STUDY OF GRAFTING COPOLYMER OF STYRENE AND 2,2,6,6-TETRAMETHYL-4-PIPERIDINYL METHACRYATE ONTO POLYPROPYLENE DURING HEATING

The grafting of copolymer of styrene and 2, 2, 6, 6-tetramethyl-4-piperidinyl methacrylate onto polypropylene during heating was studied by IR and ESR. It is found that the graft reaction is going through the stable free radical > NO mechanism.     

建设管理模式匹配关系及其对项目绩效的影响

建设管理模式对项目内外部条件的适应程度直接影响项目绩效水平.基于对建设管理模式的研究成果和实践案例分析,揭示建设管理模式描述要素和项目条件要素之间的匹配关系对项目绩效的影响,构建了要素之间的匹配关系模型.提取世界银行在中国投资的30个公共建设项目案例数据,通过Spearman相关分析对模型作了定量检验,分析了匹配关系对项目绩效的影响及其作用机理.结果表明,在项目中咨询方通过项目可行性研究等前期工作促进了业主对项目的风险控制水平,从而提高了项目绩效,管理模式和项目条件之间的匹配关系越合理则项目绩效越良好.据此,提出了项目建设管理模式选择的建议和原则,建立的模型和成果对类似工程建设管理模式的构建具有借鉴意义.     

A Comparison of Cysteine-Conjugated Nitroxide Spin Labels for Pulse Dipolar EPR Spectroscopy

The structure-function and materials paradigms drive research on the understanding of structures and structural heterogeneity of molecules and solids from materials science to structural biology. Functional insights into complex architectures are often gained from a suite of complementary physicochemical methods. In the context of biomacromolecular structures, the use of pulse dipolar electron paramagnetic resonance spectroscopy (PDS) has become increasingly popular. The main interest in PDS is providing long-range nanometre distance distributions that allow for identifying macromolecular topologies, validating structural models and conformational transitions as well as docking of quaternary complexes. Most commonly, cysteines are introduced into protein structures by site-directed mutagenesis and modified site-specifically to a spin-labelled side-chain such as a stable nitroxide radical. In this contribution, we investigate labelling by four different commercial labelling agents that react through different sulfur-specific reactions. Further, the distance distributions obtained are between spin-bearing moieties and need to be related to the protein structure via modelling approaches. Here, we compare two different approaches to modelling these distributions for all four side-chains. The results indicate that there are significant differences in the optimum labelling procedure. All four spin-labels show differences in the ease of labelling and purification. Further challenges arise from the different tether lengths and rotamers of spin-labelled side-chains; both influence the modelling and translation into structures. Our comparison indicates that the spin-label with the shortest tether in the spin-labelled side-group, (bis-(2,2,5,5-Tetramethyl-3-imidazoline-1-oxyl-4-yl) disulfide, may be underappreciated and could increase the resolution of structural studies by PDS if labelling conditions are optimised accordingly.     

PDS用于不同温度下的近红外光谱模型传递研究

采用合适的计算方法可降低测定环境对近红外光谱校正模型稳健性的影响。该文以喷气燃料为研究对象,考察了分段直接校正算法对所建模型预测结果的影响,通过选择转移样品数及窗口宽度,建立了最佳的校正模型和光谱转移参数。结果表明,在20℃下建立近红外光谱校正模型,直接预测30℃下喷气燃料的密度,预测集样品均方根误差（RMSEP）为0.2031,而30℃近红外光谱采用分段直接校正算法模型转移后,预测集样品均方根误差（RMSEP）降低为0.1354,预测结果得到明显改善,有效地解决了样品温度对近红外光谱分析结果的影响。     

网络综合布线系统的工程设计

随着信息技术的普及应用,各种智能化建筑逐渐成为普通大众的工作、生活必需品．智能化建筑的建设,综合布线系统是基础,它为信息资源的传递提供了物理通道,是现今和未来计算机网络和信息系统的基础支撑环境．文章从网络综合布线系统建设的规划、设计入手,研究网络综合布线系统建设的工程设计方法和技术,并结合《综合布线系统工程设计规范》给出完整的综合布线工程设计要点和流程,对网络综合布线工程建设具有实际指导意义．     

Preparation and Properties of One-Dimensional C60 Nano-Structure in a Zeolite FSM-16

Abstract

C₆₀ molecules were embedded in the pores of a zeolite FSM-16 by using a liquid phase method. The shift of photoluminescence spectra of C₆₀ solid embedded in FSM-16 was discussed using data of ESR, PDS and SAXS.     

基于APDL的钢板剪力墙可靠性研究

应用ANSYS中的APDL参数化语言对非加劲肋钢板剪力墙、十字加劲肋钢板剪力墙、斜加劲肋钢板剪力墙进行了建模及随机有限元可靠性分析。在随机有限元可靠性分析中,使用PDS模块,确定了钢板剪力墙的可靠度,并将结果生成可靠性分析报告。结果表明:相同强度地震力作用下的三种模型,可靠度从小到大依次为非加劲肋钢板剪力墙、十字加劲肋钢板剪力墙、斜加劲肋钢板剪力墙。三种模型中竖向压力对可靠度影响最大。     

基于硫酸根自由基的先进氧化活化方法及其在有机污染物降解上的应用

基于硫酸根自由基(SO₄^.-)的先进(高级)氧化法(AOPs)因其对新型有机污染物的高降解能力和高适应性而受到越来越多的关注。相比羟基自由基(·OH),SO₄^.-的选择性更好、还原电位更高、半衰期更长、pH范围更宽且成本更低,因而能更有效的降解污染物。SO₄^.-可由过一硫酸盐(PMS)或过二硫酸盐(PDS)等过硫酸盐(PS)通过热、机械化学、过渡金属、碳质材料、碱、紫外(UV)或电化学等方法活化产生。本文分析了不同活化方法的优缺点及其应用于有机污染物降解上的研究进展,总结了SO₄^.-降解含不同官能团污染物的三种机理(加成作用、夺氢作用和直接电子转移),并综述了SO₄^.-降解持久性有机污染物(POPs)、“伪持久性有机污染物”——药物和个人护理品(PPCPs)及有机染料三大类有机污染物的降解途径、降解产物及其研究进展,最后展望了该技术未来的研究方向。     

基于PDS的IKE安全协议形式化分析

介绍了支持复杂协议形式化并行推导的PDS协议衍生推导系统和IKE协议.给出了使用PDS形式化衍生IKE协议的核心认证部分的方法.     

Efficient Degradation of Congo Red in Water by UV-Vis Driven CoMoO4/PDS Photo-Fenton System

In order to improve the catalytic activity of cobalt molybdate (CoMoO₄), a PDS-activated and UV-vis assisted system was constructed. CoMoO₄ was prepared by coprecipitation and calcination, and characterized by XRD, FTIR, Raman, SEM, TEM, XPS, TGA Zeta potential, BET, and UV-Vis DRS. The results showed that the morphology of the CoMoO₄ nanolumps consisted of stacked nanosheets. XRD indicated the monoclinic structures with C2/m (C³_2h, #12) space group, which belong to α-CoMoO₄, and both Co²⁺ and Mo⁶⁺ ions occupy distorted octahedral sites. The pH of the isoelectric point (pHIEP) of CMO-8 at pH = 4.88 and the band gap of CoMoO₄ was 1.92 eV. The catalytic activity of CoMoO₄ was evaluated by photo-Fenton degradation of Congo red (CR). The catalytic performance was affected by calcination temperature, catalyst dosage, PDS dosage, and pH. Under the best conditions (0.8 g/L CMO-8, PDS 1 mL), the degradation efficiency of CR was 96.972%. The excellent catalytic activity of CoMoO₄ was attributed to the synergistic effect of photo catalysis and CoMoO₄-activated PDS degradation. The capture experiments and the ESR showed that superoxide radical (·O₂⁻), singlet oxygen (¹O₂), hole (h⁺), sulfate (SO₄⁻·), and hydroxyl (·OH⁻) were the main free radicals leading to the degradation of CR. The results can provide valuable information and support for the design and application of high-efficiency transition metal oxide catalysts.