Endor frequencies of randomly oriented triplets by electron spin echo spectroscopy

ENDOR frequencies of randomly oriented triplets have been measured from the fast Fourier transform of electron spin echo envelope modulation. Important experimental conditions are low temperatures, high microwave power and long phase memory time in a proper form of solvent. The technique is exemplified by using diphenylmethylenes in rigid glasses, polycrystalline forms and single crystals of benzophenones.     

The noncumulative effect of methyl substituents on the rate of addition of benzeneselenenyl chloride to olefins1

The rates and products of addition of benzeneselenenyl chloride to ethylene and its six Me substituted derivatives have been determined in methylene chloride at 25°. Unlike the addition of 4-chlorobenzenesulfenyl chloride to this same series of compounds, the effect of Me groups on the rates of addition is not cumulative. Also the regiochemistry of the product is different. For arenesulfenyl chloride additions, products of anti-Markownikoff orientation are formed preferentially under conditions of kinetic control. Under similar conditions regiospecific formation of the Markownikoff adduct is observed for the addition of benzeneselenenyl chloride to methylpropene and 2-methyl-2-butene. These data indicate a difference in both rate and product determining transition states between additions of arenesulfenyl and selenenyl chlorides to alkenes.     

A re-investigation of the far-infrared spectrum of isotactic polystyrene in the 7–2400 cm−1 region at ambient temperature

Fourier-transformed interferometric techniques have been utilized to obtain new data for the far-infrared spectrum of isotactic polystyrene. The region in which rotational and translational crystalline bands are observed has been investigated and 21 absorptions associated with infrared active crystal lattice modes have been observed in the 7–400 cm^?1 region. Possible assignments of these bands have been attempted, and a comparison with the previously reported data for polypropylene has been made.     

Peripatetic Highlights in Bern

This tour of significant scientific sites in Bern uses the local legacy of its most illustrious scientists, Albert Einstein (1879–1955) and Fritz Houtermans (1903–1966), as its guiding thread through the old town and the university district.Ann M.Hentschel is translator of the correspondence volumes of The Collected Papers of Albert Einstein and is currently employed by the Institute for the History and Philosophy of Science at the University of Bern to write the guide for a city tour of Einsteins old haunts in Bern for the coming jubilee of special relativity in 2005. For the historical companion guidebook, see Hentschel and Grasshoff, Albert Einstein (ref. 4) and the website <.     

I.I. Rabi: The Two Cultures and the Universal Culture of Science

I set forth and discuss I.I. Rabis views on the nature of science and society, focusing specifically on Rabis views on science and government, science and education, and science and religion. I also explore the influence of Rabi and C.P. Snow on each other. In the 1960s, Rabi set forth his mature and boldest positions, advocating science as the center of education and science as the replacement for religion. His positions culminate in science as the universal culture. I highlight Rabi not only as a scientist and public servant, but also as a public intellectual actively engaged with and connected to major issues of his time.Michael A. Day is Professor of Physics at Lebanon Valley College. He holds doctorates in both physics and philosophy.     

Enrico Fermi in Pisa

I discuss the early work of Enrico Fermi (1901-1954) as a student in Pisa at the Scuola Normale Superiore and at the University of Pisa (1918-1922), paying particular attention to the four papers he published during those years and to his licenza and doctoral theses.     

Multivariate Refinement Equations and Convergence of Cascade Algorithms in Lp（0〈p〈1）Spaces

We consider the solutions of refinement equations written in the form

英国兰开夏大学的物理实验教学

简要介绍了英国兰开夏大学的物理实验教学和成绩评定方法,分析了其特色,可以看出该大学较重视学生创造性综合能力的培养.