关于带有完全对称函数的广义数值域

本文给出了矩阵Ａ的带有完全对称函数Ｃｋ的ｍ－数值域在复平面上为线段的充分必要条件．     

光谱法研究氢等离子体循环机制

利用多道光学分析仪测量Hα线形分布,从线形的分布推出再循环的氢原子主要来源于离子中性化后的反射和氢分子的离解。通过双高斯拟合H_α线形分布,由多普勒频移得出了氢原子的入射速度。从氢原子能量分布上的特征峰得出氢分子的离解方式主要是电离和直接离解。     

Polarization of line radiation in the presence of external electric quadrupole and uniform magnetic fields: II. Arbitrary orientation of magnetic field

In continuation of our earlier investigation (referred to hereafter as part I) where we considered the mathematically simple case of magnetic field orientation along the Z-axis of the principal axes frame (PAF) of the electric quadrupole field, we take up here the general problem of arbitrary orientation of the magnetic field with respect to the PAF, and investigate the nature of polarized line spectra of an atom making a transition from an upper level with spin J_u to a lower level with spin J_l. Explicit formulae for the emitted Stokes parameters are obtained and we discuss their physical significance by computing numerically the cases of transitions J_u=1→J_l=0 and . Specific features or signatures of the polarized line spectra are discussed as functions of the relevant physical parameters. The Stokes parameters are also analyzed in terms of the Zeeman term contributions and the cross-term contributions (which arise due to quantum interference).     

Spectroscopically determined potential energy surfaces of the H2O, H2O, and H2O isotopologues of water

Adiabatic potential energy surfaces (PESs) for three major isotopologues of water, H₂¹⁶O, H₂¹⁷O, and H₂¹⁸O, are constructed by fitting to observed vibration-rotation energy levels of the system using the nuclear motion program DVR3D employing an exact kinetic energy operator. Extensive tests show that the mass-dependent ab initio surfaces due to Polyansky et al. [O.L. Polyansky, A.G. Császár, S.V. Shirin, N.F. Zobov, P. Barletta, J. Tennyson, D.W. Schwenke, P.J. Knowles, Science 299 (2003) 539-542.] provide an excellent starting point for the fits. The refinements are performed using a mass-independent morphing function, which smoothly distorts the original adiabatic ab initio PESs. The best overall fit is based on 1788 experimental energy levels with the rotational quantum number J = 0, 2, and 5. It reproduces these levels with a standard deviation of 0.079 cm⁻¹ and gives, when explicit allowance is made for nonadiabatic rotational effects, excellent predictions for levels up to J = 40. Theoretical linelists for all three isotopologues of water involved in the PES construction were calculated up to 26 000 cm⁻¹ with energy levels up to J = 10. These linelists should make an excellent starting point for spectroscopic modelling and analysis.     

顺序等离子体光谱技术测定煤飞灰中常量,少量和微量元素

本文采用顺序等离子体光谱技术测定煤飞灰中主要成份（Ｃａ、Ｍｇ、Ｆｅ、Ａｌ、Ｓｉ、Ｎａ、Ｋ、Ｔｉ）及微量成份（Ｃｕ、Ｓｃ、Ｖ、Ｎｉ、Ｂｅ、Ｍｎ）。用扫描光谱法研究了分析线的选择和光谱背景的扣除。试样用密封罐混酸溶解。测定煤飞灰标准样品ＮＢＳ１６３３ａ的结果与标准值一致。方法用于测定新制备的煤飞灰标准参考物。     

CO2 line intensity FTS measurements with 1% assumed accuracy in the 1.5-1.6 μm spectral range

Using Fourier-transform spectra and a multispectrum fitting procedure, 124 absolute line intensities of ¹²C¹⁶O₂ are obtained for the cold band 30011-00001 and the hot band 01131-01101 between 6460 and 6950 cm⁻¹. Vibrational transition dipole moments squared and Herman-Wallis coefficients are reported for each band. Cross comparisons made with previous experimental results and with data available in the HITRAN and Carbon Dioxide Spectroscopic Databank (CDSD), bring some confidence on the good level of accuracy of the present results. Motivated by the demanding needs of some atmospheric experiments dedicated to the survey of the carbon cycle, an additional evaluation of potential absolute line intensity measurement limit is also performed on recently published carbon dioxide absolute line intensity independent measurements. These are obtained in two different laboratories on the bands 30013-00001 and 30012-00001 both located in the 1.6 μm spectral window. It is shown that Fourier-transform experimental CO₂ line intensity determination is approaching the challenging required figure of about 0.3% accuracy needed for the survey of the atmospheric carbon cycle.     

The absorption spectrum of phosphine (PH3) between 2.8 and 3.7 μm: Line positions, intensities, and assignments

Over 8000 line positions and intensities of phosphine (PH₃) at 3 μm have been measured at 0.0115 cm⁻¹ resolution with the McMath-Pierce Fourier Transform spectrometer at Kitt Peak. The observed line intensities ranged from 4.13 × 10⁻⁶ to 4.69 × 10⁻² cm⁻² atm⁻¹ at 296 K, for line positions between 2724.477 and 3601.652 cm⁻¹. This region spans eight interacting vibrational states: 3ν₂ (2940.8 cm⁻¹), 2ν₂ + ν₄ (3085.6 cm⁻¹), ν₂ + 2ν₄ (3214.9 cm⁻¹), ν₁ + ν₂ (3307.6 cm⁻¹), ν₂ + ν₃ (3310.5 cm⁻¹), 3ν₄ (∼3345 cm⁻¹), ν₁ + ν₄ (3426.9 cm⁻¹), and ν₃ + ν₄ (3432.9 cm⁻¹). Assignments have been determined for all the bands except 3ν₄ (a weak band in a highly congested area) for a total of 4232 transitions. The total integrated intensity for this region is 5.70 cm⁻² atm⁻¹ near 296 K, and assigned lines account for 79% of the observed absorption. The two strongest bands in the region are ν₁ + ν₄ and ν₃ + ν₄ with band strengths at 296 K of 1.61 and 2.01 cm⁻² atm⁻¹, respectively. An empirical database of PH₃ line parameters (positions, intensities, and assignments) is now available. Lower state energies (corresponding to assignments from this study) and line widths from the literature are included; default values are used for unassigned features.     

线谱对参数的一步插值预测矢量量化

利用语音短时谱变化相对较慢、其邻近ＬＳＰ（ＬｉｎｅＳｐｅｃｔｒｕｍＰａｉｒ）失量存在充分相关这一特性，提出了一种新的谱编码方法，即ＬＳＰ编码的一步插值预测矢量量化。本文设计了一个１８ｂｉｔ／ｆｒａｍｅ分裂矢量量化方案用于量化预测残差，当帧变化周期为３０ｍｓ时，平均谱失真仅为１．１７８ｄＢ。     

线有向图的幂敛指数

设G是有向图，LG表示c的线有向图，本文得到了它们的幂敛指数及周期之间的关系：k（G）－1≤（LG）≤k（G）＋1,p（LG）=p（G）特别地，当G为本原图时有：k（LG）＝k（G）＋1