《人的境遇》中的文化想象

《人的境遇》是一部西方哲理性概念小说。小说对人的命运的哲学沉思中隐含着作者的东方文化想象,这种想象是20世纪西方现代人的思想困惑在东方的心理投射,这与西方现代人的二元思维结构和分裂的世界观紧密相关,而其抗拒命运的途径中也显出人道主义的缺失与不足。     

La_(0.5)M_(0.5)MnO_3(M=Sr,Ba)的水热合成与表征

我们用水热法合成了钙钛矿锰氧化物La0.5M0.5MnO3(M=Sr,Ba)系列样品,研究了制备条件对结构、形貌和磁性的影响.     

单一稀土处理油菜种子对其吸收镉的影响

探讨了Ｌａ，Ｃｅ，Ｎｄ，Ｐｒ４种单一稀土处理油菜种子，在不同程度Ｃｄ污染土壤上种植后，对油菜生长发育及吸Ｃｄ量的影响。结果表明，Ｃｅ抑制油菜吸收重金属Ｃｄ效果最佳，其次为Ｌａ，随土壤Ｃｄ污染程度加重，Ｎｄ，Ｐｒ对油菜吸收Ｃｄ也表现出一定的抑制效果，同时均不同程度地提高了干物质产量。影响Ｃｄ累积率降低幅度大小顺序为：Ｃｅ＞Ｎｄ＞Ｌａ＞Ｐｒ。     

镧、铈、钕、镨浸种处理对油菜吸收铬量及生物产量的影响

使用单一稀土—La、Ce、Nd、Pr对油菜种子进行浸种处理 ,以盆栽方式 ,明确了浸种处理后 ,油菜对Cr吸收、积累及生物产量的影响。结果表明 ,在不同程度Cr污染土壤上 ,4种单一稀土浸种处理均抑制了土壤中重金属Cr向油菜地上可食部分的吸收和转移 ,其抑制效果因土壤Cr污染程度不同而异。影响Cr累积率降低幅度大小均以Ce处理表现最佳 ,同时均不同程度地提高了油菜中干物质的积累     

Ti-Fe-Ni-La合金的组织结构与吸放氢特性

研究了Ｔｉ－Ｆｅ－Ｎｉ－Ｌａ合金的组织结构与吸放氢性能。利用光学金相显微技术，Ｘ射线衍射技术和电子探针分子析了合金成分变化对其金相组织、第二相形态及分布的影响。     

Influence of the electric characteristics of II–VI semiconductor material on the electroluminescence of lanthanide complex

The organic-inorganic combined structural device (ITO/PVK:Eu/ZnS/Al) is fabricated based on layered optimization scheme. II–VI semiconductor material ZnS is acted as an electron function (transporting and acceleration) layer. The hot electrons which have been accelerated in the ZnS layer directly impact excitation europium ions through resonant energy transfer and then recombine with injected holes to form excitons in PVK or EuTTA₂(N-HPA)Phen. Europium (Eu) ions may also be excited by intramolecular energy transfer from ligands. There are two kinds of excitation mechanisms: impacted excitation and injected recombination for the combined structural device. The electroluminescence (EL) intensity of the combined structural device is strongly improved and reaches up to 381 cd/m² at 20 V compared with the pure organic structural device. It may be an effective method to improve the EL intensity of the lanthanide complex by using electric characteristics of inorganic semiconductor materials.     

Electronic structure and g factors of narrow-gap zinc-blende nanowires and nanorods

The Hamiltonian in the framework of eight-band effective-mass approximation of the zinc-blende nanowires and nanorods in the presence of external homogeneous magnetic field is given in the cylindrical coordinate. The electronic structure, optical properties, magnetic energy levels, and g factors of the nanowires and nanorods are calculated. It is found that the electron states consist of many hole-state components, due to the coupling of the conduction band and valence band. For the normal bands which are monotone functions of |k_z|, long nanorods can be modeled by the nanowires, the energy levels of the nanorods approximately equal the values of the energy band E(k_z) of the nanowires with the same radius at a special k_z, where k_z is the wave vector in the wire direction. Due to the coupling of the states, some of the hole energy bands of the nanowires have their highest points at k_z≠0. Especially, the highest hole state of the InSb nanowires is not at the k_z=0 point. It is an indirect band gap. For these abnormal bands, nanorods can not be modeled by the nanowires. The energy levels of the nanorods show an interesting plait-like pattern. The linear polarization factor is zero, when the aspect ratio L/2R is smaller than 1, and increases as the length increases. The g_z and g_x factors as functions of the k_z, radius R and length L are calculated for the wires and rods, respectively. For the wires, the g_z of the electron ground state increases, and the g_z of the hole ground state decreases first, then increases with the k_z increasing. For the rods, the g_z and g_x of the electron ground state decrease as the R or the L increases. The g_x of the hole ground state decreases, the g_z of the hole ground state increases with the L increasing. The variation of the g_z of the wires with the k_z is in agreement with the variation of the g_z of the rods with the L.     

稀土离子La~(3+)修饰纳米TiO_(2-x)F_x光催化性能

以四氯化钛、硝酸镧、硫脲、氟化铵、氨水等为主要实验药品,采用常温络合-控制水解法制备具有可见光催化活性的La离子修饰纳米TiO2-xFx光触媒乳液.使用XRD、UV-Vis、纳米激光粒度分析仪等表征了样品的物相、粒径、组成、光吸收等性质.在光照下,考察了La修饰纳米TiO2-xFx光触媒乳液降解酸性红3R的光催化性能.结果表明,当La掺杂物质的量浓度为0.1%,F掺杂物质的量浓度为0.3%,体系pH值为6,回流时间为15min时,样品乳液对酸性红3R染料的降解率达到95%以上.     

La含量对Ni-S_2O_8~(2-)/ZrO_2-Al_2O_3固体超强酸催化剂结构及异构性能的影响

制备一系列不同La质量分数的La-Ni-S2O82-/Zr O2-Al2O3催化剂(记为La-Ni-SZA),采用XRD、BET、H2-TPR、FTIR、Py-IR等手段对催化剂进行表征。以正戊烷异构化为探针反应,考察La质量分数对催化剂结构和异构化性能的影响。结果表明:引入适量的La能使催化剂中四方晶相Zr O2的颗粒尺寸减小,改善催化剂的氧化还原性能,促进L酸和B酸的形成;催化剂总酸量顺序为La(1.0)-Ni-SZANi-SZASZA;La质量分数为1.0%的La(1.0)-Ni-SZA催化剂具有最高的异构化活性,在反应温度为140℃、压力为2.0 MPa、氢烃摩尔比为4、质量空速为1.0 h-1时,异戊烷产率达66.5%,明显高于Ni-SZA催化剂最佳反应温度(180℃)下的异戊烷产率(55.0%)。     

La2O3和WSi2增强MoSi2基复合材料的摩擦磨损性能研究

选用MRH-5A型环-块摩擦磨损试验机测定了3种载荷和2种转速条件下La2O3和WSi2增强MoSi2基复合材料在滑动干摩擦时的摩擦磨损性能,采用扫描电子显微镜分析了复合材料磨损表面形貌.结果表明:La2O3和WSi2增强MoSi2基复合材料的抗磨性能优于MoSi2及WSi2/MoSi2材料;当载荷与速度乘积(pv)值小于183.04N·m/s时,La2O3和WSi2增强MoSi2基复合材料的磨损质量损失仅为相同条件下MoSi2的1/4～1/6和WSi2/MoSi2的1/2;这是由于La2O3和WSi2复合增强相存在硬化和韧化协同作用所致;随着pv值增加,La2O3和WSi2增强MoSi2基复合材料依次呈现犁削、粘着磨损和疲劳磨损特征.