含氧化钛高炉型渣中氧化镁对氧化钙活度的影响

在1500℃,用碳还原锡吸收法测定了含氧化钛高炉型渣中氧化钙的活度α_(cao),确定了渣中 MgO 对α_(cao)的影响,在碱度不变的条件下α_(cao)随 MgO 含量的增加而增加,α_(cao)达到极大值后随 MgO 增加而降低.α_(cao)为极大值时,%MgO=8.1～8.6.     

On the possibilities of high-resolution continuum source graphite furnace atomic absorption spectrometry for the simultaneous or sequential monitoring of multiple atomic lines

This paper explores the potential of commercially available high-resolution continuum source graphite furnace atomic absorption spectrometry instrumentation for the simultaneous or sequential monitoring of various atomic lines, in an attempt to highlight the analytical advantages that can be derived from this strategy. In particular, it is demonstrated how i) the monitoring of multiplets may allow for the simple expansion of the linear range, as shown for the measurement of Ni using the triplet located in the vicinity of 234.6 nm; ii) the use of a suitable internal standard may permit improving the precision and help in correcting for matrix-effects, as proved for the monitoring of Ni in different biological samples; iii) direct and multi-element analysis of solid samples may be feasible on some occasions, either by monitoring various atomic lines that are sufficiently close (truly simultaneous monitoring, as demonstrated in the determination of Co, Fe and Ni in NIST 1566a Oyster tissue) or, alternatively, by opting for a selective and sequential atomization of the elements of interest during every single replicate. Determination of Cd and Ni in BCR 679 White cabbage is attempted using both approaches, which permits confirming that both methods can offer very similar and satisfactory results. However, it is important to stress that the second approach provides more flexibility, since analysis is no longer limited to those elements that show very close atomic lines (closer than 0.3 nm in the ultraviolet region) with a sensitivity ratio similar to the concentration ratio of the analytes in the samples investigated.     

高炉煤气管道的腐蚀问题分析与建议

国内大型高炉煤气净化系统投运干法、TRT发电后,TRT后部煤气管道均发生严重腐蚀问题。分析了高炉煤气的腐蚀机理,论述了目前采取的防腐措施及存在的问题,提出了控制高炉煤气管道腐蚀的建议。     

传统高温炉的改造

使用传统的高温炉时采用机械式方法进行操作,升温速度靠人工手动电流调节旋钮来控制。在升温过程中必须不断地观察并调节电流大小以控制升温速度,因而在烧结样品时温度控制不够准确,且花费较多的时间、耗费较多的电量。为了满足烧结工艺对炉温的高要求,选用智能控温仪,通过改进线路,对老式高温炉温度控制系统进行技术改造。改造后的高温炉能通过控温程序准确控制烧结过程,温差为±1℃～2℃,并达到了节能、省时的效果。     

Effect of sintering temperature on the microstructure and properties of foamed glass-ceramics prepared from high-titanium blast furnace slag and waste glass

Foamed glass-ceramics were prepared via a single-step sintering method using high-titanium blast furnace slag and waste glass as the main raw materials The influence of sintering temperature (900-1060℃) on the microstructure and properties of foamed glass-ceramics was studied. The results show that the crystal shape changed from grainy to rod-shaped and finally turned to multiple shapes as the sintering temperature was increased from 900 to 1060℃. With increasing sintering temperature, the average pore size of the foamed glass-ceramics increased and subsequently decreased. By contrast, the compressive strength and the bulk density decreased and subsequently increased. An excessively high temperature, however, induced the coalescence of pores and decreased the compressive strength. The optimal properties, including the highest compressive strength (16.64 MPa) among the investigated samples and a relatively low bulk density (0.83 g/cm3), were attained in the case of the foamed glass-ceramics sintered at 1000℃.     

In situ observation of containerless solidification from undercooled Lu2O3 and Y2O3 melts

Containerless solidification processes in undercooled Lu₂O₃ and Y₂O₃ melts were investigated using an aerodynamic levitation furnace and a high-speed video. Double recalescence, indicative of two successive phase transitions, was observed for both oxides. The melting point following the first recalescence (T _M1) was higher than that of the second (T _M2) for Y₂O₃, which suggests that Y₂O₃ has a phase transition from a melt to a high temperature phase at T _M1, and then to a room temperature phase at T _M2. Two solid phases of Lu₂O₃ were also identified at T _M1 and T _M2. However, in contrast to Y₂O₃, T _M1 was lower than T _M2 for Lu₂O₃. This implies that the first crystallized phase from a melt is a metastable phase. The life duration of this metastable Lu₂O₃ was in the order of tens of milliseconds.     

Electronic Absorption Spectrum of Mesitylene Vapour

Abstract

The electronic absorption spectrum of mesitylene vapour has been photographed on a Q-24 Medium Quartz Spectrograph. The molecule belongs to D_3h symmetry and the transition is A→₁A₂ which is forbidden and due to that the (0,0) band does not appear in the spectrum. The position of (0,0) band in this case has been fixed at 36562 cm^?1 with the help of 0→1 and 1→0 transitions. There are 66 bands and most of them are assigned in terms of two ground state frequencies of magnitudes 278 and 519 cm^?1 and 7 excited state frequencies of magnitudes 267, 436, 554, 968, 1268, 1386 and 1575 cm^?1     

Al2O3对高炉渣物化性能影响的理论分析

随着优质铁矿资源的消耗,钢铁企业可利用的铁矿原料品位逐渐降低。因此,高铝质铁矿资源越来越受到钢铁企业的关注,但高铝原料在高炉冶炼过程中会带来渣铁黏稠、炉温偏低、冶炼安全等一系列问题。本研究中采用FactSage热力学软件分析Al₂O₃质量分数对高炉渣平衡物相、熔化温度、相析出温度的影响以及高铝渣液相区变化和黏度变化,旨在为高炉冶炼高铝原料提供一定的基础支撑。研究发现：炉渣为低铝（5%～10%）含量时,随着Al₂O₃含量增加,炉渣熔化温度升高,析出相为黄长石相和纯物质相,高炉渣黏度变化不大,炉渣中SiO₂含量高,炉渣黏度过高,不适合高炉冶炼;炉渣为中铝（10%～15%）含量时,随着Al₂O₃含量增加,炉渣熔化温度升高,析出相为尖晶石相、黄长石相和纯物质相,高炉渣黏度增加幅度略有提高,Al₂O₃含量对高炉渣性质影响较小,增加炉渣二元碱度对炉渣黏度降低效果较明显;炉渣为高铝（15%～30%）含量时...     

石英质捣打料的烧结性能研究

以大容量中频炉用石英质捣打料为对象,研究在不同烧结温度、添加不同含量促烧剂条件下烧结捣打料的性能。结果表明,石英平均晶粒度为550μm;α-磷石英向α-方石英的相变温度约为1 250℃;随着促烧剂含量的增加,1 100℃烧结试样的线变化率总体呈增大趋势,1 600℃烧结试样的线变化率先增大后减小,试样的显气孔率总体呈降低趋势,捣打料的耐压强度均随促烧剂含量的增加而逐渐增大;促烧剂对捣打料中温烧结强度影响明显,其高温烧结则主要依赖于石英粉体。