Strongly localized states in a single carbon nanotube with polymer molecules

A single-walled carbon nanotube (SWCNT) with conjugated polymer molecules is analyzed via optical spectroscopy. The presence of strongly localized excitonic states in the SWCNT is confirmed using time-integrated photoluminescence (PL). The PL spectrum exhibits extremely narrow width (~0.8 meV) which is attributed to the strong confinement of the states by polymer molecules. In addition, I observed that the excited states are gradually filled as a function of the excitation power, which supports the localized excitonic behavior. Only the ground excitonic state is observed at low excitation powers, but three additional PL peaks appear as the excitation power is increased. Especially, the power-dependent PL spectrum shows a blueshift and increased width, which can be elucidated in terms of quantum confined stark effect and the screening of induced electric fields. Overall, I demonstrate that the presence of polymer molecules induces several localized states in a single SWCNT.     

应用于染料敏化太阳能电池的基于染料R6的含有不同吸电子基团的有机染料的理论研究

Dye-sensitized solar cells (DSSCs) are the most promising alternatives to traditional fossil energy because of their advantages of low production cost, facile structure, relatively low environmental impact, relatively high photoelectronic absorption efficiency, and overall high efficiency. In addition, several studies on sensitizers as vital components have been conducted over the last three decades. Compared to metal dyes, metal-free organic dyes have been considered as promising candidates because of their simple fabrication, multiple structures, high molar absorption coefficients, easily tunable properties, and environmental friendliness. In this study, we systematically investigated the optoelectronic properties of six metal-free organic donor-acceptor dyes (RD1–6) derived from the known dye R6 by using the density functional theory (DFT) and time-dependent DFT methods. Cell performance parameters were discussed, including the geometrical and electronic structures, absorption spectrum, adsorption energy, light harvesting efficiency (LHE) curve, predictive short circuit current density (J_sc^Pred.), predictive open circuit voltage (V_oc^Pred.), and theoretical power conversion efficiency (PCE). Results revealed that all the designed dyes exhibited high theoretical PCE. In particular, dyes RD1, 2, and 4–6 showed greater conjugations, and dyes RD1–3 had smaller energy gaps than those of the reference dye. In addition, dyes RD1–3, 5, and 6 exhibited better light harvesting capacities that covered the entire visible region and extended to the near-infrared region with obviously red-shift maximum absorption wavelengths (λ_max), wider LHE curves, and higher J_sc^Pred. as compared to the reference dye. It was critical that dyes RD1 and 2 not only have greater conjugations and narrow band gaps but also good light harvesting capacities with more than 56-nm red-shift maximum absorption wavelengths and broadened LHE curves than those of the reference dye. Notably, mainly because of an average increment of 12.0% of J_sc^Pred., a remarkable increment of the theoretical power conversion efficiency was observed from 12.6% for dye R6 to 14.1% for dyes RD1 and 2. Thus, dyes RD1 and 2 exhibited superior cell performances and could be promising sensitizer candidates for highly efficient DSSCs. These results could be used to guide effective synthetic efforts in the discovery of efficient metal-free organic dye sensitizers in DSSCs.     

营销组合理论演变的动因分析

1960年,麦卡锡创立了经典的4Ps营销组合理论。在随后的40多年历史发展中,营销组合理论发展迅速,各种理论层出不穷,6Ps、7Ps、10Ps、4Cs、4R s等学说百家争鸣。营销理念由注重短期交易关系转变为对长期交易关系的注重是营销组合理论发展的思想背景,而企业组织结构柔性化和企业交易控制权弱化则是推动营销组合理论演变的双重最终动因。     

幂格

本文引入了幂格的概念并讨论了其相关性质。     

On the power graph and the reduced power graph of a finite group

In this paper, for a finite group, we investigate to what extent its directed (resp. undirected) reduced power graph determines its directed power graph (resp. reduced power graph). Moreover, we investigate the determination of the orders of the elements of a finite group from its directed (resp. undirected) reduced power graph. Consequently, we show that some classes of finite groups are recognizable from their undirected reduced power graphs. Also, we study the relationship between the isomorphism classes of groups corresponding to the equivalence relations induced by the isomorphism of each of these graphs on the set of all finite groups.     

阳极界面修饰对钙钛矿太阳能电池性能的影响

采用在聚(3,4-乙撑二氧噻吩)∶聚苯乙烯磺酸(Poly(3,4-ethylenedioxythiophene)∶Poly(styrenesulfonate),PEDOT∶PSS)阳极界面层上直接旋涂二甲基亚砜(Dimethyl Sulfoxide,DMSO)的方法,对PEDOT∶PSS薄膜进行修饰,以提高所制得的钙钛矿太阳能电池器件性能.在5000rpm转速条件下旋涂DMSO后,器件的能量转换效率达到11.43%,与PEDOT∶PSS阳极界面层未做任何修饰的器件相比,效率提高了29.15%.测试表征了修饰前后PEDOT∶PSS薄膜的透光性、表面形貌、电导率、器件的外量子效率曲线以及器件在光照和暗态下的J-V特性曲线,分析了器件性能提高的原因.结果表明:经过修饰的PEDOT∶PSS薄膜导电性显著增强,从而更加有利于器件阳极对空穴的抽取和收集;较未修饰时,器件的短路电流密度得到了大幅度提升,进而使得器件获得更高的能量转换效率.     

功率超声对溶液性质的影响

本文研究了在功率超声作用下，电解质溶液，小分子溶液和大分子溶液的粘度，表面张力和电导率等物理化学性质的变化规律。实验结果表明，在超声波作用下，溶液的粘度和表面张力暂时下降，而电导率长期升高。     

超导低电阻接头衰减法测试过程中的拟合偏差控制

超导技术在许多高新技术领域有着广泛而深远的应用前景,其中超导导体接头技术是超导发展过程中必不可少的关键环节之一,快速而又准确地评估低电阻接头显得尤为重要.本文在考虑超导体的E-J特性后,针对目前低电阻接头采用的衰减法测量,计算得出感应电流完整的衰减曲线方程-幂函数方程.对比目前广泛采用的指数方程拟合与采用幂函数方程拟合的偏差,指出采用指数方程代替幂函数方程拟合的必要条件,为接头电阻衰减法测试,尤其是低电阻接头情况下的测量提供参考.     

Development of superconducting power devices in Europe

Europe celebrated last year (2008) the 100-year anniversary of the first liquefaction of helium by H. Kammerling Onnes in Leiden. It led to the discovery of superconductivity in 1911. Europe is still active in the development of superconducting (SC) devices. The discovery of high critical temperature materials in 1986, again in Europe, has opened a lot of opportunities for SC devices by broking the 4 K cryogenic bottleneck.     

粉体材料颗粒堆积状态对收缩的影响

为提高粉体材料颗粒堆积状态,获得更佳工作性能,各研究人员致力于改善水泥颗粒粒径分布或掺加不同粒径粉体材料。本文通过对不同水泥品种、不同矿物掺合材进行堆积密度及流动度试验结合粉煤灰和硅粉化学收缩实验,从用水量及孔隙结构两方面阐明颗粒堆积状态对收缩的影响。