The compounds KAs4O6 X (X=Cl,Br, I) and NH4As4O6 X (X=Br,I): Hydrothermal syntheses and structure determinations

The crystal structures of five isotypic hexagonal compounds with general formulaMAs₄O₆ X [M=K, NH₄;X=Cl, Br, I; space group: P622;Z=1] were determined from 370 single crystal X-ray data and refined toR values <0.05. The structure type is characterized by neutral charged [As₂O₃] sheets arranged parallel (00.1). The As atoms of neighbouring two sheets point to each other and the sheets are combined by interlayeredM andX atoms, respectively. TheM atoms are coordinated to twelve oxygen atoms, theX atoms are coordinated to twelve arsenic atoms. In both cases the coordination polyhedron is a hexagonal prism. The compounds were synthesized by thermal treatments of cubic As₂O₃ and potassium or ammonium haloids in a saturated aqueous solution of potassium acetate resp. ammonia [500 K, saturation vapour pressure].

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Die Verbindungen KAs₄O₆ X (X=Cl, Br, I) und NH₄As₄O₆ X (X=Br, I): Hydrothermalsynthese und Strukturbestimmung

Zusammenfassung Die Kristallstrukturen der fünf isotypen hexagonalen Verbindungen mit der allgemeinen FormelMAs₄O₆ X [M=K, NH₄;X=Cl, Br, I; Raumgruppe: P622;Z=1] wurden anhand von 370 Einkristall-Röntgendaten bestimmt und aufR-Werte <0.05 verfeinert. Der Strukturtyp ist ausgezeichnet durch neutrale [As₂O₃]-Schichten, die parallel (00.1) angeordnet sind. Die As-Atome zweier benachbarter Schichten weisen jeweils aufeinander zu, und die Schichten selbst werden durch zwischengelagerteM- bzw.X-Atome verbunden. DieM-Atome werden jeweils von zwölf O-Atomen, dieX-Atome von zwölf As-Atomen umgeben. Das Koordinationspolyeder ist in beiden Fällen ein hexagonales Primsa. Die einzelnen Verbindungen wurden unter Hydrothermalbedingungen aus kubischem As₂O₃ und dem jeweiligen Kalium- oder Ammoniumhalogenid in einer gesättigten wäßrigen Lösung von Kaliumacetat bzw. Ammoniak synthetisiert (500 K, Sättigungsdampfdruck).

     

B样条曲线数控R参数编程加工

针对802S等中低档数控系统内存有限、加工由B样条曲线曲面组成的复杂零件轮廓过程中所遇到的问题,研究了使用数控系统R参数编程功能及指令实现德布尔算法计算B样条曲线上任一点坐标值的方法,生成了较短的R参数数控程序加工代码。使得中低挡数控系统中存入缩短的复杂零件程序进行快速加工成为可能。最后经802S系统数控铣床实际加工运行凸轮样条曲线轮廓段R参数加工程序验证缩短程序正确。零件精度满足设计要求。     

基于MCNP5和ORIGEN2.1程序的停堆剂量程序开发与 初步验证

为了准确分析核设施停机后周围空间的三维辐射剂量场分布情况,基于严格两步法(rigorous two step method,R2S)停堆剂量计算的方法,开发了基于蒙特卡罗输运计算程序MCNP5和燃耗计算程序ORGEN2. 1耦合的三维停堆剂量计算程序M OCA,实现了中子输运计算、材料活化计算和光子剂量计算的自动耦合,并通过中子辐照例题与Super MC程序进行对比验证,结果表明MOCA的计算结果与Super MC计算的结果吻合较好,可以为核设施的运维检修以及退役的剂量率空间分布提供参考数据。     

Synthesis of two new thiazolidines and their hepatoprotective effects

Two new 2-substituted thiazolidine-4（R）-carboxylic acids （TCAs）, 2-glusosaminal-TCA （GIcNH2Cys） and 2-N-acetyl-glueosanlinal-TCA （GlcNAeCys）, were synthesized. Their protective effects against liver toxicity induced by acetaminophen （APAP） were investigated in a mice model. The resuits demonstrate that administration of TCAs （ i. p. , 800 mg/kg） 30 min after APAP challenge efficiently decrease ALF, AST, and LDH levels in liver. GlcNAcCys shows the best proteetive eftects, decreasing ALT, AST and LDH levels to 63%, 18.4% and 37% of the APAP group respectively. Comparison with the control showed that APAP greatly decreases total sulfhydlyl （T-SH） levels （43%）, non-protein hound sulfhydryl （NP-SH） levels （50%） and total antioxidative capabilities （57%） in the liver 24 hr after challenge. TCAs treatments 30min after APAP challenge significantly elevate sulfhydryl levels and total antioxidative capabilities. APAP administration also markedly （P 〈 0.05） increases liver lipid peroxidation to 1.65 and 1.17 times that of the control 4 hr and 24 hr after APAP administration respectively. TCAs treatments can inhibit lipid peroxidation as measured by decreased malondialdehyde （MDA） contents in liver. The histopathological results also further confirm the hepatoprotective effects of TCAs. In conclusion, our data show that TCAs, GleNAcCys particularly, have hepatoprotective anti antioxidant etfects.     

润滑油对水平管外R134a池沸腾换热的影响

本文对不同含油量下三根水平蒸发管外R134a的池沸腾换热性能进行了试验研究.实验表明润滑油对蒸发表面的换热性能的影响因管型和含油量而异.     

基于关联数据技术的地质资料实体建模与Web发布

我国在长期的地质调查工作中,积累了大量的地质资料。为了方便这些资料的分布式存储和管理,并实现共享和关联,尝试将关联数据技术引入到地质资料中,对原始数据进行RDF建模,从而为广大地调人员提供统一的查询入口。研究以关联数据四项基本原则为指导,参考其他领域关联数据发布框架,根据地质资料自身数据特点,建立了地质资料关联数据发布流程。利用D2R发布工具,以20 000条地质资料为试验,将存储于关系型数据库中的元数据映射为RDF格式,并通过Web发布,实现了地质资料关联数据的发布。     

On the Ono invariants of imaginary quadratic number fields

J. Cohen, J. Sonn, F. Sairaiji and K. Shimizu proved that there are only finitely many imaginary quadratic number fields K whose Ono invariants OnoK are equal to their class numbers hK. Assuming a Restricted Riemann Hypothesis, namely that the Dedekind zeta functions of imaginary quadratic number fields K have no Siegel zeros, we determine all these K's. There are 114 such K's. We also prove that we are missing at most one such K. M. Ishibashi proved that if OnoK is large enough compared with hK, then the ideal class groups of K is cyclic. We give a short proof and a precision of Ishibashi's result. We prove that there are only finitely many imaginary quadratic number fields K satisfying Ishibashi's sufficient condition. Assuming our Restricted Riemann Hypothesis, we prove that the absolute values dK of their discriminants are less than 2.3⋅¹⁰⁹. We determine all these K's with dK?¹⁰⁶. There are 76 such K's. We prove that there is at most one such K with dK?1.8⋅¹⁰¹¹.     

Irreducible algebraic integers in short intervals

We study distribution of irreducible algebraic integers in short intervals and prove that if the class number of an algebraic number field K exceeds 2, every interval of the form (x, x + x ^θ) with a fixed θ > 1/2 contains absolute value of the norm of an irreducible algebraic integer from K provided x ≥ x ₀. The constant x ₀ effectively depends on K and θ. The author was supported in part by the grant no. N N201 1482 33 from the Polish Ministry of Science and Higher Education.     

Homotopy monomorphisms and H-splitting in loop space fibrations

Let be a fibration, the holonomy action of this fibration and the connecting map. It is shown that if the fibre F admits an H-structure ν such that ρ?ν○(1×∂) (principal fibrations of all kinds satisfy such a condition), then i is a monomorphism if and only if it is weak monomorphism, the latter is equivalent to that Ωp has a homotopy right inverse Γ. If in addition Γ is an H-map, then ΩE has the same H-type as ΩB×ΩF.