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181.
182.
M. Aguilar 《Solid State Communications》1984,50(9):837-840
A study by means of the Electron-Paramagnetic-Resonance (EPR) technique of the valence states of the cobalt ion in oxidized and reduced BaTiO3 is presented. As a result, the identification of high-spin Co+ in reduced crystals was possible. The Co2+ centre is also discussed. 相似文献
183.
We obtain a simple derivation of Korzhik's result on the burst distribution of a linear code. 相似文献
184.
The low temperature (1.3–20.0 K) heat capacity of the weak itinerant electron ferromagnet Sc3In was measured in magnetic fields up to ~ 10 T. The heat capacity peak observed around Tc = 6.0 K in zero field becomes smaller with increasing fields and at 9.98 T its magnetic entropy is ≈ 18% of the zero field value. Above Tc, the spin fluctuation contribution to the heat capacity, which is enhanced by the magnetic field at lower fields (?5 T), is quenched at higher fields (?5 T). This depression of the spin fluctuation contibution to the heat capacity by the high magnetic fields occurs at lower magnetic fields than had been considered possible heretofore. Our results suggest that the itinerant ferromagnetism is Sc3In is completely quenched at 12 T. 相似文献
185.
Doubly differential cross sections, in energy and angle, are reported for the electron transfer reaction between potassium and nitrogen dioxide in a crossed beam apparatus at relative collision energies between 2.7 and 30.8 eV. The formation of NO?2 in its ground 1A1 and excited 3B1 state has been observed. Theoretical consideration of these processes indicates that bond bending during the collision has a stronger influence on ion-pair formation than bond stretching. At the lower collision energies most of the excess energy is converted into internal energy of NO?2. 相似文献
186.
187.
E. Fatás-Lahoz M. Sluyters-Rehbach J.H. Sluyters 《Journal of Electroanalytical Chemistry》1982,136(1):59-81
The adsorption of Cd(II) has been studied by measuring the interfacial admittance spectra at different dc potentials of the dropping mercury electrode (DME) in solutions of: (a) 1 M KBr+0.48 mM Cd(NO3)2,(b) 1 M KI+0.105 mM CdI2 and (c) 0.1 M NaI+0.9 M NaClO4 +0.116 mM CdI2 The experimental data were analysed using the procedures described in Part I of this series. The frequency dependence of the admittance corresponds to that of a reversible electrode reaction with reactant adsorption. The potential dependence of the resulting adsorption parameters can be mathematically described by a Langmuir isotherm for adsorption of Cd(II) with the adsorption energy being at least a quadratic function of potential. Detailed checks on the consistency of this model have been applied and were found to be satisfactory. 相似文献
188.
M. Jaros 《Solid State Communications》1978,25(12):1071-1074
It is argued that the recent quantitative results concerning localized defects in semiconductors (e.g. GaAs) are consistent with the possibility of large Auger-type cross sections associated with recombination at these centers.It is proposed that many of the capture cross sections reported to be in the range 10?13–10?16cm2, which exhibit only weak temperature dependence, and which do not depend on carrier concentration, might be explained by this mechanism. 相似文献
189.
The crystal structure of bicyclo [3.3.3]undecane-1,5-diol has been determined. It is monoclinic, P21/c, a = 12.99(2), b = 14.16(2), c = 12.50(1)A,β = 112.42(2)°, with two independent molecules in the asymmetric unit. One of these is disordered, but the other has almost exact C3h symmetry and its conformation and precise molecular geometry agree well with previous calculations by molecular mechanics. The molecule shows considerable angle strain, having bridge angles in the range 118–121° 相似文献
190.
B.M. Craven C. Cusatis G.L. Gartland E.A. Vizzini 《Journal of Molecular Structure》1973,16(2):331-342
X-ray crystal structure determinations show systematic perturbations of the order of 0.01 Å in the oxopyrimidine rings of twelve barbiturate molecules. They appear to be related to the mode of intermolecular NHβO hydrogen bonding. 相似文献