两种新型卟啉吡啶季铵盐的合成

合成了两种新型卟啉吡啶季铵盐:溴化5-[4-N-(对硝基)苄铵基吡啶基]-10,15,20-三(4-N吡啶基)卟啉和氯化5-[4-N-(对甲氧基)苄铵基吡啶基]-10,15,20-三(4-N-吡啶基)卟啉.这两种化合物尚未见文献报道,它们的结构分别由紫外可见光谱、红外光谱、核磁共振谱、质谱、元素分析得到确证.     

Facile Desulfurization of Thioamides and Thioureas with Tetrabutylammonium Periodate under Mild Conditions

Summary. Thioamides and thioureas were reacted with tetrabutylammonium periodate at room temperature to afford the corresponding amides and ureas, respectively, under aprotic conditions.     

合肥地区第四纪孢粉组合及古植被、古气候研究

本文孢粉组合是从合肥地区城建施工单位工程钻孔中获得。根据,木本、草本、和蕨类植物在钻孔剖面中的变化规律,分两个孢粉组合带。 第一组合带,木本植物占17.62％,乔木层中的落叶阔叶层片以栎、榆、桦为主要树种,针叶层片中以松属,油杉属为优势树种,蕨类植物与草本植物计占15—70％,以蕨类中的卷柏,紫萁,水龙骨及草本类的禾本科,菊科,蒿属,十字花科为草木本层中的主要成分,低洼的地沼水域中繁殖大量环纹藻。 第二组合带的第一亚组合,木本植物的属种明显下降,其含量则上升为38—94％乔木层非常单调,松属几乎独占了贫脊的山岗坡地,蕨类植物踪迹稀少,禾本科、毛莨科、蒿属,豆科等草本层散生于河谷岸边及低矮的坡地。 第二亚组合,木本植物占27—56％,乔木层中:针叶层片内以松属,油杉属为建群主要树种,落叶阔叶层片只占3.3—9.0％,栎、柳、胡桃、枫杨、榆、漆树等均有一定含量。蕨类和草本植物占2.5—14 5％,蕨类植物类型较少,水龙骨为植被中的常见物种,草本类以禾本科,毛莨科,蒿属为主,其它属种出现不多,这个阶段草本层仍不大兴旺。 以上两个组合带中末发现冷杉,云杉的踪影,桦属含量极低,植被反映为温湿或温凉的气候,因此两个组合不可能为晚冰期,其地层时代应晚于晚更新世,这样可确认合肥地区为全新世晚期,     

Simultaneous determination of bromide and iodide ions by capillary isotachophoresis using quaternary ammonium salts

Bromide and iodide ions were determined simultaneously by capillary isotachophoresis using an aqueous electrolyte system; the separation principle was based on the ion-pairing equilibria between tetradecyldimethylbenzylammonium ion and these anions in the leading electrolyte. The interaction between iodide ion and tetradecyldimethylbenzylammonium ion was stronger than that for bromide ion. Thus complete separation of bromide and iodide ions could be obtained by using a leading electrolyte containing 1.5 mM tetradecyldimethylbenzylammonium ion. The pH of the leading electrolyte was adjusted to 5.0. The relative standard deviations of the zone length for bromide and iodide ions were 1.1 and 1.2%, respectively, when mixture of 3.0 mM of these ions was analysed. A 150-μl volume could be injected for the simultaneous determination of low concentrations of bromide and iodide ions.     

Synthesis of Chiral Ionic Polymers Containing Quaternary Ammonium Sulfonate Structure and their Catalytic Activity in Asymmetric Alkylation

Repeated reaction between chiral quaternary ammonium dimer and disodium disulfonate gave the ionic polymer, which contains chiral quaternary ammonium sulfonate structure as a repeating unit. This chiral ionic polymer showed an excellent catalytic activity in asymmetric alkylation reaction. With the chiral ionic polymer catalysts, high level of enantioselectivities up to 97% ee were attained.     

季铵盐胶束的制备及其抗菌性能研究

为了研究季铵盐胶束是以胶束的形式抗菌还是以胶束解体后的单体形式与细胞膜结合达到抗菌效果,制备了一种季铵盐表面活性剂,该表面活性剂可以自组装成非交联胶束,还可以通过含有酯键的交联剂获得表面交联胶束.交联胶束在脂肪酶的作用下能解交联形成解交联胶束.利用核磁共振氢谱和动态光散射对合成的表面活性剂进行了分析,通过最低抑菌浓度和透射电子显微镜探讨了胶束的抗菌性能.     

C12-s-C12•2Br和C12En混合水溶液的胶团化行为

季铵盐二聚表面活性剂C12 s C12•2Br（s=2、3、4、6）和非离子表面活性剂C12E10或C12E23在水溶液中生成混合胶团.其临界胶团总浓度cmcT值介于二元复配体系中各组分的临界胶团浓度和之间.当添加少量非离子型表面活性剂（在水溶液中的摩尔分数α2=0.1）时,混合胶团中C12E10或C12E23的摩尔分数均已超过0.35;随着溶液中非离子型表面活性剂含量的增大,混合胶团中逐渐以C12E10或C12E23成分为主.     

壳聚糖季铵盐的合成及结构表征

用异相法合成了水溶性壳聚糖季铵盐衍生物，并用红外光谱及核磁共振谱进行结构表征。结果表明：在中性反应条件下，壳聚糖分子的季铵盐衍生化反应主要发生于亲该中心Ｃ２位的氨基上，所合成的壳聚糖季铵盐衍生物可直接溶解于水。其水溶液可以任意比例与乙醇、丙二醇、甘油等混溶。     

季铵盐固相催化使聚氯乙烯脱HCl

通过将季铵盐与聚氯乙烯(PVC)混溶成膜,使其在固相脱HCl,研究了催化剂对PVC脱HCl反应速度和产物结构的影响以及固相反应与温度、时间的关系.发现在催化性能上下基铵盐比乙基铵盐好得多,根据实验结果提出了季铵盐通过分解成叔胺实现催化的机理.