全文获取类型
收费全文 | 6048篇 |
免费 | 133篇 |
国内免费 | 626篇 |
专业分类
化学 | 2466篇 |
晶体学 | 50篇 |
力学 | 342篇 |
综合类 | 1篇 |
数学 | 251篇 |
物理学 | 3230篇 |
综合类 | 467篇 |
出版年
2024年 | 7篇 |
2023年 | 68篇 |
2022年 | 59篇 |
2021年 | 54篇 |
2020年 | 104篇 |
2019年 | 96篇 |
2018年 | 93篇 |
2017年 | 129篇 |
2016年 | 163篇 |
2015年 | 180篇 |
2014年 | 285篇 |
2013年 | 603篇 |
2012年 | 266篇 |
2011年 | 492篇 |
2010年 | 359篇 |
2009年 | 417篇 |
2008年 | 406篇 |
2007年 | 406篇 |
2006年 | 337篇 |
2005年 | 243篇 |
2004年 | 247篇 |
2003年 | 199篇 |
2002年 | 196篇 |
2001年 | 162篇 |
2000年 | 178篇 |
1999年 | 131篇 |
1998年 | 137篇 |
1997年 | 97篇 |
1996年 | 85篇 |
1995年 | 98篇 |
1994年 | 82篇 |
1993年 | 67篇 |
1992年 | 74篇 |
1991年 | 56篇 |
1990年 | 39篇 |
1989年 | 42篇 |
1988年 | 40篇 |
1987年 | 24篇 |
1986年 | 15篇 |
1985年 | 11篇 |
1984年 | 12篇 |
1983年 | 7篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1976年 | 3篇 |
1974年 | 2篇 |
1973年 | 6篇 |
排序方式: 共有6807条查询结果,搜索用时 15 毫秒
31.
As predicted by Haldane, spin, S=1 one-dimensional (1D) Heisenberg antiferromagnet (HAF) has an energy gap between the singlet ground state and first excited triplet. On application of magnetic field, the triplet state Zeeman splits and the energy of one of the triplet state becomes zero at a critical field, Hc. Above Hc the system recovers magnetism. Then, we expect that a quasi-1D HAF will show a magnetic long-range ordering (LRO) at low temperatures due to the inter-chain coupling. This field-induced LRO has not been observed before due to complication of the crystal structure in the materials studied so far and/or technical difficulty.From a heat capacity measurement on a single crystal of an S=1 quasi-Q1D HAF, Ni(C5H14N2)2N3(PF6), we found an anomaly at a temperature in finite fields indicating a field-induced phase transition. A magnetic LRO is confirmed by a neutron diffraction measurement on the same sample. The temperature versus magnetic field phase diagram of this compound is constructed and discussed. 相似文献
32.
33.
Naoki Miyamoto Shusuke Nisiyama Satoshi Tomioka Takeaki Enoto 《Optics Communications》2007,272(1):67-72
We utilize nitroanisole, that absorbs infrared (IR) radiation as heat, as an optical modulation device based on a thermal process. The nitroanisole exhibits a thermal lens effect, i.e. a temperature dependent refractive index. Hence, the nitroanisole can induce phase modulation to visible light, in direct response to intensity of the incident IR radiation. The proposed method can be used to obtain the phase modulation distribution that corresponds to the IR intensity distribution, i.e. the IR hologram itself, on the nitroanisole by examining the phase map of visible light that is modulated upon passing through the nitroanisole. The IR wavefront can be reconstructed by calculating extracted IR holograms through the Fresnel transform. It is verified that both the amplitude and the phase of the IR wavefront can be reconstructed accurately by proposed method. 相似文献
34.
利用傅里叶变温红外光谱仪分别测定了三羟甲基甲胺(TAM)、季戊四醇(PE)及其二元体系变温红外谱。实验表明,多元醇分子中羟基吸收峰随温度升高耐发生位移向高波数移动,此结果既能反映多元醇及其二体系固-固相变的温度区间,又与转变热相对应,从而揭示了多元醇及其二元体系固-固相变贮热的机理。 相似文献
35.
We report the coexistence of γ(γ′) and θ alumina grown on the CoAl(1 0 0) surface. Both phases were observed after annealing of alumina at 1150 K by means of scanning tunnelling microscopy (STM). The crystal structures of γ(γ′) and θ alumina were indexed based on low energy electron diffraction (LEED) and STM experimental data. 相似文献
36.
We use the PCP-SAFT equation of state, which is of the Van der Waals type and has a sound physical basis, to predict mixture properties, such as vapor–liquid and liquid–liquid equilibria, as well as excess enthalpies. We use molecular properties, such as dipole moment, quadrupole moment, polarizability and dispersion interaction coefficients, that have been determined quantum mechanically in Part I of this publication and adjust the remaining three pure compound parameters to pure compound data. We finally present a new combination rule for the dispersion energy parameter ? that is based on the quantum mechanically determined data. The predictions based on quantum mechanically determined pure compound properties along with the new combination rule show an improved performance compared to the original PCP-SAFT combination rule. 相似文献
37.
用不同的固相微萃取(SPME)针头结合气相色谱-质谱分析对生活污水进行提取、浓缩、分离、测定,对照结果表明,用聚硅氧烷涂层可以减少一次分析化合物的种类,提高分析的准确性。 相似文献
38.
采用Monte Carlo模拟方法研究了多嵌段聚合物在A/B/嵌段聚合物三组份体系作为相容剂使用的有效性.占总体积19%的A组份在体系中为分散相.模拟结果显示了两嵌段和多嵌段聚合物在界面上的聚集行为,以及如何影响这个不相容体系的相形为.两嵌段聚合物趋于直立在相界面上,而多嵌段聚合物更容易横跨在相界面上并占据较大的界面积.从而导致多嵌段聚合物更有效的阻止体系相分离的发生. 相似文献
39.
Hollow particles with interconnected cavities have been prepared by a simple modified suspension polymerization of acrylate monomers in the incorporation of a phase inversion process and polymerizable emulsifier. The morphology of particles has been characterized by scanning electron micrographs (SEMs). Based on observations made using an optical microscope equipped with a digital camera and SEM images of particles obtained under different conditions, the formation mechanisms for multiporous hollow particles are discussed. 相似文献
40.
M.Yu. Tretyakov V.V. Parshin M.A. Koshelev A.P. Shkaev A.F. Krupnov 《Journal of Molecular Spectroscopy》2006,238(1):91-97
Extension of the working frequency of modern resonator spectrometers into submillimeter wave range is described. Experimental record of atmospheric absorption spectrum covering 45-370 GHz range is demonstrated for the first time, and measured water vapor J′ka′, kc′-Jka, kc = 51,5-42,2 at 325 GHz line parameters are presented. For the first time pressure lineshift for the 325-GHz water vapor line is measured. Further extension of working range is discussed. New estimations of physical limits of time needed for measurements of absorption in the whole Backward Wave Oscillator (BWO) range are given for phase continuous synthesizer regime. Basic schemes of fast broadband continuous phase synthesized sources are discussed. Verification of the previous measurements of water vapor 31,3-22,0 at 183 GHz line parameters is presented. Comparisons with ringdown resonator spectrometers are given. 相似文献