尼龙1010／尼龙6共聚物的表观相图研究

采用显微熔点法和ＤＳＣ测定了尼龙１０１０／尼龙６共聚物的表观相图；分析了投料比与链节结构单元含量的关系。最低熔点时尼龙１０１０／尼龙６的理论重量投料比为６０／４０，摩尔比为３３．３／６６．７，实验结果与此相近。     

Phase Relations in the Ni–Mn–Ga Ternary System and Aging Effect on Shape Memory Properties of Ferromagnetic Ni<Subscript>2</Subscript>MnGa Sputtered Films

Summary. Isothermal sections of the Ni–Mn–Ga ternary phase diagram at 1073 and 1273 K were investigated over a wide range of alloy compositions. The range of the β-Ni₂MnGa phase, its equilibria with the γ-(Mn, Ni), α′-Ni₃Ga, and γ-Ni₃Ga₂ phases, and the liquidus and solidus lines were determined experimentally. The aging effect on the shape memory effect (SME) of Ni₂MnGa sputtered films was also investigated. The two-way SME of the constraint-aged films was confirmed by the temperature change.     

Study on the Phase Diagram of CsCl-CeCl3-HCl(11%)-H2O System and the Properties of the Compounds

The equilibrium solubility of CsCl-CeCl3-HCl(11%)-H2O qua-ternary system at 25℃ has been determined by the physicchemical analysis method ,and the phase diagram was plotted, Two new double salts 3CsCl.CeCl3.3H2O and CsCl.CeCl3.4H2O obtained from the complicated system were identified and characterized by XRD,TG-DTA ,DSC,UV and fluorescence spectroscopy, Studies on the fluorescence excitation and emission show that 3CsCl.CeCl3.3H2O and CsCl.CeCl3.4H2O have upconversion luminescence of infrared-visible range,and the upconversion emission intensity increases with the increase of ratio of CeCl3 in CsCl.     

Nanostructural Approach to Proton Ordering in Gas Hydrate Cages

A nanostructural approach to analysis of proton ordering in gas hydrate cages has been worked out within the framework of the topological model of strong and weak H-bonds. The approach involves rejection of the periodic boundary conditions, decomposition of the H-bond net into spherical layers, and two-dimensional drawing of the structure of spherical (spheroidal) fragments in the form of conjugate Schlegel diagrams. To analyze proton ordering in the spherical fragments composed of gas hydrate voids, we used the simulated annealing procedure and the correlation extension method proposed earlier.     

Structural materials: metal-silicon-Boron. The Nb-rich corner of the Nb-Si-B system

Phase equilibria in the Nb-Nb₅Si₃-NbB region were studied in the melting (crystallization) range by means of light microscopy, XRD, SEM and EMPA on alloys after arc-melting and annealing at 1800°C and at subsolidus temperatures. Phase transition and melting temperatures were determined by DTA and pyrometric Pirani-Alterthum technique resulting in a solidus projection and two isopleths, Nb₇₇Si₂₃-Nb₇₇B₂₃ and Nb₉₉Si₁-Nb₅Si₂B. The T₂-phase Nb₅Si_3−xB_x (0?x?2, Cr₅B₃-type) was found to form equilibria with (Nb), NbB, Nb₃Si, and with the T₁-phase (Mn₅Si₃ derivative type). The T₂-phase melts incongruently (Nb₅Si_1.8B_1.2 at 2245°C) and forms a quasibinary eutectic with the niobium solid solution on a minimum tie-line at ∼1880°C.     

Diagramme de phases du systeme binaire LiNO3-NaNO3

Phase diagram of the binary system LiNO₃-NaNO₃ has been obtained by using direct and differential thermal analysis between 323 and 623 K. This system is characterized by an eutectic plateau at 467 K. The eutectic point is at 0.465 mole NaNO₃. A peritectic appears at 550 K. There is no miscibility in the solid state. These findings associated with some other thermodynamic results have been used to calculate the activities of the constituents along the liquids curve and the excess thermodynamic functions at 618 K. The constituents seem not to have a symmetrical influence on the thermodynamic quantities.

     

Deux methodes photothermiques a l'etude d'une preparation de contact d'un melange binaire de cristaux liquides

The photopyroelectric (PPE) method is proposed as a sensitive technique to study a binary mixture of liquid crystals in a contact preparation. The photothermal signal is generated while scanning the contact preparation. The crystal-smectic A, smectic A-nematic, and nematic-isotropic interphase boundaries are detected. The displacement of these boundaries due to the variation of the temperature is monitored. The study of these displacements allows us to draw the complete temperature-concentration phase diagram of a binary mixtures. This revised version was published online in August 2006 with corrections to the Cover Date.     

模式识别—人工神经网络在化学中的若干新应用

本文通过我们应用模式识别－人工神经网络方法预报新化合物、熔盐相图以及复杂化学反应体系的研究，展示应用模式识别－人工神经网络方法与物理化学理论相结合，研究化学现象的可能性和应用价值。     

BaB2O4—CdO和BaB2O4—ZnO二元系相图的研究

本文用差热分析和X射线衍射方法测定了BaB_2O_4-CdO和BaB_2O_4-ZnO二元系相图。在BaB_2O_4-CdO体系中存在着一新化合物BaCdB_2O_5,在785±3℃同成份熔化。在BaB_2O_4-ZnO体系中,由包晶反应形成一新化合物BaZn_3B_2O_7,反应温度为903±3℃。在富BaB_2O_4区形成一个宽的低温相BaB_2O_4固溶区。研究结果表明,用Zn~(2 )替代BaB_2O_4中Ba~(2 )形成固溶体,不能将高温相BaB_2O_4稳定到室温,证实了“经验函数关系式”的预测结果。     

The Binary System BaF2/AlF3

The system BaF₂/AlF₃ is investigated by X-ray and D.T.A., and the liquid-solid phase diagram is established. Five ternary fluorides are disclosed: trimorphic BaAlF₅, Ba₃Al₂F₁₂, Ba₅AlF₁₉, polymorphic Ba₃AlF₉ and Ba₅AlF₁₃. Neutron thermodiffractometry experiments are performed to specify some parts of the diagram. The cell parameters of the fluorides are given and the results are discussed and compared with those of the previous works.