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991.
992.
The absorbance characteristics and influential factors on these characteristics for a liquid-phase gas sensor, which is based on gas–permeable liquid core waveguides (LCWs), are studied from theoretical and experimental viewpoints in this paper. According to theory, it is predicted that absorbance is proportional to the analyte concentration, sampling time, analyte diffusion coefficient, and geometric factor of this device when the depletion layer of the analyte is ignored. The experimental results are in agreement with the theoretical hypothesis. According to the experimental results, absorbance is time-dependent and increasing linearly over time after the requisite response time with a linear correlation coefficient r2 > 0.999. In the linear region, the rate of absorbance change (RAC) indicates improved linearity with sample concentration and a relative higher sensitivity than instantaneous absorbance does. By using a core liquid that is more affinitive to the analyte, reducing wall thickness and the inner diameter of the tubing, or increasing sample flow rate limitedly, the response time can be decreased and the sensitivity can be increased. However, increasing the LCW length can only enhance sensitivity and has no effect on response time. For liquid phase detection, there is a maximum flow rate, and the absorbance will decrease beyond the stated limit. Under experimental conditions, hexane as the LCW core solvent, a tubing wall thickness of 0.1 mm, a length of 10 cm, and a flow rate of 12 mL min−1, the detection results for the aqueous benzene sample demonstrate a response time of 4 min. Additionally, the standard curve for the RAC versus concentration is RAC = 0.0267 c + 0.0351 (AU min−1), with r2 = 0.9922 within concentrations of 0.5–3.0 mg L−1. The relative error for 0.5 mg L−1 benzene (n = 6) is 7.4 ± 3.7%, and the LOD is 0.04 mg L−1. This research can provide theoretical and practical guides for liquid–phase gas sensor design and development based on a gas-permeable Teflon AF 2400 LCW. 相似文献
993.
小批量制备了电泳纯鲨鱼肝铁蛋白(Liver ferritin of Sphyma zygaena, SZLF). 用透射电子显微镜技术研究SZLF的铁核和蛋白壳亚基解离和重组过程. 用盐酸解离(pH=1.5)和分离膜透析技术制备铁蛋白亚基, 并用酸碱中和方法重组亚基成为脱铁核铁蛋白(apoSZLF), 同时将胰岛素(Insulin, INS)包裹于apoSZLF蛋白壳内, 构建纳米INS核-SZLF. 用电子光谱、MALDI-TOF质谱和SDS-PAGE技术分别揭示了纳米INS核-SZLF分子结构的真实性, 提出铁蛋白亚基包裹INS构建为纳米INS核-铁蛋白的途径. 相似文献
994.
不完备信息系统中的属性约简一直是粗糙集研究领域的一个难点.在不完备信息系统中,用以往的属性约简算法得到的约简结果中,某一属性要么属于该约简,要么不属于该约简.但在实际生活中,当属性以比较大的概率可区分两对象时,这就表明该属性可能以某一概率属于约简结果.基于这种想法,文中通过构造概率区分矩阵,并在此基础上给出相应的区分函数,提出了一种概率属性约简算法,分析了算法正确性.从该算法得到的约简,可以看出各属性属于约简的可能性.最后用实例表明该算法是有效和可行的. 相似文献
995.
Ali Hyder Akbar Ali Jamil A. Buledi Ayaz Ali Memon Muzaffar Iqbal Talib Hussain Bangalni Amber R. Solangi Khalid Hussain Thebo Javeed Akhtar 《Chemical record (New York, N.Y.)》2024,24(4):e202400006
Nanodiamonds (NDs) have garnered attention in the field of nanomedicine due to their unique properties. This review offers a comprehensive overview of NDs synthesis methods, properties, and their uses in biomedical applications. Various synthesis techniques, such as detonation, high-pressure, high-temperature, and chemical vapor deposition, offer distinct advantages in tailoring NDs′ size, shape, and surface properties. Surface modification methods further enhance NDs′ biocompatibility and enable the attachment of bioactive molecules, expanding their applicability in biological systems. NDs serve as promising nanocarriers for drug delivery, showcasing biocompatibility and the ability to encapsulate therapeutic agents for targeted delivery. Additionally, NDs demonstrate potential in cancer treatment through hyperthermic therapy and vaccine enhancement for improved immune responses. Functionalization of NDs facilitates their utilization in biosensors for sensitive biomolecule detection, aiding in precise diagnostics and rapid detection of infectious diseases. This review underscores the multifaceted role of NDs in advancing biomedical applications. By synthesizing NDs through various methods and modifying their surfaces, researchers can tailor their properties for specific biomedical needs. The ability of NDs to serve as efficient drug delivery vehicles holds promise for targeted therapy, while their applications in hyperthermic therapy and vaccine enhancement offer innovative approaches to cancer treatment and immunization. Furthermore, the integration of NDs into biosensors enhances diagnostic capabilities, enabling rapid and sensitive detection of biomolecules and infectious diseases. Overall, the diverse functionalities of NDs underscore their potential as valuable tools in nanomedicine, paving the way for advancements in healthcare and biotechnology. 相似文献
996.
Weiqing Yin Ling Jiang Yanjia Wang Xiaohua Huang 《Journal of Polymer Science.Polymer Physics》2006,44(21):3121-3127
A novel functional complex with the thermosensitive, magnetic, and fluorescent properties of poly(N‐isopropylacrylamide)‐grafted poly(N‐isopropylacrylamide‐co‐styrene) (PNNS) microspheres and Tb(III), PNNS–Tb(III), has been synthesized and characterized with different techniques. When PNNS with a core–shell structure interacts with Tb(III), Tb(III) mainly bonds to oxygen of the carbonyl groups of PNNS, forming the novel PNNS–Tb(III) complex. PNNS shows antiferromagnetic behavior, whereas the PNNS–Tb(III) complex exhibits paramagnetic behavior. The saturation magnetization is approximately 50 times higher than that of PNNS. The fluorescence intensity of the PNNS–Tb(III)complex at 545 nm is enhanced as much as 223 times in comparison with that of pure Tb(III). The novel magnetic and fluorescent properties of the PNNS–Tb(III) complex may be useful in biomedicine and fluorescence systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3121–3127, 2006 相似文献
997.
We consider an evolution model describing the vertical movement of water and salt in a domain splitted in two parts: a water reservoir and a saturated porous medium below it, in which a continuous extraction of fresh water takes place (by the roots of mangroves). The problem is formulated in terms of a coupled system of partial differential equations for the salt concentration and the water flow in the porous medium, with a dynamic boundary condition which connects both subdomains.We study the existence and uniqueness of solutions, the stability of the trivial steady state solution, and the conditions for the root zone to reach, in finite time, the threshold value of salt concentration under which mangroves may live. 相似文献
998.
In this paper we investigate impact and compression after impact properties of plain weave carbon fiber sandwich composites.
Impact tests were conducted on different sample types to obtain information about absorbed energy and maximum impact force.
The different samples consisted of foam-filled and hollow honeycomb cores with four-layer carbon fiber facesheets on one or
both sides. The impact and compression after impact data provided valuable information to allow for comparisons between the
different sample types. Also, the compression after impact tests were conducted in order to determine the reduction in compressive
strength when comparing impacted to non-impacted samples. In conclusion, a two-degrees-of-freedom spring/mass model was compared
to experimental results. The comparison helped illustrate the limitations of current impact theory.
This paper was presented, in part, at a symposium honoring Dr Christian P. Burger, Novel Applications of Experimental Methods
in Mechanics, held at the 2003 SEM Annual Conference and Exposition on Experimental and Applied Mechanics, June 2–4, 2003,
Charlotte, North Carolina. 相似文献
999.
HT-7托卡马克中等离子体平衡研究 总被引:1,自引:0,他引:1
本文解决了二维轴对称近似下带铁芯的托卡马克中等离子体平衡问题,计算了HT-7托卡马克中的等离子体平衡位形以及极向场系统的非线性电感和垂直场系数。最后应用Kirchhoff方程组和平衡垂直场公式得到了一组等离子体、加热场和垂直场线圈的电流波形的自洽曲线。 相似文献
1000.