全文获取类型
收费全文 | 131660篇 |
免费 | 9784篇 |
国内免费 | 9297篇 |
专业分类
化学 | 39034篇 |
晶体学 | 772篇 |
力学 | 6643篇 |
综合类 | 744篇 |
数学 | 26653篇 |
物理学 | 22279篇 |
综合类 | 54616篇 |
出版年
2024年 | 306篇 |
2023年 | 1379篇 |
2022年 | 2295篇 |
2021年 | 2674篇 |
2020年 | 3047篇 |
2019年 | 3010篇 |
2018年 | 2812篇 |
2017年 | 3344篇 |
2016年 | 3740篇 |
2015年 | 3817篇 |
2014年 | 5772篇 |
2013年 | 7505篇 |
2012年 | 6866篇 |
2011年 | 8010篇 |
2010年 | 6464篇 |
2009年 | 7926篇 |
2008年 | 7707篇 |
2007年 | 8519篇 |
2006年 | 7436篇 |
2005年 | 6607篇 |
2004年 | 6087篇 |
2003年 | 5304篇 |
2002年 | 5698篇 |
2001年 | 3999篇 |
2000年 | 3686篇 |
1999年 | 3319篇 |
1998年 | 2702篇 |
1997年 | 2432篇 |
1996年 | 2369篇 |
1995年 | 2394篇 |
1994年 | 2132篇 |
1993年 | 1765篇 |
1992年 | 1653篇 |
1991年 | 1372篇 |
1990年 | 1245篇 |
1989年 | 998篇 |
1988年 | 760篇 |
1987年 | 551篇 |
1986年 | 418篇 |
1985年 | 395篇 |
1984年 | 335篇 |
1983年 | 186篇 |
1982年 | 285篇 |
1981年 | 273篇 |
1980年 | 216篇 |
1979年 | 202篇 |
1978年 | 170篇 |
1977年 | 150篇 |
1976年 | 123篇 |
1973年 | 68篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
Chau O. Shillor M. Sofonea M. 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2004,55(1):32-47
A model for the dynamic, adhesive, frictionless contact
between a viscoelastic body and a deformable foundation is
described. The adhesion process is modeled by a bonding field on
the contact surface. The contact is described by a modified normal
compliance condition. The tangential shear due to the bonding
field is included. The problem is formulated as a coupled system
of a variational equality for the displacements and a differential
equation for the bonding field. The existence of a unique weak
solution for the problem is established, together with a partial
regularity result. The existence proof proceeds by construction of
an appropriate mapping which is shown to be a contraction on a
Hilbert space. 相似文献
992.
Ioannis K. Argyros 《Journal of Mathematical Analysis and Applications》2004,298(2):374-397
We provide a local as well as a semilocal convergence analysis for two-point Newton-like methods in a Banach space setting under very general Lipschitz type conditions. Our equation contains a Fréchet differentiable operator F and another operator G whose differentiability is not assumed. Using more precise majorizing sequences than before we provide sufficient convergence conditions for Newton-like methods to a locally unique solution of equation F(x)+G(x)=0. In the semilocal case we show under weaker conditions that our error estimates on the distances involved are finer and the information on the location of the solution at least as precise as in earlier results. In the local case a larger radius of convergence is obtained. Several numerical examples are provided to show that our results compare favorably with earlier ones. As a special case we show that the famous Newton-Kantorovich hypothesis is weakened under the same hypotheses as the ones contained in the Newton-Kantorovich theorem. 相似文献
993.
LI Na ZHAO Degang & YANG Hui State Key Laboratory on Integrated Optoelectronics Institute of Semiconductors Chinese Academy of Sciences Beijing China 《中国科学G辑(英文版)》2004,47(6):694-701
Because of their large band-gap, large high-field electron velocity, large breakdownfield, and large thermal conductivity, GaN and its heterojunction with AlGaN and InGaNhave foreseeable potential in the applications of high-power/temperature electronics, andoptoelectronic devices operative in UV and visible wavelength. Polarization inducedelectric field can reach the magnitude of ~MV/cm[1,2]. For AlGaN/GaN based FETs theconcentration of sheet carrier induced by polarization in the cha… 相似文献
994.
995.
Young C. Kim Mikhail A. Anisimov Jan V. Sengers Erik Luijten 《Journal of statistical physics》2003,110(3-6):591-609
The character of critical behavior in physical systems depends on the range of interactions. In the limit of infinite range of the interactions, systems will exhibit mean-field critical behavior, i.e., critical behavior not affected by fluctuations of the order parameter. If the interaction range is finite, the critical behavior asymptotically close to the critical point is determined by fluctuations and the actual critical behavior depends on the particular universality class. A variety of systems, including fluids and anisotropic ferromagnets, belongs to the three-dimensional Ising universality class. Recent numerical studies of Ising models with different interaction ranges have revealed a spectacular crossover between the asymptotic fluctuation-induced critical behavior and mean-field-type critical behavior. In this work, we compare these numerical results with a crossover Landau model based on renormalization-group matching. For this purpose we consider an application of the crossover Landau model to the three-dimensional Ising model without fitting to any adjustable parameters. The crossover behavior of the critical susceptibility and of the order parameter is analyzed over a broad range (ten orders) of the scaled distance to the critical temperature. The dependence of the coupling constant on the interaction range, governing the crossover critical behavior, is discussed. 相似文献
996.
Chung-Cherng Lin 《Journal of Physics and Chemistry of Solids》2004,65(5):913-921
The phase transition of a synthetic clinoenstatite in a diamond-anvil cell has been studied by using Raman spectroscopy at various pressures and room temperature. The phenomena observed in clinoenstatite have been compared with that observed in orthoenstatite. It is found that the pressure-induced phase transitions in the two enstatites are reversible, but with different transition pressures and transition behavior. An analysis of Raman spectra has revealed that the two enstatites have different high-pressure polymorphs. This result suggests that the space group of the high-pressure polymorph of orthoenstatite is not of C2/c, and that orthoenstatite and orthoferrosilite have different transition routes at room temperature and high pressure. The compressional behavior of the high-PC2/c enstatite is also discussed according to the pressure dependences of Raman frequencies. 相似文献
997.
In this paper, the problem of estimating the covariance matrix of the elliptically contoured distribution (ECD) is considered. A new class of estimators which shrink the eigenvalues towards their arithmetic mean is proposed. It is shown that this new estimator dominates the unbiased estimator under the squared error loss function. Two special classes of ECD, namely, the multivariate-elliptical t distribution and the ε-contaminated normal distribution are considered. A simulation study is carried out and indicates that this new shrinkage estimator provides a substantial improvement in risk under most situations. 相似文献
998.
《Magnetic resonance in chemistry : MRC》2003,41(8):626-628
15N isotopic enrichment was necessary for the unequivocal assignment of the 1H NMR lines to the protons in the NH–OH fragment of benzohydroxamic acid, BHXA, C6H5CONHOH, in dry dimethyl sulfoxide solutions. The assignment [δ(NH) = 11.21, δ(OH) = 9.01, 1J(15N,1H) = 102.2 Hz, 2J(15N,1H) <1.5 Hz], which is opposite to that used by other authors, confirms the assignment extended to BHXA by Brown and co‐workers from the spectra of acetohydroxamic acid. The enrichment allowed also assignment of the 29Si lines in the spectra of disilylated benzohydroxamic acid, (Z)‐tert‐butyldimethylsilyl N‐tert‐butyldimethylsilyloxybenzoimidate (2) and (Z)‐tert‐butyldiphenylsilyl N‐tert‐butyldiphenylsilyloxybenzoimidate (3), and confirmed structure of the monosilylated products, N‐tert‐butyldiphenylsilyloxybenzamide (4) and N‐tert‐butyldiphenylsilyloxy benzoimidic acid (5). Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
999.
Summary The detachment of a rubber matrix from a rigid inclusion under monotonic loading and at subsequent relaxation is investigated within two dimensional analysis. Examined are stress–strain experimental data acquired with the help of a test bed equipped with a digital image-acquisition device. The influence of the interfacial bonding strength and the particle size on the detachment process is analyzed. The influence of the interfacial bonding strength is visible in the stress–strain diagram of loading and in the recorded images. The relaxation test reveals no influence of the bonding strength on the stress-relaxation. However, the image analysis indicates a secondary transient creep of the contour of detachment, which depends on the interfacial bonding. 相似文献
1000.
Intra and intermolecular interactions of heptasulfur imide (S7NH) are investigated in terms of topological properties analyses, such analyses are applied to both experimental (multipole model) and theoretically calculated (DFT and PDFT calculations) charge densities of the isolated molecule and of the crystal. The same analyses are also applied to a multipole model density obtained from theoretically (PDFT) derived structural amplitudes. The covalent bond character of S-N, N-H and S-S bonds are well described in terms of density, ρb, and total energy density, Hb, at the bond critical point rc, though it is clear that the S-S bonds are weaker shared interactions than those of N-H and S-N bonds. Lone pair electron regions of sulfur and nitrogen atoms are revealed as the local charge concentration site from the Laplacian of charge density. The even weaker intermolecular interactions are well characterized; these include the N-H?S hydrogen bonding, N?S binding interactions and S?S binding interactions. All these intermolecular binding interactions are closed-shell interactions. The Laplacian of charge density demonstrates a directional intermolecular binding interaction. The corresponding intermolecular binding energies are derived by MP2/6-311+G(d,p) calculations. Atomic graph of each atom of the molecule is described in detail by the vertices, edges and faces of the polyhedron around the nucleus to illustrate such directional interactions. 相似文献