铽－甲基吲哚乙酰丙酮三元配合物发光过程研究

测定和分析了ＲＥ．Ｌ１．Ｌ２（ＲＥ＝Ｔｂ（Ⅲ）、Ｇｄ（Ⅲ），Ｌ１＝３Ｍ（３甲基吲哚－１－乙酰基丙酮），Ｌ２＝ＴＰＰＯ、Ｐｈｅｎ、Ｄｉｐｙ）三元配合物的荧光光谱、磷光光谱、磷光寿命及变温荧光光谱等．讨论了Ｔｂ（Ⅲ）与配体之间的能级匹配和Ｌ１与Ｌ２的三重态之间传能的问题，说明了影响这些三元配合物荧光效率的主要因素及其发光过程．     

Range reliability in random walks

This paper introduces a definition of reliability based on a process range. Thus, process failure is defined when the range of a process first reaches a given and unacceptable level. The Mean Time To Failure (MTTF) which is denned as the mean of the first time for a range to attain a given amplitude is then calculated for an asymmetric random walk process. The probability distribution of the range is then given and the process reliability over long periods of system operations are then calculated. Applications such as the control of wings movements, stock price and exchange rates volatility (defined in terms of reliability) are also used to motivate the usefulness of range processes in reliability studies. Finally, we point out that there is necessarily a relationship between the range reliability and the propensity of a series to become chaotic.     

Game Theory Study on Distributors＇ Alliance to Gain Competitive Advantage in Marketing Channel

Using the Cournot Game Model, this paper has analyzed the motivation of the distributors＇ alliance to gain competitive advantage in marketing channel. At first, this paper separately analyzed the advantage of alliance in the situation of one- short game and infinitely repeated game, then, based on the analysis of distributors＇ betrayal of the alliance under infinitely repeated game, the conditions to maintain the distributors alliance are put forward and discussed.     

具有新光学性质的Zn-Zn2SiO4纳米同轴线阵列

采用气相沉积技术在Si衬底上生长了Zn-Zn₂SiO₄芯-壳结构纳米同轴线阵列。根部呈笋状的纳米同轴线,直径约100nm,长度可以超过10μm;同轴线芯直径约50nm、壳层厚约25nm。通过X射线衍射的表征以及能量色散谱的线扫描,确定纳米同轴线的芯为Zn,壳层为Zn₂SiO₄。我们提出了一种新的生长机制,同时也为生长均匀的纳米同轴线提供一种新的技术。观察阴极荧光谱发现,纳米同轴线有三个主要发光带:强度最大的中紫外300nm发光、较弱的可见光区560nm以及红外谱区865nm的发光。对纳米同轴线截面的300nm发光峰观测发现,中紫外发光来源于Zn₂SiO₄壳层。正是这种同轴线的结构,使得其具备特殊的光学性质。     

Synthesis and characterization of poly(ethylene oxide‐co‐ethylene carbonate) macromonomers and their use in the preparation of crosslinked polymer electrolytes

Methacrylate‐functionalized poly(ethylene oxide‐co‐ethylene carbonate) macromonomers were prepared in two steps by the anionic ring‐opening polymerization of ethylene carbonate at 180 °C, with potassium methoxide as the initiator, followed by the reaction of the terminal hydroxyl groups of the polymers with methacryloyl chloride. The molecular weight of the polymer went through a maximum after approximately 45 min of polymerization, and the content of ethylene carbonate units in the polymer decreased with the reaction time. A polymer having a number‐average molecular weight of 2650 g mol^?1 and an ethylene carbonate content of 28 mol % was selected and used to prepare a macromonomer, which was subsequently polymerized by UV irradiation in the presence of different concentrations of lithium bis(trifluoromethanesulfonyl)imide salt. The resulting self‐supportive crosslinked polymer electrolyte membranes reached ionic conductivities of 6.3 × 10^?6 S cm^?1 at 20 °C. The coordination of the lithium ions by both the ether and carbonate oxygens in the polymer structure was indicated by Fourier transform infrared spectroscopy. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2195–2205, 2006     

青海城镇体系发展的历史轨迹与动力

青海城镇体系经历了发韧期、奠基期、转型期3个发展历程.在这一过程中,湟水谷地最先拉开了城镇发展的历史帏幕,随后逐步向西扩展进入青海湖地区.宏观上,从农耕区向农牧交错区渗透,进而向游牧区拓展,反映了社会历史进程和地域开发进程的调控作用,因此城镇分布数量和密度呈现出农耕区—农牧交错区—游牧区逐级递减的趋势.中观上,以河流为脉络,城镇发展或溯源而上伸入高原腹地,或向河谷两岸推进,进入山区,表现为从优势生存空间向劣势生存空间的时空转化,城镇数量与密度呈现出川水地区—浅山地区—脑山地区的递减趋势.微观上,河谷农耕区城镇选址多位于河流阶地上,土地肥沃,取水便利;而牧区城镇的选址却往往与水草丰美的牧场相关,映射出古代城镇对自然条件和自然物质基础的依赖性.总体而言,青海省城镇兴起和发展的动力,主要来自于外部中央行政建制和军事据点的设置,而非城镇内部社会经济自我发展.就单个城镇而言,民族文化、民族宗教与民族贸易的亲合关系和响应力,是城镇成长的主要推进剂.     

从民问借贷的保护机制看惯例的经济价值

运用博弈论理论分析了民间借贷的保护机制——惯例形成的根据。进一步研究了惯例的经济价值——节省社会交易成本，并实现了非正式制度的资源配置功能。     

On the behavior of ECN/RED gateways under a large number of TCP flows: Limit theorems

We consider a discrete-time stochastic model of an ECN/RED gateway where competing TCP sources share the link capacity. As the number of competing flows becomes large, the asymptotic queue behavior (normalized by the number of flows) at the gateway can be described by a simple recursion and the throughput behavior of individual TCP flows becomes asymptotically independent. A Central Limit Theorem complement is also presented, yielding a more accurate characterization of the asymptotic queue size. These results suggest a scalable yet accurate model of this complex large-scale stochastic feedback system, and crisply reveal the sources of queue fluctuations. This work was prepared through collaborative participation in the Communications and Networks Consortium sponsored by the U.S. Army Research Laboratory under the Collaborative Technology Alliance Program, Cooperative Agreement DAAD19-01-2-0011. This work was also supported by the Space and Naval Warfare Systems Center—San Diego under Contract No: N66001-00-C-8063. The views and conclusions contained in this document are those of the authors and should not be interpreted as representing the official policies, either expressed or implied, of the Army Research Laboratory or the U.S. Government.     

Lévy processes and Fourier multipliers

We study Fourier multipliers which result from modulating jumps of Lévy processes. Using the theory of martingale transforms we prove that these operators are bounded in Lp(Rd) for 1<p<∞ and we obtain the same explicit bound for their norm as the one known for the second order Riesz transforms.     

少齿差偏摆齿轮传动机构平衡的探讨

少齿差偏摆锥齿轮传动有传动比大、结构紧凑、重量轻、承载力大等优点,但存在着离心惯性力和轴向惯性力,因而引起多方向的振动。本文通过对运动的分析探讨解决此类机构平衡问题的方法。