关于构建和谐社会若干问题的思考

构建社会主义和谐社会是新一届领导集体提出的重要战略思想,这具有重要的理论意义和实践价值。本文采用社会学方法,对构建和谐社会应注意的五个基本问题展开论证。对构建社会主义和谐社会提出了自己的一些看法。     

武汉市星级饭店布局的影响因素分析

以武汉市的110家星级饭店为研究对象,运用GIS空间分析工具,分析和探讨了其规模结构、空间布局特征和规律.结果表明武汉市星级饭店在等级规模上表现为纺锤形结构,在空间分布上呈现出核心—边缘结构.具体为向主干道和商贸发达地区集聚.得出了武汉市星级饭店空间布局影响因素为人口密度、交通区位条件、商贸发达程度和旅游景点的分布.     

武汉市土地利用结构信息熵演变及动力分析

采用武汉市建成区1990~2003年土地利用及相关的社会经济统计数据作为研究的基础数据,借助信息论的信息熵原理,分析了武汉市土地利用结构的动态演变特征,利用主成分与灰色关联相结合的分析方法得出了武汉市土地利用结构变动的主要动力因子.研究表明:武汉市土地利用信息熵持续下降,均衡度、优势度呈波动状态,土地利用职能相对收缩,土地空间利用类型表现出不均衡态势,土地利用开发经历了1990~1994年的剧变期和1995~2003年的平稳期两个阶段;影响武汉市土地利用结构变动的主要因子有城市产业结构变化拉动因子、城市建设与改造压力因子、城市福利与城市社会结构变化推动因子,其中前两者的影响更为显著.     

LiCl对脂肪族聚氨酯脲结构与性能的影响

通过FT-IR和DSC等研究了L iC l对脂肪族聚氨酯脲溶液粘度以及聚氨酯脲膜的结构和性能的影响。研究结果表明:L iC l的加入使聚氨酯脲溶液的初期粘度降低,后期粘度升高;含L iC l的聚氨酯脲的Tg和氨酯羰基的氢键化程度提高,但脲羰基的氢键化程度降低;L iC l的加入使聚氨酯脲的拉伸模量、硬度、撕裂强度和吸水率显著升高。     

气动人工肌肉位置控制策略

针对气动人工肌肉位置控制系统,提出了两层滑模的变结构鲁棒控制策略,控制器的推导基于李亚普诺夫稳定性理论.实验表明所设计的气动人工肌肉位置控制系统稳态控制精度可达到±0.2 mm,在负载质量和气源压力改变的情况下,稳态位置控制精度仍可达到±0.3 mm,实验结果证明了所提出方法的有效性和系统的鲁棒性.该研究为气动人工肌肉获得广泛的应用提供了理论依据.     

Syntheses and Crystal Structures of Ternary Complexes of Zinc(Ⅱ) and Cadmium(Ⅱ) with 3-Aminobenzoic Acid and 1,10-Phenanthroline

Two new ternary complexes [Zn(3-aba)2(phen)](2.58H2O 1 and {[Cd(3-aba)- (phen)2]·(NO3)·(1.5H2O)}n 2 (3-aba = 3-aminobenzoic acid anion, phen = 1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, UV spectrum and X-ray diffraction. Complex 1 crystallizes in the rhombohedral system, space group R with a = 3.5733(3), b = 3.5733(3), c = 1.1231(2) nm, V = 12.419(3) nm3, C26H25.17N4O6.58Zn, Mr = 564.37, Z = 18, F(000) = 5253, μ = 0.937 mm-1, Dc = 1.358 g/cm3, R = 0.0668 and wR = 0.1690 for 2424 observed reflections (I > 2σ(I)). Complex 2 belongs to the tetragonal system, space group P4/ncc with a = 2.88451(10), b = 2.88451(10), c = 1.55571(11) nm, V = 12.9441(11) nm3, C31H25CdN6O6.50, Mr = 697.97, Z = 16, F(000) = 5648, μ = 0.727 mm-1, Dc = 1.433 g/cm3, R = 0.0607 and wR = 0.1742 for 3468 observed reflections (I > 2σ(I)). Complex 1 displays a mononuclear structure. The carboxylate group of 3-aminobenzoic acid anion coordinates to Zn(Ⅱ) in a chelating bidentate mode, and the nitrogen atom of the ligand does not involve in coordination. Complex 2 exhibits a one-dimensional chain structure with 3-aminobenzoic acid anion coordinating to Cd(Ⅱ) in a μ2-bridging mode through its nitrogen atom and one of its oxygen atoms.     

非对映立体专一性合成二芳基取代环丙烷氨基酸及晶体结构

室温下对氯苯基重氮甲烷与(Z)-2-苯基-4-苯亚甲基-5(4H)口-恶唑酮经1,3-偶极环加成反应,以82%的产率得到环加成物,再经醇解开环、水解去保护得到顺-2-(4-氯苯基)-反-3-苯基-r-1-氨基环丙烷羧酸,产率56%。环加成产物的晶体结构及其粗产物的GC-M S测定结果表明,对氯苯基重氮甲烷与口恶唑酮的环加成反应是非对映立体专一性的。     

广西小城镇地域空间结构特征及其发展探析

受区位因素、自然条件、经济社会发展水平和基础设施状况的影响,广西小城镇发展极不平衡,分布总体上东密西疏,且有明显的沿河流和交通干线及平原分布的特征,并形成四大城镇空间发展区,构成了广西小城镇的网络结构系统;针对小城镇发展腹地特点,不同地区的小城镇发展重点也应有所区别.     

The Impact of Foaming Effect on the Physical and Mechanical Properties of Foam Glasses with Molecular-Level Insights

Foaming effect strongly impacts the physical and mechanical properties of foam glass materials, but an understanding of its mechanism especially at the molecular level is still limited. In this study, the foaming effects of dextrin, a mixture of dextrin and carbon, and different carbon allotropes are investigated with respect to surface morphology as well as physical and mechanical properties, in which 1 wt.% carbon black is identified as an optimal choice for a well-balanced material property. More importantly, the different foaming effects are elucidated by all-atomistic molecular dynamics simulations with molecular-level insights into the structure–property relationships. The results show that smaller pores and more uniform pore structure benefit the mechanical properties of the foam glass samples. The foam glass samples show excellent chemical and thermal stability with 1 wt.% carbon as the foaming agent. Furthermore, the foaming effects of CaSO₄ and Na₂HPO₄ are investigated, which both create more uniform pore structures. This work may inspire more systematic approaches to control foaming effect for customized engineering needs by establishing molecular-level structure–property–process relationships, thereby, leading to efficient production of foam glass materials with desired foaming effects.     

Structural Diversity of Silver Fluorinated β-Diketonates: Effect of the Terminal Substituent and Solvent

In order to demonstrate the role of the fluorination and some solvents in the structural organization of the Ag(I) coordination polymers with β-diketonate ligands (R¹C(O)C_αHC(O)R²)⁻ we synthesized a series of the compounds containing tfac- (R₁ = CH₃, R² = CF₃) and pfpac- (R₁ = CH₃, R² = C₂F₅) anions. Solvent-free [Ag(L)]_∞ (L = tfac 1, pfpac 2) compounds and the corresponding acetonitrile and toluene adducts have been characterized by elemental analysis and/or NMR, IR and single-crystal XRD. This series includes five new coordination polymers. Compound 1 is a 3D coordination framework based on Ag–O_{chelate/bridge}, Ag–C_α bonds, and argentophilic interactions. An increase in the fluorinated group leads to a chain coordination polymer 2 of an unusual structural organization. These chains can be represented as a “DNA-type”, where two intertwined helices based on Ag–O_chelate and Ag–C_α bonds are connected through Ag–O_bridge ones. Two structural types of chain coordination polymers, [Ag(tfac)(CH₃CN)] and [Ag₂(L)₂(solvent)], have been revealed for the adducts. The latter structural type differs significantly from the previously studied toluene and acetonitrile adducts of fluorinated Ag(I) β-diketonates of the same stoichiometry. Thermal analysis in helium showed that both 1 and 2 decompose to metallic silver with the compound of pfpac-ligand being slightly more stable.