Noncovalent associations in fluorous fluids

Perfluorocarbons (PFCs) are emerging as a new type of liquid phase in which molecular recognition processes can effectively take place. The combination of perfluorocarbons (PFCs) and noncovalent associations, mostly hydrogen bonds, ion pairing, halogen bonds or coordination bonds, has already been successfully exploited for applications in organic synthesis (catalyst recycling, by-product removal), electrochemical sensing, selective extraction/titration processes or to prepare gels. Due to the extreme solvophobic effect in PFCs, the least polar existing fluids, noncovalent associations tend to be enhanced. For instance, quantitative data on the increase in association strength occurring in PFCs have recently been reported for ion-pairing interactions or encapsulation processes. Moreover, several examples show that confining a receptor in a fluorous phase leads to recognition processes with improved selectivity.     

主手征场方程的对称及其构成的李代数

利用主手征场方程的Lax 对及无穷小意义下的“穿衣服”方法,得到了主手征场方程的无穷多串对称,并且证明了它们构成一圈代数以及某一与Virasors 代数类似的无穷维李代数.     

城乡公交服务质量评价方法

在解析城乡公交特性,建立城乡公交服务质量评价指标体系,以及对指标体系进行量化与分级的基础上,分别应用面向乘客需求的城乡公交服务质量差距模型和基于集对分析法(SPA)的城乡公交服务质量综合评价模型,研究城乡公交服务质量.以慈溪市城乡公交为案例进行实证分析,通过两种方法的对比得到了较为一致的结果,表明集对分析法在评价城乡公交服务质量上是可行的.     

三阶超对称非线性Schr?dinger方程的延拓结构

超对称的Heisenberg铁磁连模型是一类非常重要的可积系统,它与固体物理中的电子强关联Hubbard模型有着紧密的联系.文章主要利用超对称延拓结构理论的方法,分析高阶超对称非线性Schr?dinger方程,进行研究得到了该方程延拓代数对应的Lax对.     

极强激光场驱动超亮伽马辐射和正负电子对产生的研究进展

高功率超短超强激光脉冲的诞生开启了相对论非线性光学、高强场物理、新型激光聚变、实验室天体物理等前沿领域.近年来,随着数拍瓦级乃至更高峰值功率激光装置的建成,超强激光与等离子体相互作用进入到一个全新的高强场范畴.这种极强激光场与等离子体相互作用蕴含着丰富的物理过程,除了经典的波与粒子作用、相对论效应、有质动力效应等非线性物理过程外,量子电动力学(QED)效应变得格外重要,例如辐射阻尼效应、正负电子对产生、强伽马射线辐射、QED级联、真空极化等.本文主要介绍我们近年来在极端强激光场与等离子体相互作用中激发的QED效应以及伴随的超亮强伽马射线辐射和稠密正负电子对产生等方面的研究进展.     

羟基硅酸盐润滑油添加剂对45#钢/球墨铸铁摩擦副摩擦磨损性能的影响

采用MM-200型摩塔磨损试验机考察了45^#钢／球墨铸铁摩擦副在650SN基础油和含羟基硅酸盐矿物复合微粉的650SN基础油(KF-1)润滑下的摩擦磨损性能，结果表明：在650SN基础油润滑下的摩擦系数和磨损率随试验时间增加变化较小；而在KF-1润滑下，试验初期的摩擦系数和磨损率比基础油润滑下的稍大，随着试验时间的延长，相应的摩擦系数和磨损率同基础油润滑下的相比明显降低．磨损表面显微硬度测试结果表明，在KF-1润滑下45^#钢磨损表面形成了多孔摩擦改性层，硬度明显提高，因而摩擦磨损性能显著改善．     

pePC-SAFT: Modeling of polyelectrolyte systems: 1. Vapor–liquid equilibria

A molecular thermodynamic model for polyelectrolyte systems—called pePC-SAFT—is proposed. The effect of charged monomers within the polyelectrolyte chain is explicitly taken into account in the reference term by replacing the hard-chain contribution of the PC-SAFT model by a charged-hard-chain contribution. Moreover, counterion condensation is accounted for to determine the effective number of charges along the polyion as well as of free counterions. The electrostatic contribution of the free counterions is described by a Debye–Hückel term.     

Separation of amino alcohols using divalent dipeptides as counter ions in aqueous CE

Divalent dipeptides have been introduced as counter ions in aqueous CZE. The dipeptides form ion pairs with amino alcohols in the BGE and facilitate the separation of amino alcohols. High concentrations of dipeptide caused reversed effective mobility for the analytes. The net charge of the dipeptide can be controlled using a buffer or a strong base, and regulates the interaction between the dipeptide and the amino alcohol. A stronger interaction and higher selectivity of amino alcohols was observed when the dipeptides were used as divalent counter ions, than in monovalent or uncharged form. Association constants for ion pairs between divalent dipeptides and amino alcohols can be used to enhance selectivity for amino alcohols in CZE. No chiral separation of amino alcohols was observed when using the dipeptides as ion‐pairing chiral selectors in aqueous BGE, but addition of methanol to the BGE promoted enantioselectivity.     

Au-Au碰撞中大横动量双轻子对的产生(英文)

运用微扰QCD讨论了重离子碰撞中大横动量轻子对的分布, 计算了Au-Au碰撞中两个部分子产生的轻子对的贡献。引入了轻子对产生的直接单光子过程和分解单光子过程。大横动量情况下的所有过程都包括在内, 而且考虑了核遮蔽效应和同位旋效应, 作为QGP背景的双轻子信号有了一个好的修正。The large transverse momentum distribution of lepton pairs produced in heavy-ion collisions has been studied, making use of the perturbative QCD. The contribution of the two parton production process into lepton pairs in Au Au collisions is calculated. Lepton pair production with the direct single photon process and the resolved single photon process are introduced. We believe that the photon processes are significant. The complete processes at large transverse momentum are included, and moreover, the effect of shadowing and isospin of nucleus are also considered in heavy ion collisions. Dilepton signals to regard the background of QGP have a good correction.