611篇 |
1993年 | 1379篇 |
1992年 | 1285篇 |
1991年 | 980篇 |
1990年 | 822篇 |
1989年 | 785篇 |
1988年 | 585篇 |
1987年 | 436篇 |
1986年 | 342篇 |
1985年 | 241篇 |
1984年 | 237篇 |
1983年 | 135篇 |
1982年 | 208篇 |
1981年 | 172篇 |
1980年 | 191篇 |
1979年 | 177篇 |
1978年 | 164篇 |
1977年 | 121篇 |
1976年 | 105篇 |
1973年 | 66篇 |
排序方式: 共有10000条查询结果,搜索用时 109 毫秒
901.
本文第一部分主要把扭曲的方法运用到模上,从而得到扭曲模.作为特例,我们构造了H M的Smaush模和量子模.当K是有限维Hopf代数,证明K* M是一个右D(K)-Hopf模,因此得到了一个基本同构定理.第二部分主要把斜余配对双代数进行推广,得到了斜余配对Hopf模,并且给出判断斜余配对Hopf模的一个充要条件. 相似文献
902.
Binyuan Liu Yang Li Boo‐Gyo Shin Do Yeung Yoon IL Kim Li Zhang Weidong Yan 《Journal of polymer science. Part A, Polymer chemistry》2007,45(15):3391-3399
Three novel functionalized polynorbornenes (PNB) with pendant dimethyl carboxylate group (carboxylates—acetate, propionate, and butyrate) are synthesized as a vinyl‐type with a palladium (II) catalyst in high yield. The effects of size of substitutents, molar ratio of monomer to catalyst, solvent polarity, reaction time, and temperature on the polymerization of exo‐norbornene dimethyl propionate were systematically investigated. The low molar ratio and temperature, as well as high polarity of solvent, and long reaction time, are favorable for the enhancement of the monomer conversion, especially, the solvent have an obvious effect on the catalyst activity. The resulting poly(cis‐norbornene‐exo‐2,3‐dimethyl carboxylates) (PNB‐dimethyl carboxylates) show good solubility in common organic solvent and high thermal stability up to 360 °C. The glass transition temperature was detected by DMA at 331, 324, and 318 °C for acetate, propionate, and butyrate, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3391–3399, 2007 相似文献
903.
904.
Sylvie Large-Radix 《Journal of fluorine chemistry》2003,124(2):147-149
In the presence of a stoichiometric amount of Bu4NF·3H2O, (trifluoromethyl)trimethylsilane reacts with aromatic thiones in both thiophilic and carbophilic ways to deliver, in medium yield, a mixture of (trifluoromethylthio)diarylmethane and 1,1-diaryl-2,2,2-trifluoroethanethiol, the former product being the major one. 相似文献
905.
Stefanie M. Walz Thomas E. Malner Ulrich Mueller Rolf Muelhaupt 《Journal of Polymer Science.Polymer Physics》2003,41(4):360-367
We explored phase separation and self‐assembly of perfluoroalkyl segments at the surface of polymer films obtained from latices of semifluorinated acrylate copolymers and the corresponding latex blends of nonfluorinated and semifluorinated polyacrylates. With laser‐induced secondary mass spectrometry the fluorine distribution was measured after annealing above the minimum film‐forming temperature of the polymers up to a depth of several micrometers. Depth profiles of a semifluorinated acrylate homopolymer and latex blends thereof with fluorine‐free alkylacrylates with 25, 50, and 75 mol % semifluorinated acrylate as well as a copolymer comprised of alkyl acrylate and semifluorinated acrylate (50/50 mol %) were investigated. In the case of latex blends containing both semifluorinated polyacrylates and fluorine‐free or low‐fluorine polymers, self‐assembly accounted for enrichment of the perfluoroalkyl segments at the surface. Coatings exhibiting low surface energy and having a substantially reduced total fluorine content were obtained. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 360–367, 2003 相似文献
906.
The main objects of study in this article are two classes of Rankin–Selberg L-functions, namely L(s,f×g) and L(s, sym2(g)× sym2(g)), where f,g are newforms, holomorphic or of Maass type, on the upper half plane, and sym2(g) denotes the symmetric square lift of g to GL(3). We prove that in general, i.e., when these L-functions are not divisible by L-functions of quadratic characters (such divisibility happening rarely), they do not admit any LandauSiegel zeros. Such zeros, which are real and close to s=1, are highly mysterious and are not expected to occur. There are corollaries of our result, one of them being a strong lower bound for special value at s=1, which is of interest both geometrically and analytically. One also gets this way a good bound onthe norm of sym2(g). 相似文献
907.
In 1991, one of the authors showed the existence of quadratic transformations between the Painlevé VI equations with local monodromy differences (1/2, a, b, ±1/2) and (a, a, b, b). In the present paper we give concise forms of these transformations. They are related to the quadratic transformations obtained by Manin and Ramani–Grammaticos–Tamizhmani via Okamoto transformations. To avoid cumbersome expressions with differentiation, we use contiguous relations instead of the Okamoto transformations. The 1991 transformation is particularly important as it can be realized as a quadratic‐pull back transformation of isomonodromic Fuchsian equations. The new formulas are illustrated by derivation of explicit expressions for several complicated algebraic Painlevé VI functions. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
908.
恩施野生葛块根营养成分及微量元素硒的研究 总被引:1,自引:0,他引:1
用干燥法测定恩施的野生葛块根中干物质的质量分数,用水提法提取葛根中的粗淀粉并测定其质量分数,采用比色法测定干葛根及葛根粗淀粉中硒的质量分数。结果表明,恩施野生葛块根中干物质的质量分数为33.02%—38.26%,粗淀粉的质量分数为15.15%~18.79%,干物质硒的质量分数为1.69—2.66μg/g,粗淀粉中硒的质量分数为0.130—0.157μg/g,占总硒质量分数的5.64%~8.63%,适合开发各种富硒食品及药品,是一种较理想的保健品原料。 相似文献
909.
Leszek Wachowski Antoni Grodzicki Piotr Piszczek Monika Richert Magdalena Hofman 《Reaction Kinetics and Catalysis Letters》2007,91(1):93-99
Hydrogenation of styrene has been applied as a test reaction to study the catalytic activity of TiO2 deposited by the CVD (chemical vapour deposition) method on the surface of a carbonaceous material enriched in nitrogen (CN). 相似文献
910.
There is a general interest in ranking schemes applied to complex entities described by multiple attributes. Published rankings
for universities are in great demand but are also highly controversial. We compare two classification and ranking schemes
involving universities; one from a published report, ‘Top American Research Universities’ by the University of Florida's TheCenter and the other using DEA. Both approaches use the same data and model. We compare the two methods and discover important equivalences.
We conclude that the critical aspect in classification and ranking is the model. This suggests that DEA is a suitable tool
for these types of studies. 相似文献