Orientational order parameters of nematogenic trans-4-propyl cyclohexyl-4 (trans-4-alkyl cyclohexyl) benzoates

The refractive indices and densities of three members of trans-4-propyl cyclohexyl-4 (trans-4-alkyl cyclohexyl) benzoates are reported as functions of temperature in the nematic and isotropic phases. The principal molecular polarizabilities and order parameters (S) have been evaluated using the anisotropic internal field model (Neugebauer’s approach). Also order parameters have been estimated by studying the dipole-dipole splittings in the wide line proton magnetic resonance (PMR) spectra. The results obtained are in close agreement with those obtained from refractive index measurements.     

CONVERGENCE RATE OFDISTRIBUTIONS OF TRIMMED SUMS

1.IntroductionLet{Xn,n2l}beasequenceofi.i.d.randomvariableswithnondegeneratedistributionF.Fornonnegativeintegersk.andrn,k. rn相似文献   

A Bound on the Approximation Order of Surface Splines

The functions φ _m :=|.| ^2m-d if d is odd, and φ _m :=|.| ^2m-d \log|.| if d is even, are known as surface splines, and are commonly used in the interpolation or approximation of smooth functions. We show that if one's domain is the unit ball in R ^d , then the approximation order of the translates of φ _m is at most m . This is in contrast to the case when the domain is all of R ^d where it is known that the approximation order is exactly 2m . April 23, 1996. Date revised: May 5, 1997.     

关于范畴中态射集偏序的刻划问题

本文讨论范畴中态射集偏序的刻划问题，给出了态射偏序的一致刻划。     

Stiffness in numerical initial-value problems

This paper reviews various aspects of stiffness in the numerical solution of initial-value problems for systems of ordinary differential equations.     

介绍一种剪力墙结构分析的高阶开孔单元

在香港大学Y.K.Cheung和Sisodiya提出用于剪力墙结构分析的带面内转角的平面应力单元的基础上,本文提出了一类具有32-56个自由度的高阶矩形单元,这类单元在铅垂方向采用3-6次多项式插值,具有8-14个结点,每个结点具有2个位移自由度和2个面内转角自由度,在上述单元的基础上,又提出了一类采用三角级数或梁的振型函数作泡状函数的自由度数目为58-74的高阶开孔矩形单元,对开孔剪力墙的计算表明,本文单元与8节点矩形单元和4节点双线性矩形单元相比,其位移精度分别提高2倍和4倍以上,应力精度提高的幅度则更大.而且该二类单元由于考虑了面内转角,可方便地与梁柱单元相连接.     

二阶复合型偏微分方程的函数论方法

本文讨论二阶复合型方程组（ＣＥ２）：１００１２ｔ２＋１００λ／Ｒ２２ｘ２１＋０（λ－ｋ２）／ｋ２（λ－１）／ｋ０２ｘ１ｘ２＋λ００１２ｘ２２ｕ１ｕ２＝０（０＜ｋ＜１，λ＜０）得到了该方程组有解的必要条件，并由此知道该方程组的Ｃａｕｃｈｙ问题是不适定的，转而讨论问题（Ｄ２），证明了问题（Ｄ２）是可解的，并给出了解的表达式     

Inequalities for ordered sums

Summary Letx _i =y _i +z _i ,i=1, ...n, and writex ₍₁₎≦...≦x _(n) , with corresponding notation for the orderedy _i andz _i . It is shown, for example, that ,r=1, ...n. Inequalities are also obtained for convex (or concave) functions of thex _(i) . The results lead immediately to bounds for the expected values of order statistics in nonstandard situations in terms of simpler expectations. A small numerical example illustrates the method. Research supported by U.S. Army Research Office.     

二维凝聚体系中分子的取向分布函数性质

对二阶和四阶Legondre多项式构造的取向分布函数进行了仔细研究, 发现该函数适于描述二维凝聚体系中单轴取向分子的四种分布模式, 给出了这四种分布模式对应的序参数〈P_2〉,〈P_4〉的取值区域, 具体讨论了序参数〈P_2〉,〈P_4〉改变时, 分布图形的相应变化.     

正十六烷体系凝固过程的分子动力学模拟

采用分子动力学模拟的方法,根据体系热容和自扩散系数的突变,计算了正十六烷体系以及正十六烷和降凝剂α-辛基萘、α-十二烷基萘及α-十六烷基萘等α-烷基萘混合体系的凝点,凝点降低结果与实验值相一致.用径向分布函数及末端距离分布对凝固温度附近体系的微观结构变化进行了研究.结果表明,凝固过程中正十六烷分子倾向于转变成为全反式的构象,以利于分子间平行有序的排列,这和熵减小的原理相一致.结合正十六烷的构象变化,探讨了烷基萘降凝的机理.