高性能ZnO纳米块体材料的制备及其拉曼光谱学特征

利用六面顶高压设备制备了高密度、低脆性、纳米级的ZnO块体材料，用MDI/JADE5 X射线衍射仪(Cu靶)和XL30S-FEG场发射扫描电子显微镜对高压样品的相组成、晶粒尺寸及微观形貌进行了表征.利用E55+FRA106/5傅里叶变换激光拉曼光谱仪通过ZnO块体样品位于50—500cm^-1之内的拉曼光谱, 研究了极性半导体纳米材料的拉曼光谱学特征.发现在极性半导体ZnO纳米块体材料中，没有出现明显的尺寸限制效应. 关键词： ZnO纳米块体 拉曼光谱 尺寸限制效应     

一种基于功率谱对数变换的联合变换相关器

联合功率谱的高频成份对相关峰识别具有重要作用,实验中记录的联合功率谱随着频率的增加其强度迅速降低。为增强联合功率谱的高频成分,改善其调制程度,可对功率谱进行对数变换,从而有效保留更多的高频成份,压低零级衍射光斑,提高联合变换相关器的识别能力。     

Ca+-Pyridine络合物的光解反应

使用反射式飞行时间质谱仪,得到 Ca~ -pyridine 络合物在412～ 690nm 的光解谱.从谱图可见,反应有两个通道,一个是 Ca~ 与 pyridine 分子解离开的非反应淬灭过程,这个通道在所有波段都有,且占优势；生成产物 Ca~ NH_2的通道不仅所占比例小,且在530～590nm 波段关闭. 作为激光波长函数的 Action spectrum 显示出明显的峰,对应于络合物的跃迁.反应的分支比也支持了光解谱图的结论.     

算子的Kato本质谱与Browder本质谱的连通分支

利用算子谱的精密结构的分析方法,给出算子S和T拟相似时Kato本质谱σK(S)的一个连通分支与σK(T)相交的充分条件和充要条件,同时证明了Browder本质谱σB(S)的每一个连通分支与Kato本质谱σK(T)的某些子集的交集是非空的.     

Electronic spectra of cationic forms of meso-tetrapropylporphin in a nanoporous silicate gel matrix

We have studied the fluorescence and fluorescence excitation spectra at 300 K, 77 K, and 4.2 K for silicate gel matrices colored with meso-tetrapropylporphin by impregnation of the matrix with a solution of the pigment. Comparison of the data obtained with the absorption spectra in acidified solutions and analysis of the low-temperature fine-structure vibronic spectra, and also taking into account data obtained earlier for octaethylporphin in a xerogel showed formation of two cationic forms of meso-tetrapropylporphin in the gel matrix: the short-wavelength form has a dicationic structure, while the long-wavelength form has a monocationic structure. We have traced out the correlations of the vibrational structure in the spectra of the dicationic form with data for the porphin dication, and we have drawn a number of conclusions concerning the normal vibrational modes that are active in the vibronic fluorescence and absorption spectra of the studied cationic forms. Using the AM1 semiempirical quantum chemical method, we optimized the geometry of the mesotetrapropylporphin dication: the most stable of the possible conformers is the dication structure with saddleshaped macrocycle nonplanarity. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 453–461, July–August, 2006.     

彩色透明微晶玻璃的吸收光谱

在Li2O-Al2O3-SiO2系统玻璃中掺入少量晶核剂TiO2,ZrO2,P2O5，再掺入稀土离子和过渡金属离子作为着色剂，在高温下溶制得到彩色透明玻璃，对上述玻璃进行微晶化处理，用差热分析（DTA）确定其晶化温度，测定与讨论了所获彩色透明微晶玻璃在紫外波段至近红外波段的吸收光谱特性，研究结果表明，玻璃微晶化后，由于基质玻璃对光的微弱散射，引起吸收的增强，但不改变稀土离子和过渡金属离子的本征吸收峰位。     

用多焦点全息透镜实现多重谱分数傅里叶变换

提出用多焦点全息透镜实现多重谱分数傅里叶变换.利用全息方法通过一次曝光制作出多焦点的全息透镜,分析了用此全息元件实现这种变换的条件,并在实验上实现了多重谱分数傅里叶变换. 实验结果表明这种变换方法简便可行,可广泛应用于多通道光学信息处理系统及多目标图像识别系统中.     

混杂配体金属簇合物的分子振动光谱与结构

由于原子簇化合物在催化，生物活性，功能材料等方面所呈现的重要性，使其成为无机和物理化学最重要的研究领域之一。文章中和谱学方法对一些具有混配体的过渡金属簇合物的结构及其两者之间的关系进行.     

Velocity spectrum for non-Markovian Brownian motion in a periodic potential

Non-Markovian Brownian motion in a periodic potential is studied by means of an electronic analogue simulator. Velocity spectra, the Fourier transforms of velocity autocorrelation functions, are obtained for three types of random force, that is, a white noise, an Ornstein—Uhlenbeck process, and a quasimonochromatic noise. The analogue results are in good agreement both with theoretical ones calculated with the use of a matrix-continued-fraction method, and with the results of digital simulations. An unexpected extra peak in the velocity spectrum is observed for Ornstein-Uhlenbeck noise with large correlation time. The peak is attributed to a slow oscillatory motion of the Brownian particle as it moves back and forth over several lattice spaces. Its relationship to an approximate Langevin equation is discussed.     

偶联剂修饰纳米磁性粒子红外光谱及相关分析

以三氯化铁水溶液作前驱体，采用部分还原沉淀法，通过控制一些影响反应的参数，制备纳米磁性粒子(magnetic nanoparticles，MNes)，并分别用Z-6020，Z-6030和Z-6040硅烷偶联剂对其进行表面修饰．利用红外光谱、古埃磁天平、可见光分光光度计等手段，对MNPs的表面包覆官能团、磁化率、稳定性等进行表征．红外光谱分析表明，选用不同的偶联剂修饰MNPs，可以在其表面包覆各种活性的有机基团，除都含有大量-OH之外，用Z-6020修饰的MNPs还含有-NH2和-NH；用Z-6030修饰的，还含有-C-O和-C-C；用Z-6040修饰的，还含有-C-O，-C-O-C和-C-OH．同时，用Z-6020修饰的MNPs磁化率最高，稳定性较差；用Z-6040的，磁化率次之，稳定性最好；用Z-6030的，磁化率最低，稳定性最差．