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21.
22.
Milovan M. Stoiljković Igor A. Pašti Miloš D. Momčilović Jelena J. Savović Mirjana S. Pavlović 《Spectrochimica Acta Part B: Atomic Spectroscopy》2010
Enhancement of emission line intensities by induced oscillations of direct current (DC) arc plasma with continuous aerosol sample supply was investigated using multivariate statistics. Principal component analysis (PCA) was employed to evaluate enhancements of 34 atomic spectral lines belonging to 33 elements and 35 ionic spectral lines belonging to 23 elements. Correlation and classification of the elements were done not only by a single property such as the first ionization energy, but also by considering other relevant parameters. Special attention was paid to the influence of the oxide bond strength in an attempt to clarify/predict the enhancement effect. Energies of vaporization, atomization, and excitation were also considered in the analysis. In the case of atomic lines, the best correlation between the enhancements and first ionization energies was obtained as a negative correlation, with weak consistency in grouping of elements in score plots. Conversely, in the case of ionic lines, the best correlation of the enhancements with the sum of the first ionization energies and oxide bond energies was obtained as a positive correlation, with four distinctive groups of elements. The role of the gas-phase atom-oxide bond energy in the entire enhancement effect is underlined. 相似文献
23.
C.Y. Wang A.W. Liu V.I. Perevalov S.A. Tashkun K.F. Song S.M. Hu 《Journal of Molecular Spectroscopy》2009,257(1):94-104
We present a continuation of our investigation of the second most abundant isotopic species of nitrous oxide, 14N15N16O and 15N14N16O, in the infrared (IR). Our two previous contributions looked at the 3500–9000 cm−1 region for 14N15N16O and 15N14N16O, respectively, in the 3500–9000 cm−1 region. The use of highly enriched isotopologue samples in this study allowed us to go further into the IR, down to 1200 cm−1. A total of 2 2742 transitions have been assigned based on the effective Hamiltonian model, with 108 of them being reported here for the first time. Rovibrational analyses of 98, 101, 8, 3, 6, 1 and 1 bands for the 14N15N16O, 15N14N16O, 15N15N16O, 14N15N18O, 15N14N18O, 14N15N17O and 15N14N17O isotopologues, respectively, were also performed. 相似文献
24.
马氏定律与哈勃定律的辨析 总被引:2,自引:2,他引:0
本文从理论,实验上论证了“马氏(红移)定律”,同时指出所谓“退行速度Vr”或“星系红移”与“星系间的距离”无必须的关系,从这个意义上来说,哈勃定律是错误的。 相似文献
25.
Ch. Lisdat N. Vanhaecke D. Comparat P. Pillet 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,21(3):299-309
Two-photon photoassociation spectra in a Λ-type excitation scheme are analysed under the systematically varied experimental conditions of frequency detunings and laser
intensities. Line shape fits are presented as well as the investigation of intensity and detuning dependent line shifts. From
both we determine the attained spectroscopic precision, that is corrected for a systematic line shift due to the thermal distribution
of atoms in the trap. An energy correction for this effect is given. Information about the feasibility of generating translationally
cold molecules in a well defined rotational and vibrational level by the photoassociation process is derived from the analysis.
Received 21 May 2002 Published online 15 October 2002
RID="a"
ID="a"Current address e-mail: christian.lisdat@ptb.de
RID="b"
ID="b"e-mail: pierre.pillet@lac.u-psud.fr 相似文献
26.
领导班子政绩考核评价系统的设计 总被引:1,自引:0,他引:1
领导班子政绩考核评价系统是对地方领导班子集体政绩考核测评的一套理论体系。在促进地区全面、协调可持续发展发挥着重要的指导作用,促进了对党政领导干部评价工作向着制度化、规范化发展。考核评价系统主要包括对各类考核指标的数据信息、进行全面收集、处理、统计、分析、反馈和检查考核。 相似文献
27.
邱祖铭 《西安石油大学学报(自然科学版)》1992,(3)
截交线、相贯线的原有定义在图学界未能统一,且多是以交线的形成方式为依据而建立的,给使用带来很多困难.本文试从解析几何的角度,对截交线、相贯线以新的定义,使《画法几何》中对该类问题的论述更趋合理,求解更为明晰. 相似文献
28.
罗佑新 《河北理工学院学报》1993,(3)
在分析试验数据处理的现状后,提出了试验数据处理及试验数据在线监测的非等间距的灰色GM(1.1)模型与方法,这种方法弥补了现有数据处理及其在线监测方法的不足。实例表明,该方法简单实用,是一种新的方法,值得推广使用。 相似文献
29.
30.
David Jacquemart Robert Gamache 《Journal of Quantitative Spectroscopy & Radiative Transfer》2005,96(2):205-239
This paper describes a semi-empirical calculation of the air-broadened half-widths and the air pressure-induced frequency shifts for the H216O isotopologue. This semi-empirical calculation is based on fits of several recent high-quality measurements and theoretical calculations to the first-order terms in the expansion of the complex Robert-Bonamy (CRB) equations, which yields a second- and first-order polynomial function of the differences in the upper- and lower-state vibrational quantum numbers for the half-width and line shift, respectively. The aim of this work was to obtain a complete set of air-broadened half-widths and air pressure-induced frequency shifts for transitions of H216O present in the HITRAN database from microwave to the visible in order to supplement the observed and calculated values. For around 700 sets of rotational quantum numbers (), semi-empirical coefficients describing the vibrational dependence of the air-broadened half-widths and the air pressure-induced frequency shifts have been obtained directly from the fit of experimental and/or theoretical data. The accuracy of the parameters deduced from this calculation is estimated to be between 5% and 10% for the air-broadened half-widths and between 0.001 and for the air pressure-induced frequency shifts. For sets of rotational quantum numbers for which either none or insufficient experimental/theoretical data were available to deduce a vibrational dependence, further approximations have been used to obtain a complete set of semi-empirical coefficients. 相似文献