Facile synthesis of ZnO/CuO/Eu heterostructure photocatalyst for the degradation of industrial effluent

Zinc oxide-based ternary heterostructure ZnO/CuO/Eu(1%, 3%, and 5% of Eu) nanoparticles were effectively produced by employing Vigna unguiculata (cowpea)waste skin extract as fuel in a simple one-pot combustion process. The as-synthesized heterostructure was analyzed by X-ray diffraction studies, ultraviolet-visible spectroscopy, Fourier Transform Infrared Spectroscopy, Field Emission Scanning Electron Microscopy, and High-Resolution Transmission Electron Microscopy techniques. Besides, the photocatalytic degradation efficiency of the as-obtained ternary nanocomposite was evaluated under UV light for the degradation of model organic pollutants including methylene blue (MB), Rhodamine-B (RB), and an effluent sample collected from the textile industrial waste. During this study, the effect of a variety of parameters on the photodegradation activity of the photocatalysts has been thoroughly evaluated, such as light source, catalyst dose, irradiation period, dye concentration, solution pH, etc. Under UV irradiation(100 mins), the ternary ZnO/CuO/Eu photocatalyst demonstrated excellent degradation activity of ～99 and ～93% for MB and RB, respectively, while for the industrial effluent, a decent degradation activity of 42% has been recorded. Further experiments have revealed a pH and concentration-dependent photocatalytic behavior of the heterostructure photocatalyst. Therefore, the results suggest that the heterostructure photocatalyst can be potentially applied for wastewater treatment and other environmental applications.     

海南桉林林下植被木本多样性的复合因子分析

 通过野外样方样地调查,在比较分析海南岛年降水量、土壤水分含量及土壤速效养分氮、磷、钾的基础上,试图寻找影响桉树林下植被木本多样性的关键因子.复合因子分析结果表明:在影响林下木本多样性主导因子的主成分分析中发现,年降水量成了木本多样性最主要因子即限制因子,第2因子为土壤水分含量,第3因子为土壤速效氮含量.研究结果还表明,在海南年降雨量小于1000 mm的干旱地区不宜发展速生桉树林.     

基于小波分析江苏种植业自然风险的度量

以波动概念来表示种植业自然风险,接着创造性地引入了现代数学的小波分析方法来测定种植业产量的主要趋势分量,得到江苏7种主要农作物变异率和变异系数.实证结果表明,从长远和总体来看,江苏的经济作物自然风险高于粮食作物的自然风险;4种粮食作物的风险由小至大的品种依次为稻谷、玉米、小麦、大豆;3种经济作物的风险由小到大的品种依次为棉花、油菜籽、花生.     

南宁七坡林场尾巨桉人工林生物量的初步研究

【目的】为科学、可持续地经营桉树（Eucalyptus）人工林以及评价桉树人工林在区域碳循环中的地位、作用和生态效益提供有效的依据。【方法】采用平均标准木法和收获法对南宁七坡林场的尾巨桉（Eucalyptus urophylla×E．grandis）及其林下植被的生物量进行调查。【结果】在尾巨桉人工林中,各层次生物量呈现乔木层〉灌木层〉草本层,其中尾巨桉生物量最大,处于主导地位;尾巨桉各器官生物量的大小顺序为树干（64．38％）〉根（24．29％）〉树皮（5．97％）〉老枝（2．25％）〉嫩枝（1．56％）〉老叶（1．32％）〉嫩叶（0．20％）。【结论】尾巨桉的生物量主要集中在树干上,叶的生物量最少。     

Motional relativity and industrial NMR sensors

We explore the implications of motional relativity in NMR and show that sample translation can be used to acquire NMR signals without the need for pulsed RF excitation or pulsed magnetic field gradients. Novel single-shot, on-line NMR acquisition protocols for samples being conveyed at high speed are discussed and preliminary results using a low-cost, on-line prototype NMR sensor are presented.     

高效液相色谱法测定工业废水中5-磺基水杨酸

建立了工业废水中5-磺基水杨酸的高效液相色谱分析方法。采用Kromasil-C18(150mm×4.6mm,5μm)色谱柱,流速1mL/min,柱温30℃,进样体积10μL。流动相为V(甲醇):V(0.01mol/L四丁基溴化铵溶液)=50:50,测定波长235nm。结果线性范围为:0.1—100mg/L,平均加标回收率为103.7%,相对标准偏差为1.3%。     

A Research Review on Strategic Alliance of Industrial Technology Innovation

As technological innovation has been taking a predominant role in today 's industry,strategic alliance of industrial technology innovation is an expansion in the layer of technological development and strategic alliance industry.In China,the national innovation system hasn 't been perfect yet,strategic alliance of industrial technology innovation is still a new-born object which needs further theoretical studies and practical explorations.     

行业均质度对新兴工业区地价的影响分析

新兴工业区的土地使用不仅受到市场的调节，而且在很大程度上还必须接受政策目标的约束和调整，这也会对城市地价产生影响．本以蛇口工业区为例，利用1990年和1995年的工业和商业地价资料，采用回归分析方法研究了几个区位因子和地价的关系，结果表明这些因子和地价的相关性不显．行业布局反映了政策目标的约束和调整，因此本对区内的行业均质度进行量化并分析了它与地价之间的相关关系，结果表明行业均质度和地价显相关．     

Extraction Spectrophotometric Determination of Vanadium in Industrial Waste Water

A new and simple extraction spectrophotometric method for the determination of vanadium(V) with KIO₄, N‐phenylbenzohydroxamic acid (PBHA) and crystal violet (CV), in industrial waste water samples is described. It is based on the extraction of mixed‐ligand complex V(V)‐IO₄^? ‐PBHA‐CV⁺ into chloroform solution over 2‐7 MHC1. The molar absorptivity of the complex is (7.20) × 10³1 mol^?1 cm^?1 at λ_max 535 nm. The detection limit of the method is 44 μg 1^?1 V. The linearity of the calibration curve is followed up to 6 μgmL^?1 in the organic solution with slope, intercept and correlation coefficient of 1.34 × 10^?1, 6.7 × 10^?3 and +0.99, respectively. This method enhances the sensitivity of the conventional PBHA method for the determination of vanadium, and is free from interferences of other metal ions commonly associated with vanadium. The method has been successfully tested for the determination of V in the industrial waste water samples.