超高效液相色谱法快速测定马口铁罐包装内涂层中痕量游离甲醛

建立了超高效液相色谱快速测定马口铁罐包装内涂层中痕量游离甲醛的方法.采用2,4-二硝基苯肼与游离痕量甲醛衍生化,对2,4-二硝基苯肼衍生试剂浓度、衍生化反应条件、衍生化溶液稳定时间及过滤条件等样品前处理条件进行了优化.研究结果表明衍生化条件变化对痕量甲醛衍生化影响明显,对高浓度甲醛则无显著影响.方法检出限为0.001mg/L,定量限为0.004mg/L,回收率为83.6%-102.4%.经实验室内和7家第三方认可实验室验证,实验结果实验室内相对标准偏差RSD 1.54%-2.62%,实验室间1.83%-4.78%.与其他方法相比本方法在痕量甲醛水平检测时仍具有检出限低、操作简便、快速、稳定等特点,并可应用需要测定痕量甲醛的其它领域.     

Porosity and effective mechanical properties of plasma-sprayed Ni-based alloy coatings

The aim of this paper was to address the relationship between the porosity and micro-mechanical properties of the Ni-based alloy coatings which were prepared by a novel plasma-spraying system. The porosity and the mechanical properties of the coatings varied through changing the spraying parameters. Experimental results showed that the measured data of porosity, Young’s modulus and micro-hardness of the coating exhibited high scattering and followed the Weibull distribution. From statistic trend, the micro-hardness and Young’s modulus of the coating decreased with increasing the porosity of the coating. Moreover, generally, with increasing the micro-hardness of the coating, Young’s modulus of the coating increased.     

Some aspects of colloids in photography

The principles of colloid and interface science underlie the successful formulation and manufacture of photographic products. The colour-forming components are usually delivered in colloidal form. Rapid and stable manufacture depends on the dynamic surface properties and the rheology of the coated fluids.     

Gold and ytterbium interfacing effects on the properties of the CdSe/Yb/CdSe nanosandwiched structures

Owing to the performance of the CdSe as an optoelectronic material used for the production of quantum dots, photosensors and wave traps we here, in this article, report the enhancements in structural and electrical properties that arises from the nanosandwiching of a 40 nm thick Yb film between two films of CdSe (CYbC-40). The CdSe films which were deposited onto glass, Yb and Au substrates are characterized by X-ray diffraction, temperature dependent electrical conductivity and impedance spectroscopy measurements in the frequency range of 10–1800 MHz. The analysis of the XRD patterns have shown that the glass/CdSe/Yb/CdSe films exhibit larger grain size and lower strain, defect density and lower stacking faults compared to the not sandwiched CdSe. In addition, it was observed that the Yb shifts the donor states of the n-type CdSe from 0.44 to 0.29 eV leading to a modification in the built in voltage of the material. On the other hand, the design of the energy band diagram has shown the ability of the formation of the Au/CYbC-40/Yb as Schottky (SB) and the Au/CYbC-40/Au as back to back Schottky barriers (BBSB). While the SB device show low band pass filter characteristics, the BBSB device performed as band stop filters. The BBSB device exhibited negative capacitance effects with filtering features that reveal a return loss of 42 dB at ∼1440 MHz.     

Characterization of Microvascular-Based Self-healing Coatings

A protocol is described to assess self-healing of crack damage in a polymer coating deposited on a substrate containing a microvascular network. The bio-inspired coating/substrate design delivers healing agent to cracks in the coating via a three-dimensional microvascular network embedded in the substrate. Through capillary action, monomer flows from the network channels into the crack plane where it is polymerized by a catalyst embedded in the coating. The healing efficiency of this materials system is assessed by the recovery of coating fracture toughness in a four-point beam bending experiment. Healing results for the microvascular networks are compared to data for a coating containing microencapsulated healing agents. A single crack in a brittle epoxy coating is healed as many as seven times in the microvascular systems, whereas microcapsule-based healing occurs for only one cycle. The ability to heal continuously with the microvascular networks is limited by the availability of catalyst in the coating.     

紫外光固化抗静电涂料的研制

将紫外光固化涂料技术与抗静电技术相结合,研制了一种由光敏树脂、光敏交联剂、光引发剂、抗静电剂等组成的紫外光固化抗静电涂料,探讨了光引发剂的种类和用量与紫外光固化性能的关系,并对抗静电剂种类和添加量与涂膜抗静电性能的关系进行了研究。结果表明,所得紫外光固化抗静电涂料固化速度快,附着力强。涂膜抗静电性能优良,具有耐擦洗性。     

真空管吸收涂层的吸收比对全玻璃真空管的热性能影响的试验分析

选择性吸收涂层是全玻璃真空太阳集热管的重要组成部分,其光学性能直接影响着全玻璃真空太阳集热管的热性能。衡量选择性吸收涂层的最主要参数是涂层光学吸收比,而代表全玻璃真空太阳集热管热性能的参数主要是空晒性能参数及闷晒太阳辐照量。文章通过试验研究了涂层的吸收比对全玻璃真空太阳集热管的空晒性能参数和闷晒太阳辐照量的影响。结果表明全玻璃真空太阳集热管涂层吸收比对闷晒太阳辐照量有明显影响,对空晒性能参数也有影响但不明显。     

空间物理主动实验装置电控箱热控分析

在空间物理主动实验中,与运载火箭分离后的实验装置在空间中继续飞行一段时间后进行工作,在这段飞行中无法对其进行姿态控制.为使得电控箱内的电路能够正常工作,需要对电控箱表面进行涂层处理,使其温度可以始终控制在理想范围内.计算了这种情况下电控箱的温度,结果表明,太阳辐射热流与电控箱内部发热是温度变化的主要原因.由于电控箱姿态不定,电控箱接受太阳辐射的情况会直接影响其温度变化,所以涂层需要满足多种情况的要求.计算结果表明,选择表面低吸收率(α=0.15)及相应的表面发射率(e=0.16)的全反射涂层,可以将电控箱温度变化控制在很小的范围内,保证电控箱内电路正常工作.     

Pyridine-thermal synthesis and high catalytic activity of CeO2/CuO/CNT nanocomposites

Carbon nanotubes (CNTs) were controllably coated with the uninterrupted CuO and CeO₂ composite nanoparticles by a facile pyridine-thermal method and the high catalytic performance for CO oxidation was also found. The obtained nanocomposites were characterized by transmission electron microscopy, scanning electron microscopy, X-ray diffraction as well as X-ray photoelectron spectroscopy. It is found that the CuO/CeO₂ composite nanoparticles are distributed uniformly on the surface of CNTs and the shell of CeO₂/CuO/CNT nanocomposites is made of nanoparticles with a diameter of 30-60 nm. The possible formation mechanism is suggest as follows: the surface of CNTs is modified by the pyridine due to the π-π conjugate role so that the alkaline of pyridine attached on the CNT surface is more enhanced as compared to the one in the bulk solvent, and thus, these pyridines accept the proton from the water molecular preferentially, which result in the formation of the OH⁻ ions around the surface of CNTs. Subsequently, the metal ions such as Ce³⁺ and Cu²⁺ in situ react with the OH⁻ ions and the resultant nanoparticles deposit on the surface of CNTs, and finally the CeO₂/CuO/CNT nanocomposites are obtained. The T₅₀ depicting the catalytic activity for CO oxidation over CeO₂/CuO/CNT nanocomposites can reach ∼113 °C, which is much lower than that of CeO₂/CNT or CuO/CNT nanocomposites or CNTs.     

Preparation of a novel infrared low-emissive coating from the Cu powder modified by the polyethylene wax

Cu powder was coated with polyethylene wax via the flux-capping method in hope to avoid the oxidation of it, so the increment of the infrared emissivity of the coating can be greatly reduced. The prepared product was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The infrared emissivity of the prepared material was measured by Infrared Emissometer. The influence parameters that will affect the emissivity of the coating were systematically investigated, such as the content of coated Cu powder, coating fineness, coating thickness and aging process. The results indicated that the infrared emissivity value of the coating was reduced after Cu powder was coated with polyethylene wax. The polyethylene wax/Cu composites presented a homogenous sheet structure when the content of Cu powder increased to 30 wt.%, and it has a lower emissivity. The infrared emissivity of the coating increases rapidly as thickness increases and becomes steady above thickness of 70 μm. The composite coating exhibits lower emissivity value and excellent physical properties at coated Cu content of 20 wt.%. The emissivity of the coating that was prepared from the modification of the Cu powder was decreased with the decrement of the grinding fineness and increased with the aging time. The emissivity of the coating that was prepared from the modification of the Cu powder is always lower than that of the coating that only composed of the Cu powder with the increment of the aging time. Therefore, it can be concluded that the anti-oxidation of Cu powder is greatly improved after it was modified by polyethylene wax, which results in a novel coating with long-run low emissivity.