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111.
Hassan Ali Zamani 《中国化学快报》2011,22(6):701-704
N1,N2-Bis[1-(2-hydroxyphenyl)methylidene]ethanedihydrazide(MEH) was used as new compound which plays the role of an excellent ion carrier in the fabrication of a Ho(Ⅲ) membrane electrode.The electrode shows a good selectivity for Ho(Ⅲ) ion with respect to most common cations including alkali,alkaline earth,transition and heavy metal ions.This electrode has a wide linear dynamic range from 1.0×10-6 to 1.0×10-2 mol/L with a Nernstian slope of 19.8±0.3 mV per decade and a low detection limit of 5.8×10-7 mol/L in the pH range of 2.5-9.8,while the response time was rapid(<10 s).The suggested sensor was applied to the determination of Ho(Ⅲ) ions in tap water and river water samples. 相似文献
112.
The present study describes modification of porous PVC particles by polymerization of a monomer/crosslinker/peroxide solution absorbed within the PVC particles. The modifying crosslinked polymers include butyl acrylate (BA) crosslinked with ethylene glycol dimethacrylate (EGDMA) and ethylhexyl acrylate (EHA) crosslinked with EGDMA. The monomer solution is blended with the PVC particles by dry‐blending. The monomer absorbed particles are then polymerized in a stabilizer‐free aqueous dispersion‐polymerization. The modified semi‐IPN PVC particles have better stability than the neat PVC particles in packed columns for absorption of halo‐organics from water, etc. The modified semi‐IPN PVC particles are melt processable and thus have the potential of being interesting and useful modified rigid PVC materials. The modified PVC particles characterization includes polymerization yield, non‐extractables and porosity measurements and also morphology and dynamic mechanical behavior (DMTA). PBA and PEHA polymerization has shown high yield levels. The high conversion of BA and EHA within the particle, is partly due to their low solubility in water. The levels of non‐extractable fractions found are indicative of low chemical interaction between the polyacrylate/PVC phases in the particle. The modified PVC particle's porosity levels indicate that BA and EHA partly polymerize within the PVC particles' bulk and partly in the pores as crusts covering the PVC pore surfaces. This finding is supported by SEM observations of unetched and etched freeze fractured surfaces. Higher crosslinking levels of the polyacrylate modification promote compatibility with the PVC particles' bulk. DMTA measurements show two loss modulus peaks for the 0.5%EGDMA blends in the glass transition temperature region, suggesting imcompatibility. However, at 5%EGDMA a single transition is found exhibiting enhanced compatibility owing to the high degree of crosslinking, which prevents phase separation. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
113.
Virgil Percec Anatoliy V. Popov Ernesto Ramirez‐Castillo Oliver Weichold 《Journal of polymer science. Part A, Polymer chemistry》2003,41(21):3283-3299
The first example of living radical polymerization of vinyl chloride carried out in water at 25 °C is reported. This polymerization was initiated by iodoform and catalyzed by nascent Cu0 produced by the disproportionation of CuI in the presence of strongly CuII binding ligands such as tris(2‐aminoethyl)amine or polyethyleneimine. The resulting poly(vinyl chloride) was free of structural defects, had controlled molecular weight and narrow molecular weight distribution, contained two ~CHClI active chain ends, and had a higher syndiotacticity (62%) than the one obtained by conventional free‐radical polymerization at the same temperature (56%). This novel polymerization proceeds, most probably, by a combination of competitive pathways that involves activation by single electron transfer mediated by nascent Cu0 and degenerative chain transfer. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3283–3299, 2003 相似文献
114.
115.
分析了PVC管材物化阶段的构成,识别物化阶段的主要环境影响类型,对PVC管材物化环境状况进行分析评价,结果可作为建筑工程环境影响评价的基础数据,用于评价建筑工程环境影响。 相似文献
116.
117.
增塑的PVC涂膜压电晶体传感器阵列用作香味传感系统曹忠,林辉概,王彬锋,王柯敏,陈泽忠,俞汝勤(湖南大学化学化工系,长沙,410082)关键词阵列,压电晶体传感器,增塑的PVC涂膜,香味传感系统吸附活性物质如类脂化合物等涂膜的压电晶体传感器(PCS)... 相似文献
118.
Haihong Jiang 《Applied Surface Science》2010,256(14):4559-264
Contact angles and surface energy of wood, as well as interfacial shear strength between wood and polyvinyl chloride (PVC) were investigated and used to monitor the modifications generated on the surfaces of wood treated with a copper ethanolamine solution. An increase in surface energy of wood after treatments promotes wetting of PVC on wood surfaces. Improved interfacial shear strength between treated wood and PVC matrix can be attributed to the formation of a stronger wood-PVC interphase. This suggests that treatment may be used to improve the adhesion between wood surface and PVC in the formulation of wood fiber composites to yield products with enhanced mechanical properties and better biological and physical performance against decay and insect destroying wood. 相似文献
119.
Summary: Thin films of high molecular weight PMMA, PVC and their blend were prepared with solution cast method. Further they were modified by adding Camphor Sulphonic Acid (CSA) to them. DSC studies indicate single glass transition temperature (Tg) for unmodified as well as modified blends indicating the miscibility of polymers. FTIR studies show the interaction between CSA-PVC, CSA-PMMA, CSA-(PVC+PMMA) blend. The D.C. electrical study was carried out at various temperatures from room temperature (307 K) to 373 K. After modification the variation of DC conductivity (σ) is found to decrease in PVC and the PVC-PMMA blend whereas it is found to increase in PMMA with rise in temperature. 相似文献
120.
Shuhao Qin Minmin Zhang Jinfeng Lei Min He Jie Yu 《Journal of Macromolecular Science: Physics》2013,52(5):910-918
Poly(vinyl chloride) (PVC)/acrylonitrile-butadiene-styrene (ABS) blends containing organically modified montmorillonite (OMMT) were prepared using a twin-screw extruder followed by injection molding. The OMMT dispersion was evaluated by X-ray diffraction and transmission electron microscopy. The clay was preferentially situated in the PVC phase and across the interfaces of PVC/ABS. The effect of the addition of OMMT on the morphology and mechanical properties was also evaluated. Scanning electron microscopy revealed a large reduction in domain size when OMMT was used. The mechanical properties were studied through tensile and impact tests. The yield stress increased when an appropriate amount of OMMT was used without impairing the impact strength. 相似文献