基于Ansoft的比例电磁铁电磁力的有限元分析

在Ansoft的Maxwe112D有限元软件中建立模型,分析比例电磁铁固定铁芯与可动铁芯锥面形状、吸合面位置、磁性材料对电磁铁电磁力的影响.计算表明不同的锥面形状、不同的锥面长度和厚度、吸合面位置在零点之上、选用高饱和磁感应强度的材料可获得较好电磁力,计算结果可以用于比例电磁铁的优化设计.     

我国商业银行发行次级债券国际比较及对策

根据《新巴塞尔协议》规定,银行资本金由一级资本和二级资本构成。一级资本即核心资本,由普通股和公开储备构成。二级资本也称附属资本,由非公开储备、资产重估储备、普通准备金、混合资本工具和次级长期债构成。由于次级长期债兼有债务和股权的特征,可用来补充资本金。作为银行资本有机组成部分,发行次级债还可降低资本金平均成本,提高股东回报率等。因此,面对外资银行的冲击,国内商业银行都相继选择发行次级债券来改变其资本充足率,特别是作为股改上市后补充资本金的一条重要渠道,发行次级债券一直为各家商业银行所采用。本文就商业银行发行次级债券进行了国际比较,并提出了对策。     

Preparation and characterization of conducting polyaniline layered magnetic nano composite polymer particles

Considering the application potentials of organic materials possessing both conducting and ferromagnetic functions in various electronic devices, an attempt was made to prepare conducting polyaniline (PANI) layered magnetic nano composite polymer particles. Two routes were used to modify magnetic Fe₃O₄ core particles. In one route, seeded emulsion polymerization of methyl methacrylate (MMA) was carried out in presence of nano‐sized Fe₃O₄ core particles. In another route, cross‐linker ethyleneglycol dimethacrylate (EGDM) was used in addition to MMA. The modified composite particles were named as Fe₃O₄/PMMA and Fe₃O₄/P(MMA‐EGDM), respectively. Finally, seeded chemical oxidative polymerization of aniline was carried out in the presence of Fe₃O₄/PMMA and Fe₃O₄/P(MMA‐EGDM) composite seed particles to obtain Fe₃O₄/PMMA/PANI and Fe₃O₄/P(MMA‐EGDM)/PANI composite polymer particles. The modification of Fe₃O₄ core particles was confirmed by electron micrographs, FTIR, UV–visible spectra, X‐ray photoelectron spectra, X‐ray diffraction pattern and thermogravimetric analyses. A comparative study showed that crosslinking of intermediate shell improved the magnetic susceptibility and electrical conductivity of PANI layered magnetic nano composite particles. Copyright © 2013 John Wiley & Sons, Ltd.     

Studies on the Particle Morphology of Waterborne Cationic Polyurethane/Polyacrylate Microemulsions

Polyurethane containing tertiary nitrogen atoms was synthesized from polyol, diphenylmethane diisoccyanate (MDI) and N‐methyl diethanolamine. The polymer was converted into cationomers by quarternizing with methacrylic acid (MAA) and then dispersed in water. In this reaction, methyl methacrylate (MMA) was used to decrease viscosity; at the same time, it was the monomer in the later reaction. Finally the cationic polyurethane dispersions were further polymerized with an oil‐soluble initiator, azobisisobutyronitrile (AIBN), water‐soluble initiator, K₂S₂O₈ (KPS) and the mixture of AIBN and KPS. The different emulsion particles with shell‐core structure, “invert” shell‐core structure and “irregular” sandwich structure were obtained; the morphological structures were characterized by TEM observation, FT‐IR and particle size analysis.     

Synthesis of Highly Functionalized Fluorinated Porphyrins

Highly functionalized fluorinated porphyrins were synthesized by a convergent strategy. Nucleophilic substitution using fluorinated branched unit and 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin afforded highly functionalized fluorinated porphyrin 8 containing 24 fluorinated chains in the peripheral region.     

Core/Shell Structured PCM Nanocapsules Obtained by Resin Fortified Emulsion Process

Phase change material (PCM, octadecane) nanocapsules were successfully prepared by resin fortified emulsion (RFE) polymerization using the alkali soluble resin (ASR) of poly(ethylene‐co‐acrylic acid) (EAA) and poly(styrene‐co‐acrylic acid) (SAA). Stable PCM nanocapsules were obtained by resin fortified emulsion polymerization, which could be attributed to the prevention of Ostwald ripening due to PCM being hydrophobic. Analysis of online FTIR measurements throughout the reaction confirmed that the nanocapsules contained octadecane as a PCM. TEM imaging of the PCM nanocapsules showed spherical and core/shell morphology. The characteristics of PCM nanocapsules can be controlled by process parameters. As a result, the particle size and particle size distribution (i.e., polydispersity index (Dw/Dn)) of the PCM nanocapsules were created by adjusting manufacturing conditions. The PCM nanocapsules exhibited thermal energy storage (～49.8 J/g) and release (～47.9 J/g) behavior.