ICP－AES中内标法的应用研究 Ⅲ．用内标法校正基体干扰

通过观测基体对分析元素发射强度的干扰情况，分析干扰机制，从而确定用来校正基体干扰的内标元素与分析元素的匹配条件。实验结果表明，只要选择合适的内标元素，可以校正基体干扰。     

Dicholorbenzyl alkyl ether homologs as retention index markers and internal standards for the analysis of environmental samples using capillary gas chromatography

A homologous series of 2,4-dichlorobenzyl alkyl ethers (DCBEs) have been synthesized and purified for use as retention index calibrants and internal standards. They are stable, sensitive to ECD and FID and ideal for GC-MS, with base peaks at m/z 159/161. The retention index calibration against the n-alkanes for a linear temperature program (LTP) series is given and recommendations made for the most suitable members of the DCBE series for use as internal standards in organochlorine (OC) residue analysis.     

Theoretical Study of the Photochemical Reaction Mechanism of Bicyclo [4.1.0 ] heptane

IntroductionPhotochemical reactions, which involve a three-membered ring, have been of great interest to experi-mental photochemists[1—10]. A main reason for thisphenomenon is that the cyclopropane ring exhibits somereaction characteristics of double bon…     

Symmetry numbers and chemical reaction rates

This article shows how to evaluate rotational symmetry numbers for different molecular configurations and how to apply them to transition state theory. In general, the symmetry number is given by the ratio of the reactant and transition state rotational symmetry numbers. However, special care is advised in the evaluation of symmetry numbers in the following situations: (i) if the reaction is symmetric, (ii) if reactants and/or transition states are chiral, (iii) if the reaction has multiple conformers for reactants and/or transition states and, (iv) if there is an internal rotation of part of the molecular system. All these four situations are treated systematically and analyzed in detail in the present article. We also include a large number of examples to clarify some complicated situations, and in the last section we discuss an example involving an achiral diasteroisomer.     

雄激素与鼠类的社会行为

雄激素引起的社会行为包括杀婴行为、攻击行为、交配行为和社会识别行为等 ,雄激素首先引起脑结构的性差 ,是雌雄个体社会行为发生差异的基础 .雄激素引起的杀婴行为目前还有争议 ,多数学者认为还与孕酮有关 ;雄激素引起的攻击行为还受年龄、生殖状态 (泌乳时期 )、婚配制度、父本扶养还是母本扶养等各种因素的影响 ;雄激素引起的交配行为、社会识别行为还与化学感觉系统有关 ,社会识别主要由抗利尿激素依赖雄激素而产生 .     

微尾鼩的求偶与交配行为

2005年春季对池内饲养的成体微尾鼩的发情行为进行了观察研究,结果表明微尾鼩交配期可持续3-5d,交配行为多发生在21∶00-01∶00时,每晚可交配10±2次.发情期雄体活跃雌体少动,发情行为主要分为绕嗅、咬颈、爬跨、交配等过程,其中咬颈行为存在于交配的全过程,对交配活动能否成功地完成起着重要作用.交配过程中雌体有逃避、攻击等反交配行为,但雄体却表现出强烈的交配欲望,二者对外来雄体表现出强烈的敌对性而对外来雌体的反应却十分冷淡,交配的持续时间与该次交配前的间隔休息时间无必然联系,而与雌体的反交配行为的强弱有很大关系.     

不同途径中心静脉置管在血透治疗中的对照观察

目的:探讨不同途径中心静脉置管在血透治疗中的优缺点 ,以供临床合理选用。方法:68例患者根据病情 ,分别行颈内静脉及股静脉置管 ,观察导管留置时间 ,相关并发症 ,透析效果评价及患者耐受性。结果:颈内静脉置管血流量充足 ,留置时间长 ,患者耐受性较好。结论:颈内静脉置管是首选的血管通路。     

中医英语等值翻译研究——以《黄帝内经》为例

中医英语的翻译属于科技英语翻译范畴,但是在译法上有别于其他科技文章.中医翻译不仅是两种语言的转换,而且是两种文化的交融.医学语言文学化是中医语言的一大特点,译者在翻译时应力求等值再现原文内容,将翻译对等理论和合作原则运用到中医英语翻译中,使译文和原文尽可能达到翻译中的等效     

腰椎滑脱髂骨棒杠杆复位固定系统的研制与结构分析

介绍一种自行研制的治疗腰椎滑脱的内固定装置,并进行了结构分析.结果表明:①该器械是几何不变体系.②其中支撑棒作为支点棒是整个装置的关键,采用5mm支撑杆,滑脱力是200N时是安全的.③椎弓根钉交叉植入椎体固定,有效阻止了扭转位移,角度提拉杆又使得椎弓根钉的脱出力大大减小.     

一类特殊的两性G -W分支过程及其谱半径

谱半径是不可约马尔可夫链的一个很重要的特征数字.本文主要介绍了两性G-W分支过程,并计算了一类特殊配对函数L(x,y)=x的两性G-W分支过程的谱半径.