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排序方式: 共有1621条查询结果,搜索用时 15 毫秒
61.
"在Pt/Ti/SiO2/Si基片上用溶胶-凝胶法生长制备了PZT(Pb(Zr1-xTix)O3)复合梯度铁电薄膜. 薄膜最终结构由6层组成,"向上"梯度薄膜在Pt底电极上的第一层从PbZrO3开始,顶层是PZT(50/50),即第一层是PbZrO3,第二层PZT90/10 (10%Ti),第三层是PZT80/20,第四层PZT70/30,第五层PZT60/40,第六层PZT50/50.每一层与此相反的是"向下"梯度PZT薄膜.用X射线衍射、俄歇电子能谱和阻抗分析来研究梯度薄膜的结构与介电特性.600 相似文献
62.
In ESR dating of Early Pleistocene fossil tooth enamel samples, the fitting function used for the evaluation of the DE value is undoubtedly among the major sources of uncertainty. Dose recovery tests performed on fossil tooth enamel showing DE values >1,000 Gy demonstrate: (i) that high precision ESR measurements (<0.5%) and high DE reproducibility (<5%) may be achieved; (ii) the appropriateness of the Double Saturating Exponential (DSE) fitting function for ESR dose reconstruction. In contrast, the SSE function, which has been almost exclusively used so far, does simply not correctly describe the behavior of the radiation induced ESR signal of tooth enamel with the dose.Several fitting functions and data weighting options were tested and the combination of a DSE with data weighted by the inverse of the squared intensities is the procedure providing the most accurate DE results. However, the SSE may nevertheless sometimes produce consistent results if Dmax does not exceed 6*DE. Further work is required in that direction in order to determine more precisely in which conditions the SSE could be used as a fair approximation of the DSE function for these samples. 相似文献
63.
建立微波消解–ICP–OES法测定陶土中铅和镉含量的方法。采用氢氟酸–硝酸作为消解液,微波消解法处理样品,消解液定容后直接进入耐氢氟酸的进样系统,用ICP–OES法测定陶土中重金属铅和镉的含量。结果表明,Pb和Cd检出限分别为0.027μg/m L和0.011μg/m L,回收率分别为90.5%~98.8%和95.0%~98.4%,测定结果相对标准偏差分别为1.38%和2.17%(n=7)。该方法具有快速、准确、灵敏度高等优点,适用于陶土中铅和镉含量的检测。 相似文献
64.
65.
Zircon U-Pb ages of granites at Changba and Huangzhuguan in western Qinling and implications for source nature 总被引:2,自引:0,他引:2
Mesozoic granitoids are widespread in the Qinling-Dabie-Sulu orogenic belt. Precise U-Pb dating on these granitoids can reveal
the evolution of the continental collision orogen and thus provide information on the nature of magma sources. This study
presents zircon LA-ICP-MS U-Pb dating and whole-rock geochemical analyses for two intrusions at Changba and Huangzhuguan in
western Qinling. Zircon U-Pb ages for central and marginal phases of the Huangzhuguang intrusion are 214±1 Ma and 213±3 Ma,
respectively. Zircons from the Changba intrusion yield a dominant cluster with an U-Pb age of 213±2 Ma. Collectively, these
ages are younger than ages of 220 to 240 Ma for ultrahigh-pressure metamorphism due to the continental collision between the
South China Block and the North China Block, corresponding to syn-exhumation magmatism. Some inherited zircons occur in the
Changba intrusion, yielding a weighted mean of 206Pb/238U ages at 757±14 Ma. This indicates that the Changba intrusion has the crustal source of mid-Neoproterozoic ages and a tectonic
affinity to the South China Block. Geochemically, the two intrusuons are both rich in LILE and LREE but depleted in HFSE and
HREE, similar to arc-type igneous rocks. The Huangzhuguang intrusion exhibits linear correlations between SiO2 and the other major oxides, implying chemical evolution from a cognate magma source. It contains mafic enclaves, suggesting
possible mixing of felsic-mafic magmas. The Changba granite is rich in Si and K but poor in Fe and Mg as well as has a high
value of Fe*, suggesting strong differentiation of granitic magma. Therefore, the two intrusions were derived from the Late
Triassic anatexis of the continental crust of different compositions in the northern margin of South China Block. This process
may be coupled with exhumation of the subducted continental crust in the stage of late collision. 相似文献
66.
制备了壳聚糖-沸石杂化膜,对其进行热重和扫描电镜表征,就壳聚糖-沸石杂化膜对pb2+的吸附行为进行了探讨.沸石的加入使壳聚糖膜产生了孔穴,增大了比表面积,提高了吸附性能.实验结果还表明沸石与壳聚糖质量比4∶5为最佳配比,吸附的最佳溶液pH为5.0,温度对吸附作用的影响比较小.壳聚糖沸石杂化膜对pb2+的吸附符合Lang... 相似文献
67.
以永安石林地区地质、水文地质资料为背景,利用不平衡铀系法,对区内不同高程的钙华沉积物岩样进行年龄测定,确定了永安石林形成年代为中更新世以来,距今约50万年.结合区域地质构造历史及沙溪河谷地貌发育演化过程,认为:永安石林的形成始于早更新世;主要是因地壳间歇性抬升运动且大湖盆地开始处于剥蚀环境,石炭二叠纪碳酸盐岩的上覆岩层逐渐被风化剥蚀后形成. 相似文献
68.
69.
Karolina Wieszczycka Kinga Filipowiak Aneta Lewandowska Agnieszka Marcinkowska Marek Nowicki 《Molecules (Basel, Switzerland)》2022,27(5)
Novel efficient complexing resins—poly(vinylbenzyl pyridinium salts) fabricated through poly(vinylbenzyl halogene-co-divinylbenzene) quaternization of N-decyloxy-1-(pyridin-3-yl)ethaneimine and N-decyloxy-1-(pyridin-4-yl)ethaneimine—were tested as adsorbents of Pb(II), Cd(II), Cu(II), Zn(II), and Ni(II) from aqueous solutions. The structure of these materials was established by 13C CP-MAS NMR, X-ray photoelectron spectroscopy, elemental analysis, and Fourier transform infrared spectroscopy, as well as thermogravimetric and differential thermal analyses. The textural properties were determined using scanning electron microscopy and low-temperature N2 sorption. Based on the conducted sorption studies, it was shown that the uptake behavior of the metal ions towards novel resins depended on the type of functionalities, contact time, pH, metal concentrations, and the resin dosage. The Langmuir model was investigated to be the best one for fitting isothermal adsorption equilibrium data, and the corresponding adsorption capacities were predicted to be 296.4, 201.8, 83.8, 38.1, and 39.3 mg/g for Pb(II), Zn(II), Cd(II), Cu(II), and Ni(II), respectively. These results confirmed that owing to the presence of the functional pyridinium groups, the resins demonstrated proficient metal ion removal capacities. Furthermore, VBBr-D4EI could be successfully used for the selective uptake of Pb(II) from wastewater. It was also shown that the novel resins can be regenerated without significant loss of their sorption capacity. 相似文献
70.
城市灰尘中Pb的X射线荧光光谱半定量分析 总被引:4,自引:0,他引:4
粉末压片法制备样品,采用X射线荧光光谱半定量IQ 分析方法分析灰尘中Pb,在IQ 增加Pb的测角仪道,延长对Pb的扫描时间,研究谱线选择、背景扣除.结果表明:采用Pb的Lβ线作为分析线,选择两个背景扣除能提高其分析的准确度和灵敏度,分析结果可与定量法相媲美,同时快速、简便、不需要制作校准曲线. 相似文献