全文获取类型
收费全文 | 9282篇 |
免费 | 761篇 |
国内免费 | 665篇 |
专业分类
化学 | 1584篇 |
晶体学 | 18篇 |
力学 | 439篇 |
综合类 | 57篇 |
数学 | 840篇 |
物理学 | 3787篇 |
综合类 | 3983篇 |
出版年
2024年 | 31篇 |
2023年 | 83篇 |
2022年 | 180篇 |
2021年 | 188篇 |
2020年 | 194篇 |
2019年 | 198篇 |
2018年 | 188篇 |
2017年 | 326篇 |
2016年 | 332篇 |
2015年 | 362篇 |
2014年 | 664篇 |
2013年 | 598篇 |
2012年 | 517篇 |
2011年 | 594篇 |
2010年 | 442篇 |
2009年 | 517篇 |
2008年 | 475篇 |
2007年 | 594篇 |
2006年 | 464篇 |
2005年 | 421篇 |
2004年 | 413篇 |
2003年 | 373篇 |
2002年 | 309篇 |
2001年 | 250篇 |
2000年 | 208篇 |
1999年 | 240篇 |
1998年 | 226篇 |
1997年 | 190篇 |
1996年 | 144篇 |
1995年 | 116篇 |
1994年 | 105篇 |
1993年 | 94篇 |
1992年 | 88篇 |
1991年 | 83篇 |
1990年 | 79篇 |
1989年 | 70篇 |
1988年 | 61篇 |
1987年 | 47篇 |
1986年 | 30篇 |
1985年 | 39篇 |
1984年 | 25篇 |
1983年 | 7篇 |
1982年 | 26篇 |
1981年 | 28篇 |
1980年 | 13篇 |
1979年 | 12篇 |
1978年 | 12篇 |
1977年 | 12篇 |
1976年 | 14篇 |
1973年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 281 毫秒
151.
籼粳交稻米品质性状的遗传相关分析 总被引:4,自引:0,他引:4
用种子性状遗传模型对籼粳交稻米8个主要品质性状的遗传相关进行了研究。结果表明,在籼粳杂种中,稻米品质性状之间的遗传相关主要涉及到种子直接遗传效应和母体遗传效应。其中,5个理化品质性状之间以直接效应相关为主,其次为母体效应相关;5个理化品质性状与3个外观品质性状之间只有直接加性、母体加性和母体显性相关;3个外观品质性状之间的遗传相关主要归因于母体效应。尤其是母体加性效应。在所有的性状对中,仅胶稠度和 相似文献
152.
以关联函数、关联积分为工具,研究了需求系统的分形特征,并对需求系统的时间序列进行了分形分析,寻找出无标度区,计算出分维数,进而发现无标度区的位置,分维数的大小等,可作为反映经济波动的定量指标。 相似文献
153.
本文基于Volterra理论和Wiener理论,利用相关分析法,研究并给出了构成基本串联与并联非线性系统结构模型的必要条件,它们能够为辩识一大类可以表示成这些模型和"黑箱"非线性系统提供一种重要的判别依据。文中还给出了计算机模拟算例。 相似文献
154.
G. Schütz 《Journal of statistical physics》1993,71(3-4):471-505
We present a model for a one-dimensional anisotropic exclusion process describing particles moving deterministically on a ring of lengthL with a single defect, across which they move with probability 0 p 1. This model is equivalent to a two-dimensional, six-vertex model in an extreme anisotropic limit with a defect line interpolating between open and periodic boundary conditions. We solve this model with a Bethe ansatz generalized to this kind of boundary condition. We discuss in detail the steady state and derive exact expressions for the currentj, the density profilen(x), and the two-point density correlation function. In the thermodynamic limitL the phase diagram shows three phases, a low-density phase, a coexistence phase, and a high-density phase related to the low-density phase by a particle-hole symmetry. In the low-density phase the density profile decays exponentially with the distance from the boundary to its bulk value on a length scale . On the phase transition line diverges and the currentj approaches its critical valuej
c = p as a power law,j
c – j –1/2. In the coexistence phase the width of the interface between the high-density region and the low-density region is proportional toL
1/2 if the density
f 1/2 and=0 independent ofL if = 1/2. The (connected) two-point correlation function turns out to be of a scaling form with a space-dependent amplitude n(x1, x2) =A(x2)A
Ke–r/ withr = x
2 –x
1 and a critical exponent = 0. 相似文献
155.
Th. Emmler S. Gieschler H. H. Limbach G. Buntkowsky 《Journal of Molecular Structure》2004,700(1-3):29-38
A set of OHO hydrogen bonded systems with known neutron diffraction structure has been studied by fast 1H-MAS echo spectroscopy. It is shown that the application of a simple rotor synchronized echo sequence combined with fast MAS allows a faithful determination of the chemical shift of the proton in the hydrogen bond. Employing the empirical valence bond order model, the experimental 1H chemical shifts of the hydrogen bonded protons are correlated to the hydrogen bond geometries. The resulting correlation between the proton chemical shift and the deviation of the proton from the center of the hydrogen bond covers a broad range of substances. Deviations from the correlation curve, which are observed in certain systems with strong hydrogen bonds, are explained in terms of proton tautomerism or delocalization in low-barrier hydrogen bonds. These deviations are a highly diagnostic tool to select potential candidates for further experimental and theoretical studies. Thus, the combination of the 1H-MAS echo sequence with the correlation curve yields a simple and versatile tool for the structural analysis of OHO hydrogen bonds. 相似文献
156.
19F and 1H NMR spectra of halocarbons 总被引:1,自引:0,他引:1
Foris A 《Magnetic resonance in chemistry : MRC》2004,42(6):534-555
19F NMR chemical shifts and coupling constants are reported for 215 compounds. For 77 of these compounds, 1H NMR spectral data are also given. Long-range couplings, including 8J(F,F) and 5J(F,H), are reported. The complexity of halocarbon spectra owing to the presence of rotational isomers, asymmetric centers, long-range couplings, and chlorine isotope effects are illustrated, and the methods used for analyzing such complex spectra are briefly discussed. 相似文献
157.
A. A. Balandina V. A. Mamedov E. A. Khafizova Sh. K. Latypov 《Russian Chemical Bulletin》2006,55(12):2256-2264
The combined use of 2D NMR correlation methods and ab initio chemical shift calculations is efficient and, in some cases, virtually the only way to determine the structures of new organic
compounds. This approach enabled us to establish the structure of the major unusual product of the three-component reaction
of imidazo[1,5-a]quinoxalin-4-one, bis(2-chloroethyl)amine hydrochloride, and potassium carbonate in DMF.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2172–2179, December, 2006.
Dedicated to Professor A. V. Il’yasov on the occasion of his 70th birthday. 相似文献
158.
多环麝香的分子结构和香气之间的关系 总被引:2,自引:0,他引:2
本文综述了多环麝香的当前进展,并提出了系统的分类方法。对各种多环麝香(茚满型,萘满型,异色满型,氢化引达省型,苊型)香味与分子结构之间关系的研究进行了总结,还作了比较。并描述了多环分子中环上取代基的性质,数量和位置对麝香香味的影响。 相似文献
159.
We present exact explicit expressions for the row spin-spin correlation functions
00
n0 in the isotropicd= 2 Ising model, in terms of elliptic integrals, forn 5. We also give a general structural formula for
00
n0. 相似文献
160.
Zeev Elkoshi Howard Reiss Audrey Dell Hammerich 《Journal of statistical physics》1985,41(3-4):685-708
A hole in a fluid is specified in a well-defined manner. The concentration of holes is a thermodynamic property of the fluid and we derive this concentration in three different ensembles for a one-dimensional fluid of hard rods. The thermodynamics of these rigorously defined holes is developed, and the properties of holes are explored. The ensemble in which the concentration of holes is maintained fixed exhibits dramatic properties. Finally, pair correlation functions for hard rods in the various ensembles are computed. Contrary to a frequently made assumption, the equilibrium number of holes is found to never be proportional to the probability of finding a single hole in the fluid. Constraining the concentration of holes as well as the density leads to dramatic structural effects prominently displayed by the pair correlation function. The ensemble in which the concentration of holes is fixed is an example of an internally constrained metastable system. 相似文献