具有无挠K0群的群环

本文研究了R为正则PT环时,具有无挠K_0群的群环,证明了:当R为正则局部环或主理想整环且char R≠o时,G为有限生成Abel群,则K_0RG为无挠群．     

Weakly non-Hermitian square well

Inside a box of size L we contemplate the simplest -symmetric piece-wise constant potential of size ℓ < L and purely imaginary strength ig and describe all its bound states in closed form. Presented at the 3rd International Workshop “Pseudo-Hermitian Hamiltonians in Quantum Physics”, Istanbul, Turkey, June 20–22, 2005.     

A New Approach for Preparing Effective Inhibition Film on Copper Based on Self-assembled Process

A new method for preparing effective inhibition film on copper has been developed.Pheylthiourea(PT) was firest absorbed to copper surface to form a monolayer.1-Dodecanethiol(DT) was then assembled on the surface for modification.Finally,Ac voltage was loded on copper covered the mixed film to improve it further.After these processes,an effective inhibition film was gained because of its high charge transfer resistance and low corrosion current density shown in electrochemical impedance spectra and polarization.The inhibition efficiency was more than 97%.     

Effect of Pt loading on the photocatalytic reactivity of titanium oxide thin films prepared by ion engineering techniques

Platinum-loaded titanium oxide thin-film photocatalysts were prepared by using an ionized cluster beam (ICB) deposition method and a RF magnetron sputtering (RF-MS) deposition method as dry processes. From the results of the photocatalytic oxidation of acetaldehyde with O₂ under UV light irradiation, small amounts of Pt loading (less than 10 nm film thickness) were found to dramatically enhance the photocatalytic reactivity. However, when TiO₂ thin films were loaded with relatively larger amounts of Pt (more than 30 nm as the film thickness), the photocatalytic reactivity became lower than for the pure TiO₂ thin films. Moreover, investigations of the ratio of Pt loaded onto the surface of the thin film catalysts by XPS measurements revealed that the small amounts of Pt loaded exist as very small clusters working to efficiently enhance the charge separation, whereas, large amounts of Pt covers the entire surface of the TiO₂ thin films, resulting in a decrease of the photocatalytic reactivity.     

相转移催化反应研究——Ⅰ.相转移催化剂在二卤卡宾与对-甲基苯乙烯加成反应中结构效应

本文研究了不同结构的季铵盐、季鏻盐、常用冠醚以及N,N＇-二取代氦杂冠醚等相转移催化剂,催化产生的二溴卡宾与对-甲基苯乙烯的加成反应。结果证明,具有对称烷基结构的季铵盐的催化性能优于碳链较长、对称性较差的手铵盐。在冠醚类相转移催化剂中,新型N,N＇-二取代氮杂冠醚优于常用冠醚及穴醚[2.2.2]。在十九种相转移催化剂中,以N,N＇-双(3＇、6＇-二氧杂癸烷基)-1,7,10,16-四氧杂-4,13-二氮杂环十八烷[简称二丁基2.2(2.2)]的催化性能最佳。简要讨论了鎓盐及大环多醚的PTC反应机理及催化性能,还比较了氘代氯仿、氘代氢氧化钠重水体系进行的相转移催化反应。     

Hierarchical classification designs for the estimation of different sources of variability in proficiency testing experiments

An approach to the estimation of possible different sources of variation found in proficiency testing experiments is described. Four errors namely, technique, analyst, laboratory and geographical location are considered and calculated by using a rational experimental design based on hierarchical classification. The treatment of the confidence of the design over different experimental arrangements is explored and visualised by calculating a function that depends only on the design and not on the experimental response. An illustrative example based on simulated data is used to show how the theory could be applied in practice.     

发电机出口PT接地故障的分析与处理

简要介绍了火电厂系统主接线和发变组主要保护配置,针对某机组运行时显示的故障现象,分析发变组保护装置动作报告和机组故障录波的特征,通过排查判断是发电机出口PT接地故障,对故障原因进行分析查找,并制定出相应的处理和防范措施．     

Nonlinear structure of some classical quasi-Banach spaces and -spaces

We investigate the Lipschitz structure of ℓ_p and L_p for 0<p<1 as quasi-Banach spaces and as metric spaces (with the metric induced by the p-norm) and show that they are not Lipschitz isomorphic. We prove that the PT29C7-1-B/0?wchp=dGLbVlb-zSkWz" alt="View the MathML source" title="View the MathML source" align="absbottom" border="0" height=11 width="10"/>-space L₀ is not uniformly homeomorphic to any other L_p space, that the L_p spaces for 0<p<1 embed isometrically into one another, and reduce the problem of the uniform equivalence amongst L_p spaces to their Lipschitz equivalence as metric spaces.     

Isomerization of HNO to HON in the singlet state assisted by amino acid residues and/or water molecules

The effects of amino acid residues in the presence or absence of water molecules on the isomerization of the singlet state of HNO/HON have been systematically investigated at the B3LYP/6‐311++G** level of theory. The structural characteristics, proton transfer (PT) mechanisms, and the corresponding thermodynamic and kinetic parameters, have been discussed, respectively. All the optimized complexes have been characterized by the ring structures through the intermolecular H‐bonds. The origin of the increase in N? H stretching frequency (blue shifts) occurring in the reactants has also been investigated using the natural bonding orbital (NBO) analyses, which is mainly attributed to the decrease of the electron densities in the antibonding orbital of the N? H bonds as well as the increase of the polarization of the N? H bond. All the PTs proceed with the concerted mechanisms since no ionic intermediates have been located during PT processes. At the same time, the cooperative effects of amino acid residues and water molecules on the selected PT processes have been observed, where the PTs assisted solely by the selected residues cannot occur without the participation of the water molecule. Overall, the introductions of one or two water molecules are more favorable for the isomerization of HNO assisted by the amino acid residues. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2008